Diastereoselective synthesis of pyridyl substituted thiazolidin-4-ones. New ligands for the Cu(I) catalyzed asymmetric conjugate addition of diethylzinc to enones

Tetrahedron Asymmetry

Volumn 8, Issue 10, 1997, Pages 1539-1543

  De Vries, André H M ^a   Hof, Robert P ^a   Staal, Danny ^a   Kellogg, Richard M ^a   Feringa, Ben L ^a  

^a UNIVERSITY OF GRONINGEN   (Netherlands)

Author keywords

[No Author keywords available]

Indexed keywords

LIGAND; THIAZOLIDINE DERIVATIVE;

ARTICLE; CRYSTALLIZATION; DIASTEREOISOMER; DRUG SYNTHESIS; ISOMERISM; PRIORITY JOURNAL; REACTION ANALYSIS;

EID: 0030914708     PISSN: 09574166     EISSN: None     Source Type: Journal    
DOI: 10.1016/S0957-4166(97)00146-8     Document Type: Article

References (30)

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3. c) Noyori, R. Asymmetric Catalysis in Organic Chemistry; Wiley: New York, 1994. See for example also de Vries, A.H.M.; Feringa, B.L. Tetrahedron: Asymmetry 1997, 8, 1377 and Ref. 18.
4. c) Noyori, R. Asymmetric Catalysis in Organic Chemistry; Wiley: New York, 1994. See for example also de Vries, A.H.M.; Feringa, B.L. Tetrahedron: Asymmetry 1997, 8, 1377 and Ref. 18.
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15. The use of a chiral bidentate phoshine as ligand in a CuI catalyzed addition of Grignard reagents to cyclic enones (e.e. up to 92%) has been reported recently: M. Kanai, K. Tomioka, Tetrahedron Lett. 1995, 36, 4275.
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27. a) Very recently a β-amino disulfide, derived from proline, has been used as chiral ligand in the nickel catalyzed conjugate addition of diethylzinc to chalcone (e.e. <50%); no results with other enones, for example cyclohexenone, are described: Gibson, C.L. Tetrahedron: Asymmetry 1996, 7, 3357.
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