Exploiting incommensurate symmetry numbers: Rational design and assembly of M2M′3L6 supramolecular clusters with C3h symmetry

Angewandte Chemie - International Edition

Volumn 38, Issue 9, 1999, Pages 1303-1307

  Sun, Xiankai ^b   Johnson, Darren W ^a   Caulder, Dana L ^a   Powers, Ryan E ^a   Raymond, Kenneth N ^a   Wong, Edward H ^b  

^a UNIVERSITY OF CALIFORNIA   (United States)

^b University of New Hampshire   (United States)

Author keywords

Cluster compounds; Hybrid ligands; Supramolecular chemistry; Transition metals

Indexed keywords

LIGAND; METAL;

ARTICLE; CHEMICAL ANALYSIS; CHEMICAL BINDING; CHEMICAL STRUCTURE; COMPUTER MODEL; MOLECULAR INTERACTION; STEREOCHEMISTRY; STRUCTURE ANALYSIS; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

EID: 0033519350     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(19990503)38:9<1303::AID-ANIE1303>3.0.CO;2-8     Document Type: Article

References (73)

1. J. Lu, T. Paliwala, S. C. Lim, C. Yu, T. Niu, A. J. Jacobson, Inorg. Chem. 1997, 36, 923.
2. O. M. Yaghi, H. Li, T. L. Groy, Inorg. Chem. 1997, 36, 4292.
3. O. Crespo, M. C. Gimeno, P. G. Jones, A. Laguna, C. Sarroca, Chem. Commun. 1998, 1481.
4. R. K. Kumar, S. Balasubramanian, I. Goldberg, Chem. Commun. 1998, 1435.
5. T. F. Magnera, L. M. Peslherbe, E. Körblová, J. Michl, J. Organomet. Chem. 1997, 548, 83.
6. B. F. Abrahams, B. F. Hoskins, J. Liu, R. Robson, J. Am. Chem. Soc. 1991, 113, 3045.
7. M. J. Zaworotko, Chem. Soc. Rev. 1994, 283.
8. S. Roche, C. Haslam, H. Adams, S. L. Heath, J. A. Thomas, Chem. Commun. 1998, 1681.
9. J. L. Heinrich, P. A. Berseth, J. R. Long, Chem. Commun. 1998, 1231.
10. K. K. Klausmeyer, T. B. Rauchfuss, S. R. Wilson, Angew. Chem. 1998, 110, 1808;
11. Angew. Chem. Int. Ed. 1998, 37, 1694.
12. M. Albrecht, S. J. Franklin, K. N. Raymond, Inorg. Chem. 1994, 33, 5785.
13. T. Beissel, R. E. Powers, K. N. Raymond, Angew. Chem. 1996, 108, 1166;
14. Angew. Chem. Int. Ed. Engl. 1996, 35, 1084.
15. A. Bilyk, M. M. Harding, J. Chem. Soc. Chem. Commun. 1995, 1697.
16. P. D. W. Boyd, M. Gerloch, G. M. Sheldrick, J. Chem. Soc. Dalton Trans. 1974, 1097.
17. D. L. Caulder, K. N. Raymond, Angew. Chem. 1997, 109, 1508;
18. Angew. Chem. Int. Ed. Engl. 1997, 36, 1439.
19. L. J. Charbonniere, G. Bernardinelli, C. Piguet, A. M. Sargeson, A. F. Williams, J. Chem. Soc. Chem. Commun. 1994, 1419.
20. E. C. Constable, M. J. Hannon, and D. A. Tocher, J. Chem. Soc. Dalton Trans. 1993, 1883.
21. E. C. Constable, M. J. Hannon, A. J. Edwards, P. R. Raithby, J. Chem. Soc. Dalton Trans. 1994, 2669.
22. E. J. Enemark, T. D. P. Stack, Angew. Chem. 1995, 107, 1082;
23. Angew. Chem. Int. Ed. Engl. 1995, 34, 996.
24. M. Fujita, D. Oguro, M. Miyazawa, H. Oka, K. Yamaguchi, K. Ogura, Nature 1995, 378, 469.
25. D.-P. Funeriu, Y.-B. He, H.-J. Bister, J.-M. Lehn, Bull. Soc. Chim. Fr. 1996, 133, 673.
26. T. M. Garret, U. Koert, J.-M. Lehn, A. Rigault, D. Meyer, J. Fischer, J. Chem. Soc. Chem. Commun. 1990, 557.
27. P. Jacopozzi, E. Dalcanale, Angew. Chem. 1997, 109, 665;
28. Angew. Chem. Int. Ed. Engl. 1997, 36, 613.
29. B. Kersting, M. Meyer, R. E. Powers, K. N. Raymond, J. Am. Chem. Soc. 1996, 118, 7221.
30. U. Koert, M. M. Harding, J.-M. Lehn, Nature 1990, 346, 339.
31. J.-M. Lehn, A. Rigault, Angew. Chem. 1988, 100, 1121;
32. Angew. Chem. Int. Ed. Engl. 1988, 27, 1095.
33. J.-M. Lehn, P. Baxter, A. DeCian, J. Fischer, Angew. Chem. 1993, 105, 92;
34. Angew. Chem. Int. Ed. Engl. 1993, 32, 69.
35. R. W. Saalfrank, A. Stark, M. Bremer, H. Hummel, Angew. Chem. 1990, 102, 292;
36. Angew. Chem. Int. Ed. Engl. 1990, 29, 311.
37. R. W. Saalfrank, B. Horner, D. Stalke, J. Salbeck, Angew. Chem. 1993, 105, 1223;
38. Angew. Chem. Int. Ed. Engl. 1993, 32, 1179.
39. P. J. Stang, D. H. Cao, S. Saito, A. M. Arif, J. Am. Chem. Soc. 1995, 117, 6273.
40. M. Meyer, B. Kersting, R. E. Powers, K. N. Raymond, Inorg. Chem. 1997, 56, 5179.
41. J. Xu, T. Parac, K. N. Raymond, unpublished results.
42. D. L. Caulder, R. E. Powers, T. Parac, K. N. Raymond, Angew. Chem. 1998, 110, 1940;
43. Angew. Chem. Int. Ed. 1998, 37, 1840.
44. T. Beissel, R. E. Powers, T. N. Parac, K. N. Raymond, J. Am. Chem. Soc. 1999, in press.
45. T. Parac, D. L. Caulder, K. N. Raymond, J. Am. Chem. Soc. 1998, 120, 8003.
46. C. Brückner, R. E. Powers, K. N. Raymond, Angew. Chem. 1998, 110, 1937;
47. Angew. Chem. Int. Ed. 1998, 37, 1837.
48. K. N. Raymond, D. L. Caulder, R. E. Powers, T. Beissel, M. Meyer, B. Kersting, Chem. Res. 1996, 40, 115
49. (Proc. of the 40th Robert A. Welch Found.).
50. I metal-ligand interaction as the twofold axis to drive the assembly of the desired cluster.
51. C G. Pierpoint, R. M. Buchanan, Coord. Chem. Rev. 1981, 38, 45.
52. C. G. Pierpoint, C. W. Lange, Inorg. Chem. 1994, 41, 331.
53. C. A. McAuliffe in Comprehensive Coordination Chemistry, Vol. 2 (Eds.: G. Wilkinson, F. G. A. Stone, F. W. Abel), Pergamon, Oxford, 1987, chap. 14.
54. W. Levason in The Chemistry of Organophosphorus Compounds, Vol. 1 (Ed.: F. R. Hartley), Wiley, New York, 1990, chap. 16.
55. A. M. Abdou, Y. O. El-Khoshnieh, A. A. Kamel, J. Chem. Res. Synop. 1996, 326.
56. F. Ramirez, Pure Appt. Chem. 1964, 9, 337.
57. F. Ramirez, D. Rhum, C. P. Smith, Tetrahedron 1965, 21, 1941.
58. S. B. Sembering, S. B. Colbran, D. C. Craig, Inorg. Chem. 1995, 34, 761.
59. S. B. Sembering, S. B. Colbran, D. C. Craig, M. L. Scudder, J. Chem. Soc. Dalton Trans. 1995, 3731.
60. S. Ernst, P. Hanel, J. Jordanov, W. Kaim, V. Kasack, E. Roth, J. Am. Chem. Soc. 1989, 111, 1733.
61. CAChe Version 4.0, Oxford Molecular Group, Inc., USA, 1997.
62. 2-1 as a HBr salt.
63. Reactions were performed in methanol in the presence of cesium carbonate as the base. Satisfactory CHN analytical data and spectral data were obtained for all complexes.
64. 3] shows it to be the mer isomer: X. Sun, D. W. Johnson, D. L. Caulder, R. E. Powers, K. N. Raymond, E. H. Wong, unpublished results.
65. P. S. Pregosin, R. W. Kunz, 31P and 13C NMR of Transition Metal Phosphine Complexes, Springer, New York, 1979, p. 89.
66. 2)/3.
67. 2).
68. R. D. Shannon, Acta. Crystallogr. Sect. A 1976, 32, 751.
69. SMART, Area Detector Software Package, Siemens Industrial Automation, Inc., Madison, 1995.
70. SAINT, SAX Area Detector Integration Program, 4.024, Siemens Industrial Automation, Inc., Madison, 1995.
71. G. Sheldrick, SHELXTL Crystal Structure Determination Software Package, Siemens Industrial Automation, Inc., Madison, 1993.
72. G. Sheldrick, SADABS, Siemens Area Detector ABSorption Correction Program, Advanced Copy, 1996 (Personal Communication).
73. teXsan, Crystal Structure Analysis Package, Molecular Structure Corporation, The Woodlands, TX, 1992.