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Volumn 344, Issue 10, 2002, Pages 1135-1141

Hexakis(PCP-Platinum and -Ruthenium) Complexes by the Transcyclometalation Reaction and Their Use in Catalysis

Author keywords

Homogeneous catalysis; Multimetallic complexes; P ligands; Platinum; Ruthenium; Transcyclometalation

Indexed keywords


EID: 0347898720     PISSN: 16154150     EISSN: None     Source Type: Journal    
DOI: 10.1002/1615-4169(200212)344:10<1135::AID-ADSC1135>3.0.CO;2-9     Document Type: Article
Times cited : (28)

References (39)
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    • note
    • The lower activity per ruthenium center of 5e as compared to 3b results most likely from the fact that after addition of the cyclohexanone-solution, 5e solubilizes slower in the reaction mixture. In case of a fast catalytic reaction, i. e., reduction of cyclohexanone, this has a more significant effect on the TOF of 5e as compared to 3b, leading to a decreased TOF per ruthenium center for 5e.


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