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33747569583
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note
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2, followed by fluoride-induced cleavage of the crude enol silyl ethers.
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40
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0032555049
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While our studies were underway, a closely related transformation was described, see S. Amano, N. Ogawa, M. Ohtsuka, S. Ogawa, N. Chida, Chem. Commun. 1998, 1263-1264.
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33747579325
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note
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This is a slight modification of a procedure employed in Corey and Snider's pioneering synthesis of fumagillin (reference [6]).
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42
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0028357501
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2Me) in optically active form is available from (-)-quinic acid (D. F. McComsey, B. E. Maryanoff, J. Org. Chem. 1994, 59, 2652-2654) or by Sharpless asymmetric dihydroxylation followed by isopropylidene ketal formation
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