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12944303917
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note
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Increasing either the pyridine solution concentration or temperature led to faster ligand insertion rates into the films.
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26
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12944321621
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note
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19b accompanying the pyridine N(1s) signal at 399.8 eV. consistent with a lack of covalent binding in our system.
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27
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0029830949
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29
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12944309572
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note
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Ligand removal does not damage the ability of the nanocavity to rebind ligand, as expected for a physisorptive process. Reinsertion of pyridine or trimethylamine from ligand-depleted SAMs was verified by successful film metallization.
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12944336826
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