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Volumn 125, Issue 21, 2003, Pages 6366-6367

Catalytic alcoholysis of tetramethylsilane via Pt-mediated C-H bond activation

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; CARBON; HYDROGEN; PLATINUM; SILANE DERIVATIVE; TETRAMETHYLSILANE; UNCLASSIFIED DRUG;

EID: 0037500249     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja029099v     Document Type: Article
Times cited : (45)

References (36)
  • 4
    • 0037198618 scopus 로고    scopus 로고
    • and references therein
    • (d) Labinger, J. A.; Bercaw, J. E. Nature 2002, 417, 507-14 and references therein.
    • (2002) Nature , vol.417 , pp. 507-514
    • Labinger, J.A.1    Bercaw, J.E.2
  • 10
    • 12444340061 scopus 로고    scopus 로고
    • manuscript in preparation
    • 3 dissolves in TFE to afford an acidic solution capable of protonating 1 to release methane and form 2. Isotopic scrambling patterns are inconsistent with methide abstraction from 1. Heyduk, A. F.; Labinger, J. A.; Bercaw, J. E., manuscript in preparation.
    • Heyduk, A.F.1    Labinger, J.A.2    Bercaw, J.E.3
  • 11
    • 12444265075 scopus 로고    scopus 로고
    • note
    • -1.
  • 12
    • 12444327963 scopus 로고    scopus 로고
    • note
    • 3SiCl with TFE in the presence of base.
  • 13
    • 12444260947 scopus 로고    scopus 로고
    • note
    • 3] species (vide infra), we currently favor an initial, rate-determining C-H bond activation.
  • 14
    • 12444312196 scopus 로고    scopus 로고
    • note
    • 3.
  • 15
    • 12444255396 scopus 로고    scopus 로고
    • note
    • 2 and another equivalent of methane.
  • 16
    • 12444294642 scopus 로고    scopus 로고
    • note
    • 3 group.
  • 17
    • 12444311939 scopus 로고    scopus 로고
    • note
    • II cations of chelating nitrogen ligands reductive coupling has been proposed to be faster than alkane elimination, see refs 2c, 2e and 11.
  • 23
    • 12444324824 scopus 로고    scopus 로고
    • Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chicester, Chapter 15
    • For a review of silene reactivity with alcohols see: Sakuri, H. In The Chemistry of Organic Silicon Compounds; Rappoport, Z., Apeloig, Y., Eds.; Wiley: Chicester, 1998; Vol. 3, Chapter 15.
    • (1998) The Chemistry of Organic Silicon Compounds , vol.3
    • Sakuri, H.1
  • 35
    • 37049156006 scopus 로고
    • 2, see: Ruiz, J.; Maitlis, P. M. Chem. Commun. 1986, 862-863.
    • (1949) J. Chem Soc. , pp. 2755-2764
    • Eaborn, C.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.