Excited-state exchange coupling in bent Mn(III)-O-Mn(III) complexes: Dominance of the π/σ superexchange pathway and its possible contributions to the reactivities of binuclear metalloproteins

Journal of the American Chemical Society

Volumn 122, Issue 35, 2000, Pages 8511-8523

  Brunold, Thomas C ^a,b   Gamelin, Daniel R ^a,c   Solomon, Edward I ^a  

^a STANFORD UNIVERSITY   (United States)

^b UNIVERSITY OF WISCONSIN MADISON   (United States)

^c UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

HEMERYTHRIN; MANGANESE DERIVATIVE; METAL ION; METALLOPROTEIN; RIBONUCLEOTIDE REDUCTASE;

ABSORPTION SPECTROSCOPY; ARTICLE; CALCULATION; CHEMICAL INTERACTION; ELECTRON TRANSPORT; THERMODYNAMICS;

EID: 0033824807     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja000264l     Document Type: Article

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