Toposelective and chiroselective self-assembly of [2 x 2] grid-type inorganic arrays containing different octahedral metallic centers

Angewandte Chemie - International Edition

Volumn 37, Issue 17, 1998, Pages 2364-2367

  Bassani, Dario M ^a   Lehn, Jean Marie ^a   Fromm, Katharina ^a   Fenske, Dieter ^a  

^a UNIVERSITÉ LOUIS PASTEUR   (France)

Author keywords

Coordination chemistry; Multinuclear complexes; N ligands; Supramolecular chemistry; Transition metals

Indexed keywords

EID: 0032544493     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19980918)37:17<2364::AID-ANIE2364>3.0.CO;2-7     Document Type: Article

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21. Details of the synthesis and physical properties of the complexes will be published elsewhere. The analytical and spectral properties of the new compounds are in agreement with their structures.
22. -3. Owing to the presence of both enantiomers, the metal positions were calculated as a 1:1 mixture of Fe and Ru, which led to a centrosym-metric space group. The whole cationic structure was refined isotropically. All atoms in rings (except for central pyrimidines) are calculated as pertaining to a regular hexagon. The solvent and anionic parts of the structure show severe disorder and were refined isotropically on split positions except for the chlorine anions, which were refined anisotropically. All hydrogen positions are calculated. Crystallographic data (excluding structure factors) for the structure reported in this paper have been deposited with the Cambridge Crystallographic Data Center as supplementary publication no. CCDC-101 633. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (-44)1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
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