Dynamic Behavior of [Pd(C6F5)2(SPPynPh3-n)] Complexes: Evidence for a Turnstile Mechanism in Intramolecular Exchange

Inorganic Chemistry

Volumn 36, Issue 24, 1997, Pages 5428-5431

  Casares, Juan A ^a   Espinet, Pablo ^a  

^a UNIVERSITY OF VALLADOLID   (Spain)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001475469     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970749j     Document Type: Article

References (16)

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8. ortho by pairs cannot be reached in a 300 MHz apparatus (only broadening of the signals is observed at the highest temperature accessible), but it can be seen in an 80 MHz apparatus.
9. In another paper, we have shown that the direct inter-ring coupling between ortho-F nuclei on mutually cis fluoroaryl rings allows this asignment to be made: Albéniz, A. C.; Casado, A. L.; Espinet, P. Inorg. Chem., submitted for publication.
10. 2 Ph)], where the tridentate ligand takes three mer positions in an octahedral environment with little distortion of the ideal geometry: casares, J. A.; Espinet, P.; Hernando, R.; Iturbe, G.; Villafañe, F.; Ellis, D. D.; Orpen, A. G. Inorg. Chem. 1997, 36, 44.
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