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Volumn 21, Issue 15, 2002, Pages 3278-3284

Direct observation of P(O)-C bond formation from (N down curve sign N)PdMe(P(O)(OPh)2) complexes. Rate enhancement of reductive elimination by addition of triarylphosphines

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; CRYSTALLOGRAPHY; HEATING; SOLUTIONS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

EID: 0038006287     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om0202118     Document Type: Article
Times cited : (38)

References (76)
  • 26
    • 33947460536 scopus 로고    scopus 로고
    • Quin, L. D., Ed.; Wiley-Interscience: New York
    • Alkyl and aryl phosphonates are typically prepared by the Arbusov reaction: A Guide to Organophosphorus Chemistry; Quin, L. D., Ed.; Wiley-Interscience: New York, 2000. The radical hydrophosphorylation of olefins is also known: Stiles, A. R.; Vaughan, W. E.; Rust, F. F. J. Am. Chem. Soc. 1958, 80, 714.
    • (2000) A Guide to Organophosphorus Chemistry
  • 27
    • 33947460536 scopus 로고    scopus 로고
    • Alkyl and aryl phosphonates are typically prepared by the Arbusov reaction: A Guide to Organophosphorus Chemistry; Quin, L. D., Ed.; Wiley-Interscience: New York, 2000. The radical hydrophosphorylation of olefins is also known: Stiles, A. R.; Vaughan, W. E.; Rust, F. F. J. Am. Chem. Soc. 1958, 80, 714.
    • (1958) J. Am. Chem. Soc. , vol.80 , pp. 714
    • Stiles, A.R.1    Vaughan, W.E.2    Rust, F.F.3
  • 34
    • 0000457763 scopus 로고    scopus 로고
    • Other examples of structurally characterized organometallic complexes (non-Cp) include the following. Ruthenium carbene complexes: (a) Leung, W. H.; Chan, E. E. Y.; Williams, I. D.; Wong, W. T. Organometallics 1997, 16, 3234.
    • (1997) Organometallics , vol.16 , pp. 3234
    • Leung, W.H.1    Chan, E.E.Y.2    Williams, I.D.3    Wong, W.T.4
  • 47
    • 0037877454 scopus 로고    scopus 로고
    • 8 at 110 °C
    • 8 at 110 °C.
  • 48
    • 0037539476 scopus 로고    scopus 로고
    • note
    • The fluxional process displayed by treatment of 1-3 with various phosphine ligands is currently under investigation and will be presented shortly.
  • 49
    • 0038214944 scopus 로고    scopus 로고
    • note
    • The fate of the palladium has not been determined in these reactions.
  • 73
    • 0037877455 scopus 로고    scopus 로고
    • note
    • 2) is less likely.
  • 76
    • 0038214945 scopus 로고    scopus 로고
    • note
    • All software and sources of the scattering factors are contained in the SHELXTL (version 5.1) program library (G. Sheldrick, Bruker Analytical X-ray Systems, Madison, WI).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.