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Although higher solubility is obtainable in polar solvents, significant side reactions of the chromophore occur, which in turn result in multilayers with diminished structural regularity and second-order response. See: Yitzchaik, S.; Kakkar, A. K.; Roscoe, S. B.; Orihashi, Y.; Marks, T. J.; Lin, W.; Wong, G. K. Mol. Cryst. Liq. Cryst. 1994, 240, 9-16.
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If interlayer spacings and/or electron density profiles vary significantly from trilayer to trilayer, destructive interference will occur. Consequently, no Bragg diffraction peaks will be present in the X-ray reflectivity curves.
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