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2442422414
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note
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3/molecule calculated from molar density, x = 0.74, the volume fraction for cubic closest-packing spheres, and N is Avogadro's number.
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1/3, where c = 0.74, the volume fraction for cubic closest-packed spheres. Andrade viscosity of benzene is given by the expression ln(η,cP) = -4.117 + 2093.7/RT.
-
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35
-
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2442560678
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note
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t/εl, were ε is the extinction coefficient of the transient and l is the path length, in our experiment = 1 cm.
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0001586773
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The quantum yield for t-BuO radical formation from irradiation of di-tert-butyl peroxide in benzene at ambient temperature was 1.66. Wayner, D. D. M.; Lusztyk, E.; Page, D.; Ingold, K. U.; Mulder, P.; Laarhoven, L. J. J.; Aldrich, H. S. J. Am. Chem. Soc. 1995, 117, 8737.
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2442600625
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note
-
The absorbance at time = 0 is calculate by fitting the second-order decay and extrapolating back to time = zero.
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41
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