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Volumn 120, Issue 18, 1998, Pages 4478-4487

Synthesis and properties of metalloporphyrin monolayers and stacked multilayers bound to an electrode via site specific axial ligation to a self- assembled monolayers

Author keywords

[No Author keywords available]

Indexed keywords

METALLOPORPHYRIN;

EID: 0032513716     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja973528l     Document Type: Article
Times cited : (168)

References (78)
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    • For reviews of SAMs, see: (a) Whitesides, G. M.; Laibinis, P. E. Langmuir 1990, 6, 87-96. (b) Ulman, A. An Introduction to Ultrathin Organic Films from Langmuir Blodgett to Self-Assembly; Academic Press: San Diego, 1991. Dubois, L. H.; Nuzzo, R. G. Annu. Rev. Phys. Chem. 1992, 43, 437-463. Ulman, A. Characterization of Organic Thin Films: Materials Characterization Series-Surfaces, Interfaces, Thin Films; Butterworth-HeinemAnn: Stoneham, MA, 1995.
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    • For reviews of SAMs, see: (a) Whitesides, G. M.; Laibinis, P. E. Langmuir 1990, 6, 87-96. (b) Ulman, A. An Introduction to Ultrathin Organic Films from Langmuir Blodgett to Self-Assembly; Academic Press: San Diego, 1991. Dubois, L. H.; Nuzzo, R. G. Annu. Rev. Phys. Chem. 1992, 43, 437-463. Ulman, A. Characterization of Organic Thin Films: Materials Characterization Series-Surfaces, Interfaces, Thin Films; Butterworth-HeinemAnn: Stoneham, MA, 1995.
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    • Butterworth-HeinemAnn: Stoneham, MA
    • For reviews of SAMs, see: (a) Whitesides, G. M.; Laibinis, P. E. Langmuir 1990, 6, 87-96. (b) Ulman, A. An Introduction to Ultrathin Organic Films from Langmuir Blodgett to Self-Assembly; Academic Press: San Diego, 1991. Dubois, L. H.; Nuzzo, R. G. Annu. Rev. Phys. Chem. 1992, 43, 437-463. Ulman, A. Characterization of Organic Thin Films: Materials Characterization Series-Surfaces, Interfaces, Thin Films; Butterworth-HeinemAnn: Stoneham, MA, 1995.
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    • Metalloporphyrins contained within enzymes have also been adsorbed onto gold-thiolate SAMs. Attachment has been achieved by electrostatic forces (Tarlov, M. J.; Bowden, E. F. J. Am. Chem. Soc. 1991, 113, 1847-1849) and by carbodiimide linkages through amino acid side chains (Collinson, M.; Bowden, E. F. Langmuir 1992, 8, 1247-1250).
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    • Metalloporphyrins contained within enzymes have also been adsorbed onto gold-thiolate SAMs. Attachment has been achieved by electrostatic forces (Tarlov, M. J.; Bowden, E. F. J. Am. Chem. Soc. 1991, 113, 1847-1849) and by carbodiimide linkages through amino acid side chains (Collinson, M.; Bowden, E. F. Langmuir 1992, 8, 1247-1250).
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    • Polycrystalline gold substrates prepared by cold evaporative techniques have been shown to have extremely strong (>80%) Au(111) texture: (a) Chidsey, C. E. D.; Loiacono, D. N.; Sleator, T.; Nakahara, S. Surf. Sci. 1988, 200, 45-66. (b) Chidsey, C. E. D.; Loiacono, D. N. Langmuir 1990, 6, 682-691.
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    • Polycrystalline gold substrates prepared by cold evaporative techniques have been shown to have extremely strong (>80%) Au(111) texture: (a) Chidsey, C. E. D.; Loiacono, D. N.; Sleator, T.; Nakahara, S. Surf. Sci. 1988, 200, 45-66. (b) Chidsey, C. E. D.; Loiacono, D. N. Langmuir 1990, 6, 682-691.
    • (1990) Langmuir , vol.6 , pp. 682-691
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    • Swalen, J. D.; Santo, R.; Take, M.; Fischer, J. IBM J. Res. Dev. 1977, 21, 169-175. The refractive index of metalloporphyrins on the SAM is unknown. Therefore, the observed thickness increases are qualitative rather than quantitative measurements.
    • (1977) IBM J. Res. Dev. , vol.21 , pp. 169-175
    • Swalen, J.D.1    Santo, R.2    Take, M.3    Fischer, J.4
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    • note
    • Longer deposition times (up to 24 h) resulted in no noticeable increase in the amount of adsorbed metalloporphyrin.
  • 60
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    • note
    • These data are presented in the Supporting Information.
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    • note
    • These extraneous peaks are attributable to a small amount of impurity in the porphyrin and, in our hands, are always observed.
  • 65
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    • Lippard, S. J., Ed.; John Wiley & Sons: New York
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    • note
    • IV/III or the porphyrin which are present in a 1:1 stoichiometry, the CV area still leads to a porphyrin coverage.
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    • Ennis, M.S.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.