An asymmetric conjugate addition reaction of lithium organocopper reagent controlled by a chiral amidophosphine

Tetrahedron

Volumn 55, Issue 13, 1999, Pages 3831-3842

  Kanai, Motomu ^a   Nakagawa, Yuichi ^b   Tomioka, Kiyoshi ^b  

^a UNIVERSITY OF TOKYO   (Japan)

^b KYOTO UNIVERSITY   (Japan)

Author keywords

Asymmetric reactions; Copper and compounds; Lithium and compounds

Indexed keywords

COPPER; CYCLOALKENE; LITHIUM DERIVATIVE;

ARTICLE; CHEMICAL REACTION; CONFORMATIONAL TRANSITION; ENANTIOMER; PRIORITY JOURNAL; STOICHIOMETRY; STRUCTURE ANALYSIS;

EID: 0033605831     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0040-4020(99)00094-0     Document Type: Article

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52. 4) derivative obtained by reduction. The ee was determined by a chiral stationary phase HPLC. Soai K.; Hayasaka, T.; Ugajin, S.; Yokoyama, S. Chem. Lett. 1988, 1571-1572.
53. 4) derivative obtained by reduction. The ee was determined by a chiral stationary phase HPLC. Soai K.; Hayasaka, T.; Ugajin, S.; Yokoyama, S. Chem. Lett. 1988, 1571-1572.
54. 4) derivative obtained by reduction. The ee was determined by a chiral stationary phase HPLC. Soai K.; Hayasaka, T.; Ugajin, S.; Yokoyama, S. Chem. Lett. 1988, 1571-1572.
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60. The absolute configuration was determined by the specific rotation. Cyclopentanones (3-ethyl: Posner, G. H.; Frye, L. L.; Hulce, M. Tetrahedron 1984, 40, 1401-1407. 3-butyl: Tamura. Y.; Tanaka, M.; Funakoshi, K.; Sakai, K. Tetrahedron Lett. 1989, 30, 4349-4352). Cyclohexanones (3-methyl: Leyendecker, F.; Jesser, F.; Ruhland, B. Tetrahedron Lett. 1981, 22, 3601-3604; 3-ethyl, 3-phenyl, 3-vinyl: Posner, G. H.; Frye, L. L. Isr. J. Chem. 1984, 24, 88-92. 3-butyl: ref b). 3-Methyl-cycloheptanone: Djerassi, C.; Burrows, B. F.; Overberger, C. G.; Takekoshi, T.; Gutsche, C. D.; Chang, C. T. J. Am. Chem. Soc. 1963, 85, 949-950.
61. The absolute configuration was determined by the specific rotation. Cyclopentanones (3-ethyl: Posner, G. H.; Frye, L. L.; Hulce, M. Tetrahedron 1984, 40, 1401-1407. 3-butyl: Tamura. Y.; Tanaka, M.; Funakoshi, K.; Sakai, K. Tetrahedron Lett. 1989, 30, 4349-4352). Cyclohexanones (3-methyl: Leyendecker, F.; Jesser, F.; Ruhland, B. Tetrahedron Lett. 1981, 22, 3601-3604; 3-ethyl, 3-phenyl, 3-vinyl: Posner, G. H.; Frye, L. L. Isr. J. Chem. 1984, 24, 88-92. 3-butyl: ref b). 3-Methyl-cycloheptanone: Djerassi, C.; Burrows, B. F.; Overberger, C. G.; Takekoshi, T.; Gutsche, C. D.; Chang, C. T. J. Am. Chem. Soc. 1963, 85, 949-950.
62. The absolute configuration was determined by the specific rotation. Cyclopentanones (3-ethyl: Posner, G. H.; Frye, L. L.; Hulce, M. Tetrahedron 1984, 40, 1401-1407. 3-butyl: Tamura. Y.; Tanaka, M.; Funakoshi, K.; Sakai, K. Tetrahedron Lett. 1989, 30, 4349-4352). Cyclohexanones (3-methyl: Leyendecker, F.; Jesser, F.; Ruhland, B. Tetrahedron Lett. 1981, 22, 3601-3604; 3-ethyl, 3-phenyl, 3-vinyl: Posner, G. H.; Frye, L. L. Isr. J. Chem. 1984, 24, 88-92. 3-butyl: ref b). 3-Methyl-cycloheptanone: Djerassi, C.; Burrows, B. F.; Overberger, C. G.; Takekoshi, T.; Gutsche, C. D.; Chang, C. T. J. Am. Chem. Soc. 1963, 85, 949-950.
63. The absolute configuration was determined by the specific rotation. Cyclopentanones (3-ethyl: Posner, G. H.; Frye, L. L.; Hulce, M. Tetrahedron 1984, 40, 1401-1407. 3-butyl: Tamura. Y.; Tanaka, M.; Funakoshi, K.; Sakai, K. Tetrahedron Lett. 1989, 30, 4349-4352). Cyclohexanones (3-methyl: Leyendecker, F.; Jesser, F.; Ruhland, B. Tetrahedron Lett. 1981, 22, 3601-3604; 3-ethyl, 3-phenyl, 3-vinyl: Posner, G. H.; Frye, L. L. Isr. J. Chem. 1984, 24, 88-92. 3-butyl: ref b). 3-Methyl-cycloheptanone: Djerassi, C.; Burrows, B. F.; Overberger, C. G.; Takekoshi, T.; Gutsche, C. D.; Chang, C. T. J. Am. Chem. Soc. 1963, 85, 949-950.
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