Reaction pathway of the conjugate addition of lithium organocuprate clusters to acrolein

Journal of the American Chemical Society

Volumn 119, Issue 21, 1997, Pages 4900-4910

  Nakamura, Eiichi ^a   Mori, Seiji ^a   Morokuma, Keiji ^b  

^a UNIVERSITY OF TOKYO   (Japan)

^b EMORY UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACROLEIN; COPPER COMPLEX; LITHIUM DERIVATIVE;

ALKYLATION; ARTICLE; CHEMICAL STRUCTURE; CONJUGATION; ENERGY TRANSFER; NUCLEAR MAGNETIC RESONANCE IMAGING; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS;

EID: 0030970598     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja964209h     Document Type: Article

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94. 1 is already heavily coordinated and consequently that CPcl may become more stable in solution than CPop.
95. 1 is already heavily coordinated and consequently that CPcl may become more stable in solution than CPop.
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106. (a) Nakamura, E.; Kuwajima, I. J. Am. Chem. Soc. 1984, 106, 3368-3370. Horiguchi, Y.; Matsuzawa, S.; Nakamura, E.; Kuwajima, I. Tetrahedron Lett. 1986, 27, 4025-4028. Nakamura, E.; Matsuzawa, S.; Horiguchi, Y.; Kuwajima, I. Tetrahedron Lett. 1986, 27, 4029-4032.
107. (a) Nakamura, E.; Kuwajima, I. J. Am. Chem. Soc. 1984, 106, 3368-3370. Horiguchi, Y.; Matsuzawa, S.; Nakamura, E.; Kuwajima, I. Tetrahedron Lett. 1986, 27, 4025-4028. Nakamura, E.; Matsuzawa, S.; Horiguchi, Y.; Kuwajima, I. Tetrahedron Lett. 1986, 27, 4029-4032.
108. (a) Nakamura, E.; Kuwajima, I. J. Am. Chem. Soc. 1984, 106, 3368-3370. Horiguchi, Y.; Matsuzawa, S.; Nakamura, E.; Kuwajima, I. Tetrahedron Lett. 1986, 27, 4025-4028. Nakamura, E.; Matsuzawa, S.; Horiguchi, Y.; Kuwajima, I. Tetrahedron Lett. 1986, 27, 4029-4032.
109. (b) See, also: Corey, E. J.; Boaz, N. W. Tetrahedron Lett, 1985, 26, 6015-6018 and 6019-6022. Alexakis, A.; Berlan, J.; Besace, Y. Tetrahedron Lett. 1986, 27, 1047-1050. Johnson, C. R.; Marren, T. J. Tetrahedron Lett. 1987, 28, 27-30. Horiguchi, Y.; Komatsu, M.; Kuwajima, I. Tetrahedron Lett. 1989, 30, 7087-7090.
110. (b) See, also: Corey, E. J.; Boaz, N. W. Tetrahedron Lett, 1985, 26, 6015-6018 and 6019-6022. Alexakis, A.; Berlan, J.; Besace, Y. Tetrahedron Lett. 1986, 27, 1047-1050. Johnson, C. R.; Marren, T. J. Tetrahedron Lett. 1987, 28, 27-30. Horiguchi, Y.; Komatsu, M.; Kuwajima, I. Tetrahedron Lett. 1989, 30, 7087-7090.
111. (b) See, also: Corey, E. J.; Boaz, N. W. Tetrahedron Lett, 1985, 26, 6015-6018 and 6019-6022. Alexakis, A.; Berlan, J.; Besace, Y. Tetrahedron Lett. 1986, 27, 1047-1050. Johnson, C. R.; Marren, T. J. Tetrahedron Lett. 1987, 28, 27-30. Horiguchi, Y.; Komatsu, M.; Kuwajima, I. Tetrahedron Lett. 1989, 30, 7087-7090.
112. (b) See, also: Corey, E. J.; Boaz, N. W. Tetrahedron Lett, 1985, 26, 6015-6018 and 6019-6022. Alexakis, A.; Berlan, J.; Besace, Y. Tetrahedron Lett. 1986, 27, 1047-1050. Johnson, C. R.; Marren, T. J. Tetrahedron Lett. 1987, 28, 27-30. Horiguchi, Y.; Komatsu, M.; Kuwajima, I. Tetrahedron Lett. 1989, 30, 7087-7090.
113. 3SiI. See: Bergdahl, M.; Lindstedt, E.-L.; Nilsson, M.; Olsson, T. Tetrahedron 1988, 7, 2055-2062. Eriksson, M.; Johansson, A.; Nilsson, M.; Olsson, T. J. Am. Chem. Soc. 1996, 118, 10904-10905.
114. 3SiI. See: Bergdahl, M.; Lindstedt, E.-L.; Nilsson, M.; Olsson, T. Tetrahedron 1988, 7, 2055-2062. Eriksson, M.; Johansson, A.; Nilsson, M.; Olsson, T. J. Am. Chem. Soc. 1996, 118, 10904-10905.
115. (d) For some mechanistic proposals, see: Lipshutz, B. H.; Dimock, S. H.; James, B. J. Am. Chem. Soc. 1993, 115, 9283-9284. Bertz, S. H.; Miao, G.; Rossiter, B. E.; Snyder, J. P. J. Am. Chem. Soc. 1995, 117, 11023-11024.
116. (d) For some mechanistic proposals, see: Lipshutz, B. H.; Dimock, S. H.; James, B. J. Am. Chem. Soc. 1993, 115, 9283-9284. Bertz, S. H.; Miao, G.; Rossiter, B. E.; Snyder, J. P. J. Am. Chem. Soc. 1995, 117, 11023-11024.