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Volumn 124, Issue 44, 2002, Pages 13215-13221

Structural isomers of aryl-substituted η3-propargyl complexes: η2-1-metalla(methylene)cyclopropene and η3-benzyl complexes

Author keywords

[No Author keywords available]

Indexed keywords

ISOMERIC COMPLEXES;

EID: 0037032245     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja020439m     Document Type: Article
Times cited : (20)

References (67)
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    • note
    • 3.
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    • note
    • This two step procedure was required, since the reaction of 2 with the propargyl alcohol gave intractable mixtures or very low yields.
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    • For examples of metal carbene protonations, see: (a) Casey, C. P.; Czerwinski, C. J.; Powell, D. R.; Hayashi, R. K. J. Am. Chem. Soc. 1997, 119, 5750. (b) Casey, C. P.; Vosejpka, P. C.; Askham, F. R. J. Am. Chem. Soc. 1990, 112, 3713. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079. (d) Hill, A. F.; Roper, W. R.; Waters. J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939. (e) Clark, G. R.; Roper, W. R.; Wright, A. H. J. Organomet. Chem. 1984, 273, C17.
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    • For examples of metal carbene protonations, see: (a) Casey, C. P.; Czerwinski, C. J.; Powell, D. R.; Hayashi, R. K. J. Am. Chem. Soc. 1997, 119, 5750. (b) Casey, C. P.; Vosejpka, P. C.; Askham, F. R. J. Am. Chem. Soc. 1990, 112, 3713. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079. (d) Hill, A. F.; Roper, W. R.; Waters. J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939. (e) Clark, G. R.; Roper, W. R.; Wright, A. H. J. Organomet. Chem. 1984, 273, C17.
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    • For examples of metal carbene protonations, see: (a) Casey, C. P.; Czerwinski, C. J.; Powell, D. R.; Hayashi, R. K. J. Am. Chem. Soc. 1997, 119, 5750. (b) Casey, C. P.; Vosejpka, P. C.; Askham, F. R. J. Am. Chem. Soc. 1990, 112, 3713. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079. (d) Hill, A. F.; Roper, W. R.; Waters. J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939. (e) Clark, G. R.; Roper, W. R.; Wright, A. H. J. Organomet. Chem. 1984, 273, C17.
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    • For examples of metal carbene protonations, see: (a) Casey, C. P.; Czerwinski, C. J.; Powell, D. R.; Hayashi, R. K. J. Am. Chem. Soc. 1997, 119, 5750. (b) Casey, C. P.; Vosejpka, P. C.; Askham, F. R. J. Am. Chem. Soc. 1990, 112, 3713. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079. (d) Hill, A. F.; Roper, W. R.; Waters. J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939. (e) Clark, G. R.; Roper, W. R.; Wright, A. H. J. Organomet. Chem. 1984, 273, C17.
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    • For examples of metal carbene protonations, see: (a) Casey, C. P.; Czerwinski, C. J.; Powell, D. R.; Hayashi, R. K. J. Am. Chem. Soc. 1997, 119, 5750. (b) Casey, C. P.; Vosejpka, P. C.; Askham, F. R. J. Am. Chem. Soc. 1990, 112, 3713. (c) Klein, D. P.; Bergman, R. G. J. Am. Chem. Soc. 1989, 111, 3079. (d) Hill, A. F.; Roper, W. R.; Waters. J. M.; Wright, A. H. J. Am. Chem. Soc. 1983, 105, 5939. (e) Clark, G. R.; Roper, W. R.; Wright, A. H. J. Organomet. Chem. 1984, 273, C17.
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    • note
    • Highly idealized phenyl and Cp* units were required for refinement. See Supporting Information for bond distance tables.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.