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Volumn , Issue 2, 2003, Pages 194-195

An anionic organic mixed-valence system with a remarkably well-resolved vibrational structure in its intervalence band

Author keywords

[No Author keywords available]

Indexed keywords

ANION; BORINIC ACID DERIVATIVE; ORGANIC COMPOUND;

EID: 0037242057     PISSN: 13597345     EISSN: None     Source Type: Journal    
DOI: 10.1039/b210429f     Document Type: Article
Times cited : (28)

References (30)
  • 1
    • 0003975627 scopus 로고
    • Academic Publishers, Dordrecht
    • Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology and Biology, ed. D. B. Brown, Academic Publishers, Dordrecht, 1980; Mixed Valency Systems. Applications in Chemistry, Physics and Biology, ed. K. Prassides, Kluwer Academic Publishers, Dordrecht, 1991; K. D. Demadis, C. M. Hartshorn and T. J. Meyer, Chem. Rev., 2001, 101, 2655; R. D. Cannon and R. P. White, Prog. Inorg. Chem., 1988, 36, 195.
    • (1980) Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology and Biology
    • Brown, D.B.1
  • 2
    • 0003740824 scopus 로고
    • Kluwer Academic Publishers, Dordrecht
    • Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology and Biology, ed. D. B. Brown, Academic Publishers, Dordrecht, 1980; Mixed Valency Systems. Applications in Chemistry, Physics and Biology, ed. K. Prassides, Kluwer Academic Publishers, Dordrecht, 1991; K. D. Demadis, C. M. Hartshorn and T. J. Meyer, Chem. Rev., 2001, 101, 2655; R. D. Cannon and R. P. White, Prog. Inorg. Chem., 1988, 36, 195.
    • (1991) Mixed Valency Systems. Applications in Chemistry, Physics and Biology
    • Prassides, K.1
  • 3
    • 0035470233 scopus 로고    scopus 로고
    • Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology and Biology, ed. D. B. Brown, Academic Publishers, Dordrecht, 1980; Mixed Valency Systems. Applications in Chemistry, Physics and Biology, ed. K. Prassides, Kluwer Academic Publishers, Dordrecht, 1991; K. D. Demadis, C. M. Hartshorn and T. J. Meyer, Chem. Rev., 2001, 101, 2655; R. D. Cannon and R. P. White, Prog. Inorg. Chem., 1988, 36, 195.
    • (2001) Chem. Rev. , vol.101 , pp. 2655
    • Demadis, K.D.1    Hartshorn, C.M.2    Meyer, T.J.3
  • 4
    • 0000450936 scopus 로고
    • Mixed-Valence Compounds: Theory and Applications in Chemistry, Physics, Geology and Biology, ed. D. B. Brown, Academic Publishers, Dordrecht, 1980; Mixed Valency Systems. Applications in Chemistry, Physics and Biology, ed. K. Prassides, Kluwer Academic Publishers, Dordrecht, 1991; K. D. Demadis, C. M. Hartshorn and T. J. Meyer, Chem. Rev., 2001, 101, 2655; R. D. Cannon and R. P. White, Prog. Inorg. Chem., 1988, 36, 195.
    • (1988) Prog. Inorg. Chem. , vol.36 , pp. 195
    • Cannon, R.D.1    White, R.P.2
  • 26
    • 0032569190 scopus 로고    scopus 로고
    • note
    • We note that, while several recent studies have demonstrated the ability of DFT to reproduce adequately the electronic structure and potential energy surfaces of strongly coupled mixed-valence systems (e.g. V. Barone, A. Bencini, I. Ciofini, C. A. Daul and F. Totti, J. Am. Chem. Soc., 1998, 120, 8357), in the case of weakly coupled systems DFT calculations can result in an overstabilization of delocalized states and calculations at a multiconfigurational level might then be required.
  • 27
    • 0012676423 scopus 로고    scopus 로고
    • note
    • The difference in the excited-state energies of the syn- and anti-conformers is about 0.02 eV; for each conformer, the excited-state dipole moment is similar to that for the ground state.
  • 28
    • 0037055014 scopus 로고    scopus 로고
    • note
    • A similar procedure is commonly used to derive the reorganization energy from photoelectron spectroscopy measurements (e.g. N. E. Gruhn, D. A. da Silva Filho, T. G. Bill, M. Malagoli, V. Coropceanu, A. Kahn and J.-L. Brédas,J. Am. Chem. Soc., 2002, 124, 7918).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.