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The lattice constant is determined through a complex interplay between Mn concentration and the intricate defect structure inherent to these materials. One might suspect that, based on the x-ray data, the large x samples have essentially the same Mn concentration due to diffusion of excess Mn ions to the surface during annealing. We can exclude such a scenario since the EMPA measurements (performed at 3 kV) probe the average Mn concentration in roughly the top half of the (formula presented) epilayers. Since both as-grown and annealed samples give the same EMPA results within experimental uncertainty, it is unlikely that any significant diffusion of Mn ions toward the surface occurs during the annealing process. In addition, such an inhomogeneous distribution of Mn would result in the formation of ferromagnetic MnAs phases since the average Mn concentration is already close to the solubility limit of homogeneous (formula presented) Neither x-ray diffraction nor magnetization measurements indicate any detectable traces of MnAs
-
The lattice constant is determined through a complex interplay between Mn concentration and the intricate defect structure inherent to these materials. One might suspect that, based on the x-ray data, the large x samples have essentially the same Mn concentration due to diffusion of excess Mn ions to the surface during annealing. We can exclude such a scenario since the EMPA measurements (performed at 3 kV) probe the average Mn concentration in roughly the top half of the (formula presented) epilayers. Since both as-grown and annealed samples give the same EMPA results within experimental uncertainty, it is unlikely that any significant diffusion of Mn ions toward the surface occurs during the annealing process. In addition, such an inhomogeneous distribution of Mn would result in the formation of ferromagnetic MnAs phases since the average Mn concentration is already close to the solubility limit of homogeneous (formula presented) Neither x-ray diffraction nor magnetization measurements indicate any detectable traces of MnAs.
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