Mono- and Bimetallic Bipyridyl Polyene Complexes Containing 17-Electron Molybdenum Mononitrosyl Centers: Electrochemical, Spectroscopic, and Magnetic Studies

Inorganic Chemistry

Volumn 35, Issue 3, 1996, Pages 760-774

  McWhinnie, Sean L W ^a,g   Thomas, James A ^a   Hamor, Thomas A ^a   Jones, Christopher J ^a   McCleverty, Jon A ^b   Collison, David ^c   Mabbs, Frank E ^c   Harding, Charlie J ^d   Yellowlees, Lesley J ^e   Hutchings, Michael G ^f  

^a UNIVERSITY OF BIRMINGHAM   (United Kingdom)

^b UNIVERSITY OF BRISTOL   (United Kingdom)

^c UNIVERSITY OF MANCHESTER   (United Kingdom)

^d OPEN UNIVERSITY   (United Kingdom)

^e UNIVERSITY OF EDINBURGH   (United Kingdom)

^f ASTRAZENECA   (United Kingdom)

^g BRUNEL UNIVERSITY   (United Kingdom)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0000285164     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic950358+     Document Type: Article

References (84)

1. Inorganic Materials; Bruce, D. W., O'Hare, D., Eds.; Wiley, Chichester, U.K., 1992.
2. (a) Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247-422.
3. (b) Allen, G. C.; Hush, N. S. Prog. Inorg Chem. 1967, 8, 357-390.
4. (c) Hush, N. S. Prog. Inorg Chem. 1967, 8, 391-444.
5. (d) Meyer, T. J. Prog. Inorg. Chem. 1983, 30, 389-440.
6. (e) Clark, R. J. H. Chem. Soc. Rev. 1984, 13, 219-244.
7. (f) Meyer, T. J.; Taube, H. In Comprehensive Coordination Chemistry; Wilkinson, G., Gillard, R. D., McCleverty, J. A., Eds.; Pergamon: Oxford, U.K., 1987; Vol. 1, Chapter 7.2, pp 331-384.
8. Creutz, C. Prog. Inorg. Chem 1983, 30, 1-73.
9. (a) Marder, S. R. in ref 1.
10. (b) Green, M. L. H.; Marder, S. R.; Thompson, M. E.; Bandy, J. A.; Bloor, D.; Kolinsky, P. V.; Jones, R. J. Nature 1987, 330, 360-362.
11. Coe, B. J.; Jones, C. J.; McCleverty, J. A.; Bloor, D.; Kolinsky, P. V.; Jones, R. J. J. Chem. Soc., Chem Commun. 1990, 940-943.
12. (a) Stumpf, H. O., Ouahab, L.; Pei, Y.; Grandjean, D.; Kahn, O. Science 1993, 267, 447-449.
13. (b) Miller, J S.; Epstein, A. J.; Rieft, W. M. Chem. Rev. 1988, 88, 201-220.
14. Prasad, P. N.; Williams, D. J. Introduction to Non-Linear Optical Effects in Molecules and Polymers; Wiley: New York, 1991; Chapter 10. p 238.
15. (a) Lehn, J.-M. In Non-Linear Optical Properties of Organic Molecules and crystals; Chemla, D. S., Zyss, J., Eds.; Academic Press: New York, 1987; Vol. 2, p 215-220.
16. (b) Effenburger, F.; Schloser, H.; Bauerle, P ; Maier, S.; Port, H.; Wolf, H. C. Angew. Chem., Int. Ed. Engl. 1988, 27, 281-284.
17. (c) Gust, D.; Moore, T. A.; Moore, A. L.; Barrett, D.; Harding, L. O.; Makings, L. R.; Liddell, P. A.; DeShryver, F. C.; Van der Auweraer, M.; Bensasson, R. V.; Rougee, M. J. Am. Chem. Soc. 1988, 110, 321-323.
18. (d) Gust, D.; Moore, T. A.; Moore, A. L.; Lee, S.-J.; Bittersman, E.; Luttrull, D. K.; Rehms, A. A.; DeGraziano, J. M.; Ma, X. C.; Gao, F.; Belford, R. E.; Trier, T. T. Science 1990, 248, 199-201.
19. (a) Woitellier, S.; Launay, J. P.; Spangler, C. W. Inorg. Chem. 1989, 28, 758-762
20. (b) Reimers, J. R.; Hush, N. S. Inorg. Chem. 1990, 29, 4510-4513.
21. Richardson, D E.; Taube, H. Inorg Chem. 1981, 20, 1278-1285.
22. Sutton, J. E.; Sutton, P.; Taube, H. Inorg. Chem. 1979, 18, 1017-1021.
23. Bruns, W.; Kaim, W. In Mixed Valency Systems: Applications in Chemistry. Physics. Biology; Prassides, K., Ed.; Kluwer Academic Publishers: Dordrecht, The Netherlands. 1991; pp 365-370.
24. Sutton, J. E.; Taube, H. Inorg. Chem. 1981, 20, 3125-3134.
25. McWhinnie, S. L. W ; Jones, C. J.; McCleverty, J. A.; Collison, D.; Mabbs, F. E. J. Chem. Soc., Chem Commun. 1990, 940-943.
26. Thomas, J. A.; Jones, C. J., McClevertv, J. A.; Collison, D.; Mabbs, F. E.; Harding C. J.; Hutchings, M. G. J. Chem. Soc., Chem Commun. 1992, 1796-1798.
27. (a) Trofimenko, S. Inorg. Chem. 1969, 8, 2675-2680.
28. (b) Reynolds, S. J.; Smith, C. F.; Jones, C. J.; McCleverty, J. A. Inorg. Synth. 1985, 23, 4-9
29. (a) Carsky, P.; Hunig, S.; Stemmler, L; Scheutzow, D. Liebigs Ann. Chem. 1980, 291-304.
30. (b) Arrhenius, T. S.; Blanchard-Desce, M ; Dvolaitzky, M.; Lehn, J.-M; Malthete, J. Proc. Natl. Acad. Sci. U.S.A. 1986, 83, 5355-5359.
31. International Tables for X-ray Crystallography; Kynoch Press: Birmingham, England, 1974; Vol. 4.
32. Sheldrick, G. M. Acta Crystallogr. 1990, A46, 467-473.
33. Sheldrick, G. M. SHELX76. Program for Crystal Structure Determination. University of Cambridge, England, 1978.
34. Motherwell, W. D. S.; Clegg, W. PLUTO. Program for Plotting Molecular and Crystal Structures, Cambridge Structural Database System, Users Manual, Part II. Cambridge, England, 1988.
35. McWhinnie, S. L. W.; Jones, C. J.; McCleverty, J. A.; Collison, D.; Mabbs, F. E. Polyhedron 1992, 11, 2639-2643.
36. AlObaidi, N.; Edwards, A. J.; Jones, C. J.; McCleverty, J. A.; Neaves, B. D.; Mabbs, F. E.; Collison, D. J. Chem. Soc., Dalton Trans. 1989, 127-132.
37. AlObaidi, N.; Hamor, T. A.; Jones, C. J.; McCleverty, J. A.; Paxton, K.; Howes, A. J.; Hursthouse, M. B. Polyhedron 1988, 7, 1931-1938.
38. McQuillan, F. S.; Green, T.; Hamor, T. A.; Jones, C. J.; Maher, J. P.; McCleverty, J. A. J. Chem. Soc., Dalton Trans. 1995, 3243-3250.
39. (a) Briggs, T. N ; Colquhoun, H.; El Murr, N.; Jones, C. J.; McCleverty, J. A.; Neaves, B. D.; Adams, H.; Bailey, N. A. J. Chem. Soc., Dalton Trans. 1985, 1249-1254.
40. Shriver, D. F.; Atkins, P. W.; Langford, C. H. In Inorganic Chemisiry; Oxford University Press Oxford, U.K., 1990; p 446.
41. Thomas, J. A.; Hutchings, M. G.; Jones, C. J.; McCleverty, J. A. Unpublished results.
42. (a) Mabbs, F. E ; Collison, D. Electron Paramagnetic Resonance of d-Transition Metal Compounds; Elsevier: Amsterdam. 1992; pp 88-94.
43. (b) Ibid, pp 223-273.
44. Wlodarczyk., A; Kurek, S. S.; Foulon, D.-J.; Hamor, T. A.; McCleverty, J. A. J. Chem. Soc., Dalton Trans. 1992, 981-987.
45. (a) Reitz, D. C.; Weissmann, S. I. J. Chem. Phys. 1960, 33, 700-704.
46. (b) Luckhurst, G. R. Mol. Phys. 1966, 10, 543-550.
47. (c) Glarum, S. H.; Marshall, J. H. J. Chem. Phys. 1967, 47, 1374-1378.
48. (d) Hudson, A.; Luckhurst, G. R. Chem. Rev. 1969, 69, 191-225.
49. (e) Atherton N. M. Electron Spin Resonance. Theory and Applications; Ellis Horwood: Chichester, U.K. 1973; p 182.
50. Stone, A. J. Mol. Phys. 1964, 7, 311-316.
51. Wayland, B. B.; Olson, L. W.; Siddiqui, Z. U. J. Am, Chem. Soc. 1976, 98, 94-98.
52. Mabbs, F E.; Machin, D. J. In Magnetism of Transition Metal Complexes; Chapman and Hall: London, 1973; Chapter 7.
53. Goodman, B. A.; Raynor, J. B. Adv. Inorg. Chem. Radiochem. 1970, 13, 135-362.
54. Boyd, I. W.; Dance, I. G.; Murray, K. S.; and Wedd, A. G. Aust. J. Chem. 1978, 31, 279-284.
55. Bleaney, B.; Bowers, K. D. Proc R. Soc. London 1952, A214, 451-465.
56. Woitellier, S.; Launay, J. P.; Joachim, C. Chem. Phys. 1989, 131, 481-488.
57. Dewar, M. J. S.; Zoebisch, E. G.; Healy E. F.;d Stewart, J. J. Am. Chem. Soc. 1985, 107, 3902-3909. QCPE Program 455 Version 6.0, Department of Chemistry. Indiana University, Bloomington, IN.
58. (a) Bard, A. J.; Faulkner, L. R. In Electrochemical Methods. Fundamentals and Applications; Wiley: New York, 1980.
59. (b) Imbeau, J. C.; Saveant, J. M. Electroanal Intrafacial Chem. 1973, 44, 169-172.
60. Petke, J. D.; Whitten, J. L.; Ryan, J. A. J. Chem. Phys. 1968, 48, 953.
61. Horner, M.; Hunig, S.; Putter, H. Electrochim. Acta 1982, 27, 205.
62. Ribou, A.-C.; Launay, J.-P.; Takahashi, K.; Takayasu, N.; Tarutani, S.; Spangler, C. W. Inorg. Chem. 1994, 33, 1325-1329.
63. McWhinnie, S. L. W Ph.D. Thesis, University of Birmingham, U.K., 1989.
64. Das, A.; Maher, J. P.; McCleverty, J. A.; Navas-Badioia, J. A.; Ward, M. D. J. Chem. Soc., Dalton Trans. 1993, 681-686.
65. Emsley, J. W.; Stephenson, D. S.; Lindon, J. C.; Lunizzi, L.; Pulga, S. J. Chem. Soc., Perkin Trans. 1975, 2, 1541-1544.
66. Chen, P.; Curry, M.; Meyer, T. J. Inorg. Chem. 1989, 28, 2271-2280.
67. (a) Cooke, B. J.; Palmer, T. F. Photochemistry 1984, 26, 149-163.
68. (b) Fujii, T.; Suzuki, S.; Komatsu, S. Chem. Phys. Lett. 1978, 57, 175-178.
69. Das, A.; Jeffrey, J. C.; Maher, J. P.; McCleverty, J. A.; Schatz, E.; Ward, M. D.; Wollermann, G. Inorg. Chem. 1993, 32, 2145-2155.
70. (a) Curtis, J. C., Sullivan, B. P.; Meyer, T. J. Inorg. Chem. 1983, 22, 224-229.
71. (b) Lever, A. B. P In Inorganic Elecironic Spectroscopy, 2nd ed.; Elsevier: The Netherlands, 1984; pp 778-779.
72. Haga, M.-A.; Dodsworth, E. S.; Lever, A. B. P. Inorg. Chem. 1986, 25, 447-453.
73. W. Kemp, W. In Organic Spectroscopy; Macmillan: London, 1979; p 154.
74. Kaim, W. Coord. Chem. Rev. 1987, 76, 187-235.
75. (a) AlObaidi, N.; Hamor, T. A.; Jones, C. J.; McCleverty, J. A.; Paxton, K. J. Chem. Soc., Dalton Trans. 1987, 2653-2660.
76. (b) AlObaidi, N.; Hamor, T. A.; Jones, C. J.; McCleverty, J. A.; Paxton, K. J. Chem. Soc., Dalton Trans. 1987, 1063-1069.
77. AlObaidi, N.; Hamor, T. A.; Jones, C. J.; McCleverty, J. A.; Paxton, K. J. Chem. Soc., Dalton Trans. 1986, 1525-1530.
78. Julg, A.; Francois, P. Theor. Chim. Acta 1967, 8, 249-259.
79. Allen, F. H.; Kennard, O.; Watson, D. G.; Brammer, L.; Orpen, A. G.; Taylor, R.; J Chem. Soc., Perkin Trans. 2 1987, S1-S19.
80. Marder, S R.; Perry, J. W.; Tiemann, B. G.; Gorman, C. B.; Gilmour, S.; Biddle, S. L.; Bourhill, G. J. Am. Chem. Soc. 1993, 115, 2524-2526.
81. Baughman, R. H.; Kohler, B. E.; Levy, I. J.; Spangler, C. Synth. Met. 1985, 11, 37-52.
82. Drenth, W.; Wiebenga, E. H. Acta Crystallogr. 1955, 8, 755-760.
83. (a) Groth, P. Acta Chem. Scand. B 1987, 41, 547-550.
84. (b) Chentli-Bechikha, F.; Declercq, J. P.; Germain, G.; Meersshe, M. V Cryst. Struct. Commun. 1977, 6, 421-424.