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Volumn 103, Issue 47, 1999, Pages 10489-10495

Self-Assembled Mono- and Multilayers on Gold from 1,4-Diisocyanobenzene and Ruthenium Phthalocyanine

Author keywords

[No Author keywords available]

Indexed keywords


EID: 0001199783     PISSN: 15206106     EISSN: None     Source Type: Journal    
DOI: 10.1021/jp992438v     Document Type: Article
Times cited : (49)

References (67)
  • 4
    • 0347327794 scopus 로고
    • NRL Publication 146-6190, July 1989; Naval Research Laboratory: Arlington, VA
    • Naval Research Laboratory, Bio/Molecular Engineering Branch. Biologically based self-assembly: Bio/molecular engineering; NRL Publication 146-6190, July 1989; Naval Research Laboratory: Arlington, VA, 1988.
    • (1988) Biologically Based Self-assembly: Bio/molecular Engineering
  • 20
    • 0030848621 scopus 로고    scopus 로고
    • Decher, G. Science 1997, 277, 1232.
    • (1997) Science , vol.277 , pp. 1232
    • Decher, G.1
  • 40
    • 85088083035 scopus 로고    scopus 로고
    • note
    • 2.
  • 44
    • 85088081083 scopus 로고    scopus 로고
    • note
    • 2 configuration of acetonitrile on Pt(111) was obtained from electron energy loss spectroscopy, which does not have the same selection rules as IRRAS.
  • 48
    • 0346066420 scopus 로고    scopus 로고
    • personal communication
    • Bureau, C., personal communication.
    • Bureau, C.1
  • 52
    • 0346697221 scopus 로고    scopus 로고
    • note
    • 2 + 2) = Sum (density*alpha), with alpha the polarizability. A single oscillator in the far UV usually accounts for non absorbing media. The spectra can therefore be fitted with a minimum number of unknown parameters. We report in the figure the imaginary part of the measured and fitted polarizabilities of the layer. The real part of the polarizability (not shown) was fitted with the same set of parameters. The asymmetric peak observed in Figure 3 clearly indicates the relevance of two absorption lines.
  • 53
    • 0346697215 scopus 로고    scopus 로고
    • note
    • 1s XPS signal is quite broad. However, we performed a SIMS analysis on similar architectures built on glass with pyridine groups pointing out from the surface as anchoring axial ligands. The presence of the remaining benzonitrile ligand on the outer surface of the bilayer was clearly evidenced on the SIMS spectrum.
  • 54
    • 0346697214 scopus 로고    scopus 로고
    • note
    • The roughness arising from a perfectly ordered film exhibiting protruding benzonitrile ligands regularly scattered over a close packed RuPc monolayer can be estimated as 3 Å. This figure is lower than the expected roughness of our substrates.
  • 67
    • 0346066419 scopus 로고    scopus 로고
    • note
    • -1. This result confirms that the coordination of the isocyanide group to RuPc results in a weakening of the isocyanide bond.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.