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0000148948
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Comparable Ru ⋯ C and Ru ⋯ H distances have been seen elsewhere: R. M. Stoop, C. Bauer, P. Setz, M. Work, T. Y. H. Wong and A. Mezzetti, Organometallics, 1999, 18, 5691; M. Sanford, L. M. Henling, M. W. Day and R. H. Grubbs, Angew. Chem., Int. Ed., 2000, 39, 3451; J. N. Coalter III, J. C. Huffman, W. E. Streib and K. G. Caulton, Inorg. Chem., 2000, 39, 3757; for a recent discussion of stronger agostic interactions in coordinatively unsaturated ruthenium complexes, see: W. Baratta, C. Mealli, E. Herdtweck, A. Ienco, S. A. Mason and P. Rigo, J. Am. Chem. Soc., 2004, 126, 5549.
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35
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0034596810
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Comparable Ru ⋯ C and Ru ⋯ H distances have been seen elsewhere: R. M. Stoop, C. Bauer, P. Setz, M. Work, T. Y. H. Wong and A. Mezzetti, Organometallics, 1999, 18, 5691; M. Sanford, L. M. Henling, M. W. Day and R. H. Grubbs, Angew. Chem., Int. Ed., 2000, 39, 3451; J. N. Coalter III, J. C. Huffman, W. E. Streib and K. G. Caulton, Inorg. Chem., 2000, 39, 3757; for a recent discussion of stronger agostic interactions in coordinatively unsaturated ruthenium complexes, see: W. Baratta, C. Mealli, E. Herdtweck, A. Ienco, S. A. Mason and P. Rigo, J. Am. Chem. Soc., 2004, 126, 5549.
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Comparable Ru ⋯ C and Ru ⋯ H distances have been seen elsewhere: R. M. Stoop, C. Bauer, P. Setz, M. Work, T. Y. H. Wong and A. Mezzetti, Organometallics, 1999, 18, 5691; M. Sanford, L. M. Henling, M. W. Day and R. H. Grubbs, Angew. Chem., Int. Ed., 2000, 39, 3451; J. N. Coalter III, J. C. Huffman, W. E. Streib and K. G. Caulton, Inorg. Chem., 2000, 39, 3757; for a recent discussion of stronger agostic interactions in coordinatively unsaturated ruthenium complexes, see: W. Baratta, C. Mealli, E. Herdtweck, A. Ienco, S. A. Mason and P. Rigo, J. Am. Chem. Soc., 2004, 126, 5549.
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2342529665
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Comparable Ru ⋯ C and Ru ⋯ H distances have been seen elsewhere: R. M. Stoop, C. Bauer, P. Setz, M. Work, T. Y. H. Wong and A. Mezzetti, Organometallics, 1999, 18, 5691; M. Sanford, L. M. Henling, M. W. Day and R. H. Grubbs, Angew. Chem., Int. Ed., 2000, 39, 3451; J. N. Coalter III, J. C. Huffman, W. E. Streib and K. G. Caulton, Inorg. Chem., 2000, 39, 3757; for a recent discussion of stronger agostic interactions in coordinatively unsaturated ruthenium complexes, see: W. Baratta, C. Mealli, E. Herdtweck, A. Ienco, S. A. Mason and P. Rigo, J. Am. Chem. Soc., 2004, 126, 5549.
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note
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Heating the mixture of the Caulton dimers in the solid state under vacuum (120 °C, 30 h) resulted in formation of 2.
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