Direct observation of a stannyl radical in the reactions of the tributylstannyl anion with alkyl halides by a stopped-flow technique

Organometallics

Volumn 17, Issue 10, 1998, Pages 1913-1915

  Wakasa, Masanobu ^a   Kugita, Tsuyoshi ^b  

^a INST OF PHYS AND CHEMICAL RESEARCH   (Japan)

^b TEIKYO UNIVERSITY OF SCIENCE   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000365808     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om980022i     Document Type: Article

References (15)

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7. Ashby, E. C. Acc. Chem. Res. 1988, 21, 414 and references therein.
8. Savéant, J.-M. Adv. Phys. Org. Chem. 1990, 26, 1 and references therein.
9. (Tributylstannyl)potassium was prepared similarly to the preparation of (trimethylstannyl)sodium, as described in ref 3.
10. 2 of argon was applied. When the control valve was opened for a short time, two solutions were mixed in the four-jet mixer and the mixture flowed into the monitor cell. Then, the time profile of absorption was measured by a combination of photomultiplier and digital oscilloscope.
11. Scaiano, J. C. J. Am. Chem. Soc., 1980, 102, 5399.
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13. Mochida, K.; Wakasa, M.; Sakaguchi, Y.; Hayashi, H. Chem. Lett. 1986, 1793.
14. Mochida, K.; Wakasa, M.; Sakaguchi, Y.; Hayashi, H Nippon Kagaku Kaishi 1987, 7, 1171.
15. RN1 reaction (Yammal, C. C.; Podesta, J. C.; Rossi, R. A. J. Org. Chem. 1992, 57, 5720):