Electron transfer in self-assembled inorganic polyelectrolyte/metal nanoparticle heterostructures

Journal of the American Chemical Society

Volumn 118, Issue 32, 1996, Pages 7640-7641

  Feldheim, Daniel L ^a   Grabar, Katherine C ^a   Natan, Michael J ^a   Mallouk, Thomas E ^a  

^a PENNSYLVANIA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

NANOPARTICLE;

ARTICLE; ELECTRON TRANSPORT; THEORY;

EID: 0029784124     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja9612007     Document Type: Article

References (54)

1. (a) Ozin, G. A. Adv. Mater. 1992, 4, 612.
2. (b) Mann, S. J. Mater. Chem. 1995, 5, 935.
3. (c) Lakes, R. Nature 1993, 361, 511.
4. (d) Spaepen, F. Science 1987, 23, 1010.
5. (e) Bard, A. J. Integrated Chemical Systems; John Wiley & Sons; New York, 1994.
6. (f) Whitesides, G. M.; Mathias, J. P.; Seto, C. T. Science 1991, 254, 1312.
7. (a) Panunto, T. W; Urbanczyk-Lipkowska, Z; Johnson, R.; Etter, M. C. J. Am. Chem. Soc. 1987, 109, 7786.
8. (b) Marsh, A.; Nolen, E. G.; Gardinier, K. M.; Lehn, J.-M. Tetrahedron Lett. 1994, 35, 279.
9. (c) Gallant, M.; Viet, M. T. P.; Wuest, J. D. J. Org. Chem. 1991, 56, 2284.
10. (d) Whitesell, J. K.; Davis, R. E.; Wong, M.-S.; Chang, N.-L. J. Am. Chem. Soc. 1994, 116, 523.
11. (e) Simard, M.; Su, D.; J. Am. Chem. Soc. 1991, 113, 4696.
12. (f) Seto, C. T.; Whitesides, G. M. J. Am. Chem. Soc. 1990, 112, 2440.
13. (g) Mathias, J. P.; Seto, C. T.; Simanek, E. E.; Whitesides, G. M. J. Am. Chem. Soc. 1994, 116, 1725.
14. (a) Mehrotra, V.; Giannelis, E. P. Solid State Comm. 1991, 77, 155.
15. (b) Feldheim, D. L.; Mallouk, T. E. Submitted for publication,
16. (c) Cao, G.; Mallouk, T. E. J. Solid State Chem. 1991, 94, 59.
17. (d) Thompson, M. E. Chem. Mater. 1994, 6, 1168.
18. (e) Kanatzidas, M. G.; Wu, C.-G.; Marcy, H. O. Chem. Mater. 1990, 2 (3), 222.
19. (f) Kanatzidas, M. G.; Bissessur, R., DeGroot, D. C. Chem. Mater. 1993, 5 (3), 595.
20. (a) Snover, J. L.; Thompson, M. E. J. Am. Chem. Soc. 1994, 116, 756.
21. (b) Lee, H., Kepley, L. J.; Hong, H.-G., Mallouk, T. E. J. Am. Chem. Soc. 1988, 110, 618.
22. (c) Cao, G.; Hong, H.-G.; Mallouk, T. E. Acc. Chem. Res. 1992, 25, 420.
23. (d) Putvinski, T. M.; Schilling, M. L.; Katz, H. E.; Chidsey, C. E. D.; Mujsce, A. M.; Emerson, A. B. Langmuir 1990, 6, 1567.
24. (e) Katz, H. E.; Schilling, M. L.; Chidsey, C. E. D.; Putvinski, T. M.; Hutton, R. S. Chem. Mater. 1991, 3, 699.
25. (a) Schmitt, J.; Decher, G.; Dressick, W. J.; Brandow, S. L.; Geer, R. E.; Shashidhar, R.; Calvert, J. M. Submitted for publication.
26. (b) Kleinfeld, E. R.; Ferguson, G. S. Science 1994, 265, 370.
27. (c) Ferreira, M.; Rubner, M. F. Macromolecules 1995, 28, 7107.
28. (d) Decher, G.; Hong, J. D.; Schmitt, J. Thin Solid Films 1992, 210/211, 831.
29. (e) Keller, S. W.; Kim, H. N.; Mallouk, T. E. J. Am. Chem. Soc. 1994, 116, 8817.
30. (f) Hong, J. D.; Lowack, K.; Schmitt, J.; Decher, G. Prog. Colloid Polym. Sci. 1993, 93, 98.
31. (g) Kaschak, D. M.; Mallouk, T. E. J. Am. Chem. Soc. 1996, 118, 4222.
32. (a) Dorogi, M.; Gomez, J.; Osifchin, R.; Andres, R. P.; Reifenberger, R. Phys. Rev. B 1995, 52, 9071.
33. (b) Amman, M.; Field, S. B.; Jaklevic, R. C. Phys. Rev. B. 1993, 48, 12104.
34. (c) Fulton, T. A.; Dolan, G. J. Phys. Rev. Lett. 1987,59, 109.
35. (d) Amman, M.; Wilkins, R.; Ben-Jacob, E.; Maker, P. D.; Jaklevic, R. C. Phys. Rev. B. 1991, 43, 1146.
36. (e) Krans, J. M.; van Ruitenbeek, J. M.; Fisun, V. V.; Yanson, I. K.; de Jongh, L. J. Nature 1995, 375, 767.
37. (f) Averin, D. V.; Likharev, K. K. J. Low Temp. Phys. 1986, 62, 345.
38. (g) Ashoori, R. C.; Stormer, H. L.; Weiner, J. S.; Pfeiffer, L. N.; Pearton, S. J.; Baldwin, K. W.; West, K. W. Phys. Rev. Lett. 1992, 68, 3088.
39. (h) Mullen, K.; Ben-Jacob, E.; Jaklevic, R. C.; Schuss, Z. Phys. Rev. B 1988, 37, 98.
40. (i) Barner, J. B.; Ruggerio, S. T. Phys. Rev. Lett. 1987, 59, 807.
41. (j) Osifchin, R. G.; Mahoney, W.; Andres, R. P.; Dorogi, M.; Reifenberger, R. G.; Feng, S.; Henderson, J. I.; Bein, T.; Kubiak, C. P. Polym. Mater. Sci. Eng. 1995, 73, 208.
42. (k) Single Charge Tunneling; Grabert, H.; Devoret, M. H., Eds.; NATO ASI Series B; Plenum Press: New York, 1991; Vol. 294.
43. (l) Raven, M. S. Phys. Rev. B 1984, 29, 6218.
44. (m) Andres, R. P.; Bein, T.; Dorogi, M.; Feng, S.; Henderson, J. I.; Kubiak, C. P.; Mahoney, W.; Osifchin, R. G.; Refenberger, R. Science 1996, 272, 1323.
45. (a) Grabar, K. C.; Smith, P. C.; Musick, M. D.; Davis, J. A.; Walter, D. G.; Jackson, M. A.; Guthrie, A. P.; Natan, M. J. J. Am. Chem. Soc. 1996, 118, 1148.
46. (b) Grabar, K. C.; Allison, K. J.; Baker, B. E.; Bright, R. M.; Brown, K. R.; Freeman, R. G.; Fox, A. P.; Keating, C. D.; Musick, M. D.; Natan, M. J. Langmuir, in press.
47. 2-coated glass substrates.
48. 2OH.
49. i-V curves were acquired with a Princeton Applied Research Model 173 potentiostat and MacLab electrochemical software version 1.3.
50. This is an important result since polypyrrole has been shown previously to act as an ohmic, non-ohmic, or rectifying contact depending on the polymerization conditions, film thickness, conductivity, etc. See for example: Inganas, O.; Lundstrom, I. Synth. Met. 1984, 10, 5.
51. Calculated using a film dielectric constant of 3.0; see: Kepley, L. J.; Sackett, D. D.; Bell, C. M.; Mallouk, T. E. Thin Solid Films 1992, 208, 132.
52. (a) Terrill, R. H.; Postlewaite, T. A.; Chen, C.-H., Poon, C. D.; Terzis, A.; Chen, A.; Hutchison, J. E.; Clark, M. R.; Wignall, G.; Londono, J. D.; Superfine, R.; Falvo, M.; Johnson, C. S., Jr.; Samulski, E. T.; Murray, R. W. J. Am. Chem. Soc. 1995, 117, 12537.
53. (b) Hostetler, M. J.; Green, S. J.; Stokes, J. J.; Murray, R. W. J. Am. Chem. Soc. 1996, 118, 4212.
54. Somorjai, G. A. Introduction To Surface Chemistry and Catalysis: John Wiley & Sons. Inc.: New York, 1994; p 382.