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Volumn 44, Issue 20, 2005, Pages 3062-3067

Patterning through controlled submolecular motion: Rotaxane-based switches and logic gates that function in solution and polymer films

Author keywords

Fluorescence; Logic gates; Molecular devices; Rotaxanes; Solvent effects

Indexed keywords

ALUMINA; FLUORESCENCE; LOGIC GATES; MASKS; PLASTIC FILMS; QUARTZ; SOLUTIONS; SOLVENTS; VAPORS;

EID: 21044434147     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200500101     Document Type: Article
Times cited : (216)

References (53)
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    • note
    • Most shuttling mechanisms require a concomitant - and often major - change in the rotaxane primary structure (e.g. charge, oxidation state, protonation, etc). In the absence of clear controls, attributing the changes in property to the positional displacement of components rather than the change in the electronic nature or chemical composition of the molecule is not straightforward.
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    • A solvent-switchable shuttle system has been developed for polyrotaxanes by Gibson and co-workers: d) C. Gong, H. W. Gibson, Angew. Chem. 1997, 109, 2426-2428;
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    • note
    • [10] However, the relative position of the components (tertiary structure) is similar in each.
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    • w = 0.332. All hydrogen atoms on carbon atoms were placed in idealized fixed geometries. All hydrogen atoms on nitrogen atoms were located from a ΔF map and allowed to refine. CCDC-159773 contains the supplementary crystallographic data for this paper. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.
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    • Generated by using equation 12 in Ret. [15] (C. A. Hunter, personal communication)
    • Generated by using equation 12 in Ret. [15] (C. A. Hunter, personal communication).
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.