Localization in trans,trans-[(tpy)(Cl)2OsIII(N2)Os II(Cl)2(tpy)]+ (tpy = 2,2′:6′,2″-Terpyridine)

Inorganic Chemistry

Volumn 36, Issue 25, 1997, Pages 5678-5679

  Demadis, Konstantinos D ^a   Meyer, Thomas J ^a   White, Peter S ^a  

^a University of North Carolina at Chapel Hill   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 0001338871     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic970885o     Document Type: Article

References (30)

1. (a) Tom, G. M.; Creutz, C.; Taube, H. J. Am. Chem. Soc. 1974, 96, 7828.
2. (b) Sutton, J. E.; Sutton, P. M.; Taube, H. Inorg. Chem. 1979, 18, 1017.
3. (c) Hupp, J. T.; Dong, Y.; Blackbourn, R. L.; Lu, H. J. Phys. Chem. 1993, 97, 3278.
4. (a) Richardson, D. E.; Sen, J. P.; Buhr, J. D.; Taube, H. Inorg. Chem. 1982, 21, 3136.
5. (b) Dubicki, L.; Ferguson, J.; Krautz, E. R.; Lay, P. A.; Maeder, M.; Magnuson, R. H.; Taube, H. J. Am. Chem. Soc. 1985, 107, 2167.
6. (a) Creutz, C.; Taube, H. J. Am. Chem. Soc. 1969, 91, 3988.
7. (b) Creutz, C.; Taube, H. J. Am. Chem. Soc. 1973, 95, 1086.
8. (c) Creutz, C. Prog. Inorg. Chem. 1983, 31, 1.
9. (a) Hupp, J. T.; Neyhart, G. A.; Meyer, T. J. J. Am. Chem. Soc. 1986, 108, 5349.
10. (b) Neyhart, G. A.; Timpson, C. J.; Bates, W. D.; Meyer, T. J. J. Am. Chem. Soc. 1996, 118, 3730.
11. Che, C.-M.; Lam, H.-W.; Tong, W.-F.; Lai, T.-F.; Lau, T.-C.; J. Chem. Soc., Chem. Commun. 1989, 1883.
12. Magnuson, R. H.; Taube, H. J. Am. Chem. Soc. 1972, 94, 7213.
13. Ware, D. C.; Taube, H. Inorg. Chem. 1991, 30, 4605.
14. Williams, D. S.; Coia, G. M.; Meyer, T. J. Inorg. Chem. 1995, 34, 586.
15. 15N) 1972 (vw); v(tpy) 1448 (vs), 1435 (vs), 1383 (vs).
16. 15N) 1942 (vs); v(tpy) 1451 (vs). 1439 (s), 1391 (vs).
17. w = 0.053). NRCVAX was used as the software package. Full details can be found in the Supporting Information.
18. Wilkinson, P. G.; Houk, N. B. J. Chem. Phys. 1956, 24, 528.
19. III-Cl bond lengths: 2.34-2.36 Å. Champness, N. R.; Levason, W.; Pletcher, D.; Spicer, M. D.; Webster, M. J. Chem. Soc., Dalton Trans. 1992, 2201.
20. II-Cl bond lengths: 2.43-2.45 Å. Levason, W.; Champness, N. R.; Webster, M. Acta Crystallogr. 1993, C49, 1884.
21. (a) Henderson, R. A.; Leigh, G. J.; Pickett, C. J. Adv. Inorg. Chem. Radiochem. 1983, 27, 197.
22. (b) Hidai, M.; Mizobe, Y. Chem. Rev. 1995, 95, 1115.
23. Kober, E. M.; Goldsby, K. A.; Narayana, D. N. S.; Meyer, T. J. J. Am. Chem. Soc. 1983, 105, 4303.
24. Demadis, K. D.; Meyer, T. J. Manuscript in preparation.
25. (a) Hush, N. S. Prog. Inorg. Chem. 1967, 8, 391.
26. (b) Creutz, C.; Newton, M. D.; Sutin, N. J. Photochem. Photobiol. A: Chem. 1994, 82, 47.
27. (c) The charge transfer distance used in this analysis, 4.97 Å, was taken from the crystal structure.
28. Robin, M. B.; Day, P. Adv. Inorg. Chem. Radiochem. 1967, 10, 247.
29. (a) Barbara, P. F.; Jarbeda, W. Adv. Photochem. 1990, 75, 1.
30. (b) Maroncelli, M. J. Mol. Liq. 1993, 57, 1.