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2) intermemdiate. Insertion into the Pd-P bond is also possible: Wicht, D. K.; Kourkine, I. V.; Kovacik, I.; Glueck, D. S.; Concolino, T. E.; Yap, G. P. A.; Incarvito, C. D.; Rheingold, A. L. Organometallics 1999, 18, 5381.
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1542263103
-
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note
-
Abbreviations: dppe = bis(diphenylphosphino)ethane, dppp = bis(diphenylphosphino)propane, dppb = bis(diphenylphosphino)butane, dppf = bis(diphenylphosphino)ferrocene.
-
-
-
-
20
-
-
1542292953
-
-
note
-
The Cambridge Structural Database contains 142 entries which have palladium-methyl bonds; Pd-Me distances range from 1.946 to 2.189 Å.
-
-
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21
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0038553781
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