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Volumn 100, Issue 8, 2000, Pages 2887-2900

Synthesis and reactivity of sp2 geminated organobismetallic derivatives

Author keywords

[No Author keywords available]

Indexed keywords

AROMATIC COMPOUNDS; ATOMS; CHEMICAL BONDS; DERIVATIVES; ELECTRONIC STRUCTURE; GROUND STATE; LITHIUM; MOLECULAR STRUCTURE; REACTION KINETICS; SUBSTITUTION REACTIONS; SYNTHESIS (CHEMICAL); TRANSITION METALS;

EID: 0034251446     PISSN: 00092665     EISSN: None     Source Type: Journal    
DOI: 10.1021/cr990288e     Document Type: Article
Times cited : (130)

References (133)
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    • Except the alkylidene carbene chemistry, which was recently reviewed (ref 5), the choice of the author was to concentrate this review only on reactive organometallic derivatives which can create in situ several carbon-carbon bonds
    • Except the alkylidene carbene chemistry, which was recently reviewed (ref 5), the choice of the author was to concentrate this review only on reactive organometallic derivatives which can create in situ several carbon-carbon bonds.
  • 21
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    • (b) Maercker, A In Lithium Chemistry; Sapse, A. M., von Rague Schleyer, P., Eds.; Wiley & Sons: New York, 1995; p 490.
    • (1995) Lithium Chemistry , pp. 490
    • Maercker, A.1
  • 33
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    • These precise experimental conditions are used in order to avoid the formation of the 1,1,1-trialuminioalkane
    • These precise experimental conditions are used in order to avoid the formation of the 1,1,1-trialuminioalkane.
  • 40
    • 0342636700 scopus 로고    scopus 로고
    • The second metal can have an aluminum-or titanium-containing group
    • The second metal can have an aluminum-or titanium-containing group.
  • 91
    • 0002424541 scopus 로고
    • Enders, D., Gais, H. J., Klein, W., Eds.; Vieweg: Wiesbaden
    • (n) Kocienski, P. In Organic Synthesis via Organometallics; Enders, D., Gais, H. J., Klein, W., Eds.; Vieweg: Wiesbaden, 1993; p 203-223.
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    • Kocienski, P.1
  • 93
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    • Fritsch, P. Liebigs Ann. Chem. 1894, 272, 319-324. Buttenberg, W. P. Liebigs Ann. Chem. 1894, 272, 324-337. Wiechell, H. Liebigs Ann. Chem. 1894, 272, 337-344.
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    • Fritsch, P.1
  • 94
    • 0009545744 scopus 로고
    • Fritsch, P. Liebigs Ann. Chem. 1894, 272, 319-324. Buttenberg, W. P. Liebigs Ann. Chem. 1894, 272, 324-337. Wiechell, H. Liebigs Ann. Chem. 1894, 272, 337-344.
    • (1894) Liebigs Ann. Chem. , vol.272 , pp. 324-337
    • Buttenberg, W.P.1
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    • Fritsch, P. Liebigs Ann. Chem. 1894, 272, 319-324. Buttenberg, W. P. Liebigs Ann. Chem. 1894, 272, 324-337. Wiechell, H. Liebigs Ann. Chem. 1894, 272, 337-344.
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    • Patai, S., Ed.; Wiley and Sons: New York, and references therein
    • (a) Ben-Efraim, D. A. In The chemistry of carbon-carbon triple bond, part 2; Patai, S., Ed.; Wiley and Sons: New York, 1978; p 773-776 and references therein.
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    • Wiley and sons: New York
    • (c) Moss, R. A., Jones, M., Jr., Eds. Carbenes, Vol. II; Wiley and sons: New York, 1975; p 44.
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    • Moss, R.A.1    Jones M., Jr.2
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    • These carbenoids are usually thermally labile above about -80 °C to -60 °C. However, the X-ray structure of an alkylidene Li-Cl carbenoid was recently published. Maercker, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 1023-1025 and Boche, G.; Marsch, M.; Muller, A.; Harms, K Angew. Chem., Int. Ed. Engl. 1993, 32, 1032-1033.
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    • Maercker, A.1
  • 110
    • 33748517465 scopus 로고
    • These carbenoids are usually thermally labile above about -80 °C to -60 °C. However, the X-ray structure of an alkylidene Li-Cl carbenoid was recently published. Maercker, A. Angew. Chem., Int. Ed. Engl. 1993, 32, 1023-1025 and Boche, G.; Marsch, M.; Muller, A.; Harms, K Angew. Chem., Int. Ed. Engl. 1993, 32, 1032-1033.
    • (1993) Angew. Chem., Int. Ed. Engl. , vol.32 , pp. 1032-1033
    • Boche, G.1    Marsch, M.2    Muller, A.3    Harms, K.4
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    • The diastereoisomeric ratio was determined on the deprotected alcohol
    • The diastereoisomeric ratio was determined on the deprotected alcohol.
  • 132
    • 0343942682 scopus 로고    scopus 로고
    • An alternative mechanism for the obtention of 106 can also be formulated via an oxidative addition of the Ti(II) into the chloroalkyne
    • An alternative mechanism for the obtention of 106 can also be formulated via an oxidative addition of the Ti(II) into the chloroalkyne.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.