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(b) Special issue on Molecular Machines: Acc. Chem. Res. 2001, 34, 409-522.
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For systems where large-amplitude translational motion in a rotaxane architecture brings about a property change, see: (a) size/shape variation in a molecular "muscle": Jimenez-Molero, M. C.; Dietrich-Buchecker, C.; Sauvage, J.-P. Chem. Eur. J. 2002, 8, 1456-1466.
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Jimenez-Molero, M.C.1
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Sauvage, J.-P.3
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(b) Changes in conductivity: Collier, C. P.; Wong, E. W.; Bělohradský, M.; Raymo, F. M.; Stoddart, J. F.; Kuekes, P. J.; Williams, R. S.; Heath, J. R. Science 1999, 285, 391-394.
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Collier, C.P.1
Wong, E.W.2
Bělohradský, M.3
Raymo, F.M.4
Stoddart, J.F.5
Kuekes, P.J.6
Williams, R.S.7
Heath, J.R.8
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(c) Changes in circular dichroism: Bottari, G.; Leigh, D. A.; Pérez, E. M. J. Am. Chem. Soc. 2003, 125, 13360-13361.
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(a) Altieri, A.; Bottari, G.; Dehez, F.; Leigh, D. A.; Wong, J. K. Y.; Zerbetto, F. Angew. Chem., Int. Ed. 2003, 42, 2296-2300.
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(b) Bottari, G.; Dehez, F.; Leigh, D. A.; Nash, P. J.; Pérez, E. M.; Wong, J. K. Y.; Zerbetto, F. Angew. Chem., Int. Ed. 2003, 42, 5886-5889.
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Pérez, E.M.5
Wong, J.K.Y.6
Zerbetto, F.7
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0030761677
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For other light-switchable molecular shuttles, see: (a) Murakami, H.; Kawabuchi, A.; Kotoo, K.; Kunitake, M.; Nakashima, N. J. Am. Chem. Soc. 1997, 119, 7605-7606.
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Murakami, H.1
Kawabuchi, A.2
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Kunitake, M.4
Nakashima, N.5
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(b) Armaroli, N.; Balzani, V.; Collin, J. P.; Gaviña, P.; Sauvage, J. P.; Ventura, B. J. Am. Chem. Soc. 1999, 121, 4397-4408.
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Collin, J.P.3
Gaviña, P.4
Sauvage, J.P.5
Ventura, B.6
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(c) Brouwer, A. M.; Frochot, C.; Gatti, F. G.; Leigh, D. A.; Mottier, L.; Paolucci, F.; Roffia, S.; Wurpel, G. W. H. Science 2001, 291, 2124-2128.
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Brouwer, A.M.1
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Gatti, F.G.3
Leigh, D.A.4
Mottier, L.5
Paolucci, F.6
Roffia, S.7
Wurpel, G.W.H.8
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(d) Wurpel, G. W. H.; Brouwer, A. M.; van Stokkum, I. H. M.; Farran, A.; Leigh, D. A. J. Am. Chem. Soc. 2001, 123, 11327-11328.
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Wurpel, G.W.H.1
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Leigh, D.A.5
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(e) Stanier, C. A.; Alderman, S. J.; Claridge, T. D. W.; Anderson, H. L. Angew. Chem., Int. Ed. 2002, 41, 1769-1772.
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Stanier, C.A.1
Alderman, S.J.2
Claridge, T.D.W.3
Anderson, H.L.4
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13
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0343775673
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For an example of a positionally switchable fluorescent pseudorotaxane, see: Jun, S. I.; Lee, J. W.; Sakamoto, S.; Yamaguchi, K.; Kim, K. Tetrahedron Lett. 2000, 41, 471-475.
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Tetrahedron Lett.
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Jun, S.I.1
Lee, J.W.2
Sakamoto, S.3
Yamaguchi, K.4
Kim, K.5
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15
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4644329734
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note
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2 obscures part of the olefin region.
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17
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4644270835
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note
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j in Figure 3, a and b)].
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20
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3142711543
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After this manuscript was submitted, some fascinating light-switchable shuttles were reported in which a small change in the position of a cyclodextrin on a rotaxane thread changes the solvation sphere of a fluorophore stopper sufficiently to alter the fluorescence intensity by a ratio of ∼1.5:1 [Wang, Q.-C.; Qu, D.-H.; Ren, J.; Chen, K.; Tian, H. Angew. Chem., Int. Ed. 2004, 43, 2661-2665].
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Angew. Chem., Int. Ed.
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, pp. 2661-2665
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Wang, Q.-C.1
Qu, D.-H.2
Ren, J.3
Chen, K.4
Tian, H.5
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