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Volumn 42, Issue 20, 2003, Pages 6575-6583

Regulation of geometry around the ruthenium center of Bis(2-pyridinecarboxylato) complexes by the nitrosyl moiety: Syntheses, structures, and theoretical studies

Author keywords

[No Author keywords available]

Indexed keywords

ALCOHOL; CARBOXYL GROUP; CHLORINE DERIVATIVE; COORDINATION COMPOUND; HYDROCHLORIC ACID; LIGAND; NITRO DERIVATIVE; NITROGEN DERIVATIVE; OXYGEN DERIVATIVE; PYRIDINE DERIVATIVE; RUTHENIUM COMPLEX; WATER;

EID: 0141870045     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0344261     Document Type: Article
Times cited : (23)

References (50)
  • 8
    • 0036545820 scopus 로고    scopus 로고
    • and references therein
    • (f) Nagano, T.; Yoshimura, T. Chem. Rev. 2002, 102, 1235-1269 and references therein.
    • (2002) Chem. Rev. , vol.102 , pp. 1235-1269
    • Nagano, T.1    Yoshimura, T.2
  • 13
    • 0001447384 scopus 로고
    • Geoffroy, G. L., Ed.: John Wiley and Sons: New York
    • (a) Feltham, R. D.; Enemark, J. H. In Topics in Stereochemistry; Geoffroy, G. L., Ed.: John Wiley and Sons: New York, 1981; Vol. 12, pp 155-215.
    • (1981) Topics in Stereochemistry , vol.12 , pp. 155-215
    • Feltham, R.D.1    Enemark, J.H.2
  • 39
    • 0141657689 scopus 로고    scopus 로고
    • note
    • 3OH; the methyl carbon atom of the methanol of crystallization is located at a special position, and the hydroxyl oxygen atom of the methanol is at a general position with an occupancy of 0.5. Hydrogen atoms of this methanol molecule are not included in the final refining cycle. These carbon and oxygen atoms can be distinguished by the O-H⋯O hydrogen bonds between the oxygen atom of the methanol molecule and the oxygen atom (O2) of the coordinated methoxo ligand (2,629(7) Å) and between the oxygen atom of the methanol and the carboxylic oxygen atoms (O3 and O4) of the pyca ligand (3.424(8) and 3,556(9) Å).
  • 48
    • 4243902240 scopus 로고    scopus 로고
    • Johns Hopkins University Press: Baltimore, MD
    • All the trans-pair contributions are not linearly independent. However, one can still perform the least-squares fitting by the use of singular vector decomposition. See for instance: Golub, G. H.; van Loan, C. F. Matrix, 3rd ed.; Johns Hopkins University Press: Baltimore, MD, 1996; p 582.
    • (1996) Matrix, 3rd Ed. , pp. 582
    • Golub, G.H.1    Van Loan, C.F.2
  • 50
    • 0141769665 scopus 로고    scopus 로고
    • note
    • One is the facial isomer in which three chloro ligands coordinate in a facial configuration, the second one is the meridional isomer in which three chloro ligands coordinate in a meridional configuration and the nitrosyl ligand is at the trans position to the pyridyl nitrogen, and the third one is another meridional isomer in which three chloro ligands coordinate in a meridional configuration and the nitrosyl ligand is at the trans position to the carboxylic oxygen atom of the pyca ligand.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.