Electrochemical addressing of the optical properties of a monolayer on a transparent conducting substrate

Angewandte Chemie - International Edition

Volumn 44, Issue 21, 2005, Pages 3237-3240

  Shukla, Atindra D ^a   Das, Amitava ^b   Van Der Boom, Milko E ^a  

^a WEIZMANN INSTITUTE OF SCIENCE   (Israel)

^b CSIR CENTRAL SALT AND MARINE CHEMICALS RESEARCH INSTITUTE   (India)

Author keywords

Molecular devices; Monolayers; Ruthenium; Switches; Thin films

Indexed keywords

DATA STORAGE EQUIPMENT; ELECTRIC POTENTIAL; HYDROPHILICITY; INDIUM COMPOUNDS; MONOLAYERS; OPTICAL PROPERTIES; REDOX REACTIONS; RUTHENIUM; SUBSTRATES; ULTRAVIOLET SPECTROPHOTOMETERS;

CHARGE STORAGE; CONDUCTING SUBSTRATES; ELECTROCHEMICAL CHARGE; HYDROPHILIC SUBSTRATES;

ELECTROCHEMISTRY;

EID: 20344397400     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461958     Document Type: Article

References (45)

1. a) A. Nitzan, M. A. Ratner, Science 2003, 300, 1384;
2. b) A. Salomon, D. Cahen, S. Lindsay, J. Tomfohr, V. B. Engelkes, C. D. Frisbie, Adv. Mater. 2003, 15, 1883;
3. c) M. E. van der Boom, Angew. Chem. 2002, 114, 3511;
4. Angew. Chem. Int. Ed. 2002, 41, 3363.
5. For examples of functional mono- and multilayers, see: a) P. Zhu, H. Kang, A. Facchetti, G. Evmenenko, P. Dutta, T. J. Marks, J. Am. Chem. Soc. 2003, 125, 11496;
6. b) T. van der Boom, G. Evmenenko, P. Dutta, M. R. Wasielewski, Chem. Mater. 2003, 15, 4068;
7. c) A. Facchetti, A. Abbotto, L. Beverina, M. E. van der Boom, P. Dutta, G. Evmenenko, T. J. Marks, G. A. Pagani, Chem. Mater. 2002, 14, 4996;
8. d) G. A. Neff, M. R. Helfrich, M. C. Clifton, C. J. Page, Chem. Mater. 2000, 12, 2363;
9. e) M. S. Johal, Y. W. Cao, X. D. Chai, L. B. Smilowitz, J. M. Robinson, T. J. Li, D. McBranch, D.-Q. Li, Chem. Mater. 1999, 11, 1962;
10. f) V. Burtman, A. Zelichenok, S. Yitzchaik, Angew. Chem. 1999, 111, 2078;
11. Angew. Chem. Int. Ed. 1999, 38, 2041;
12. g) A. Ulman, Chem. Rev. 1996, 96, 1533;
13. h) H. E. Katz, W. L. Wilson, G. Scheller, J. Am. Chem. Soc. 1994, 116, 6636.
14. Q. Li, G. Mathur, M. Homsi, S. Surthi, V. Misra, V. Malinovskii, K.-H. Schweikart, L. Yu, J. S. Lindsey, Z. Liu, R. B. Dabke, A. Yasseri, D. F. Bocian, W. G. Kuhr, Appl. Phys. Lett. 2002, 81, 1495.
15. a) Z. Liu, A. A. Yasseri, J. S. Lindsey, D. F. Bocian, Science 2003, 302, 1543;
16. b) R. L. Carroll, C. B. Gorman, Angew. Chem. 2002, 114, 4556;
17. Angew. Chem. Int. Ed. 2002, 41, 4378.
18. a) A. P. de Silva, D. B. Fox, T. S. Moody, S. M. Weir, Trends Biotechnol. 2001, 19, 27;
19. b) Molecular Switches (Ed.: B. L. Feringa), Wiley-VCH, Weinheim, 2001;
20. c) I. Willner, E. Katz, Angew. Chem. 2000, 112, 1230;
21. Angew. Chem. Int. Ed. 2000, 39, 1180;
22. d) special issue on "Photochromism: Memories and Switches": Chem. Rev. 2000, 100, 1683;
23. e) B. J. Coe, Chem. Eur. J. 1999, 5, 2464.
24. For an electrochemically driven metal-based switch in solution, see: D. Kalny, M. Elhabiri, T. Moav, A. Vaskevich, I. Rubinstein, A. Shanzer, A.-M. Albrecht-Gary, Chem. Commun. 2002, 1426.
25. a) G. Fabbrini, E. Menna, M. Maggini, A. Canazza, G. Marcolongo, M. Meneghetti, J. Am. Chem. Soc. 2004, 126, 6239;
26. b) J. T. M. Kennis, I. H. M. van Stokkum, S. Crosson, M. Gauden, K. Moffat, R. van Grondelle, J. Am. Chem. Soc. 2004, 126, 4512;
27. c) M. P. Debreczeny, W. A. Svec, M. R. Wasielewski, Science 1996, 274, 584;
28. d) L. Zelikovich, J. Libman, A. Shanzer, Nature 1995, 374, 790.
29. a) S. Yasutomi, T. Morita, Y. Imanishi, S. Kimura, Science 2004, 304, 1944;
30. b) M. J. Cook, A.-M. Nygård, Z. Wang, D. A. Russell, Chem. Commun. 2002, 10, 1056;
31. c) C. P. Collier, G. Mattersteig, E. W. Wong, Y. Luo, K. Beverly, J. Sampaio, F. M. Raymo, J. F. Stoddart, J. R. Heath, Science 2000, 289, 1172.
32. For chemical switching of the optical properties of a thiol-based monolayer on ultrathin Pt electrodes, see: S. Sortino, S. Petralia, S. Conoci, S. Di Bella, J. Am. Chem. Soc. 2004, 126, 1122.
33. [9] For examples of spectroelectrochemistry on noncovalently bound (adsorbed) organic films, see: a) D. R. Dunphy, S. B. Mendes, S. S. Saavedra, N. R. Armstrong, Anal. Chem. 1997, 69, 3086;
34. b) S. C. Paulson, C. M. Elliot, Anal. Chem. 1996, 68, 1711;
35. c) J. W. Perry, A. J. McQuillan, F. C. Anson, A. H. Zewail, J. Phys. Chem. 1983, 87, 1480;
36. d) for an example of spectroelectrochemistry on a multilayer based on electrostatic interactions, see: Z. Guo, Y. Shen, M. Wang, F. Zhao, S. Dong, Anal. Chem. 2004, 76, 184.
37. J. Lahann, S. Mitragotri, T.-N. Tran, H. Kaido, J. Sundaram, I. S. Choi, S. Hoffer, G. A. Somorjai, R. Langer, Science 2003, 299, 371.
38. A. J. Amoroso, A. Das, J. A. McCleverty, M. D. Ward, F. Barigelletti, L. Flamigni, Inorg. Chim. Acta 1994, 226, 171.
39. a) R. Yerushalmi, A. Scherz, M. E. van der Boom, J. Am. Chem. Soc. 2004, 126, 2700;
40. b) A. Gulino, P. Mineo, E. Scamporrino, D. Vitalini, I. Fragala, Chem. Mater. 2004, 16, 1838;
41. c) W. J. Dressick, M. S. Chen, S. L. Brandow, J. Am. Chem. Soc. 2000, 122, 982;
42. d) D.-Q. Li, B. I. Swanson, J. M. Robinson, M. A. Hoffbauer, J. Am. Chem. Soc. 1993, 115, 6975.
43. Monolayer characterization will be reported in a full paper; for details of the XPS and AFM instrumentation and analysis procedures, see: A. D. Shukla, D. Strawser, A. C. B. Lucassen, D. Freeman, H. Cohen, D. A. Jose, A. Das, G. Evmenenko, P. Dutta, M. E. van der Boom, J. Phys. Chem. B 2004, 8, 17505.
44. W. Lin, W. Lin, G. K. Wong, T. J. Marks, J. Am. Chem. Soc. 1996, 118, 8034.
45. Electrochemical Methods: Fundamentals and Applications, 2nd ed. (Eds.: A. J. Bard, L. R. Faulkner), Wiley, New York, 2001.