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2 configuration of acetonitrile on Pt(111) was obtained from electron energy loss spectroscopy, which does not have the same selection rules as IRRAS.
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2 + 2) = Sum (density*alpha), with alpha the polarizability. A single oscillator in the far UV usually accounts for non absorbing media. The spectra can therefore be fitted with a minimum number of unknown parameters. We report in the figure the imaginary part of the measured and fitted polarizabilities of the layer. The real part of the polarizability (not shown) was fitted with the same set of parameters. The asymmetric peak observed in Figure 3 clearly indicates the relevance of two absorption lines.
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1s XPS signal is quite broad. However, we performed a SIMS analysis on similar architectures built on glass with pyridine groups pointing out from the surface as anchoring axial ligands. The presence of the remaining benzonitrile ligand on the outer surface of the bilayer was clearly evidenced on the SIMS spectrum.
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54
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The roughness arising from a perfectly ordered film exhibiting protruding benzonitrile ligands regularly scattered over a close packed RuPc monolayer can be estimated as 3 Å. This figure is lower than the expected roughness of our substrates.
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