The Mechanism of Bu3SnH-Mediated Homolytic Aromatic Substitution

Angewandte Chemie - International Edition

Volumn 43, Issue 1, 2004, Pages 95-98

  Beckwith, Athelstan L J ^a   Bowry, Vincent W ^a   Bowman, W Russell ^b   Mann, Emma ^b   Parr, Jonathan ^b   Storey, John M D ^c  

^a AUSTRALIAN NATIONAL UNIVERSITY   (Australia)

^b LOUGHBOROUGH UNIVERSITY   (United Kingdom)

^c UNIVERSITY OF ABERDEEN   (United Kingdom)

Author keywords

Azo compounds; Cyclization; Radical reactions; Radicals; Reaction mechanisms

Indexed keywords

RADICAL REACTIONS;

BROMINE COMPOUNDS; FREE RADICALS; HYDROGEN; SOLVENTS; SUBSTITUTION REACTIONS;

AROMATIC COMPOUNDS;

AROMATIC COMPOUND; AZOBISISOBUTYRONITRILE; HYDROGEN; OXINDOLE; POLYCYCLIC AROMATIC HYDROCARBON; RADICAL; SOLVENT; TIN; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL STRUCTURE; CYCLIZATION;

EID: 2442630750     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200352419     Document Type: Article

References (21)

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21. The fact that reactions with iodoarenes[5] have been reported to proceed with substoichiometric amounts of AIBN indicates an alternative mechanism involving SET or possibly C-I homolysis.