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35
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0344384378
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note
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0 is the initial absorption.
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-
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36
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0345247151
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note
-
Owing to the limited amount of 23b available, we were not able to measure the extinction coefficient at several different concentrations in order to ascertain whether anchimeric complexation is still dominant at high concentrations, i.e. to check whether the Lambert-Beer law is satisfied over a broad concentration range. Moreover, the fact that the equilibrium disfavours 23a, which is responsible for the CT absorption, renders such a determination uncertain.
-
-
-
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37
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0344816102
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note
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A small decrease in the equilibrium CT absorption (ca. 5%) was observed after each experiment, which may be accounted for by chemical decomposition upon refluxing.
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38
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0345247149
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note
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[6][7]
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-
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39
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0344816103
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note
-
The data were fitted (Ultra-Fit 2.11) using the following expression relating the chemical shift change (Δδ) of the host (i.e. 3) and the concentration c of the guest (i.e. TTF): formula presented The concentration of host was kept constant at c(host); Δδ(sat) denotes the saturated chemical shift change, i.e. when all of the host is present in its complexed form.
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40
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85045588015
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