Understanding strong two-photon absorption in π-conjugated porphyrin dimers via double-resonance enhancement in a three-level model

Journal of the American Chemical Society

Volumn 126, Issue 47, 2004, Pages 15352-15353

  Drobizhev, Mikhail ^a   Stepanenko, Yuriy ^a   Dzenis, Yuliya ^a   Karotki, Aliaksandr ^a   Rebane, Aleksander ^a   Taylor, Peter N ^a   Anderson, Harry L ^a  

^a NONE

Author keywords

[No Author keywords available]

Indexed keywords

DIMER;

ABSORPTION; ARTICLE; CHROMATOPHORE; CONJUGATION; MICROSCOPY; PHONON; PHOTOCHEMISTRY; PHOTODYNAMICS;

EID: 9644281391     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja0445847     Document Type: Article

References (25)

1. Lin, T.-C.; Chung, S.-J.; Kim, K.-S.; Wang, X.; He, G. S.; Swiatkiewicz, J.; Pudavar, H. E.; Prasad, P. N. Adv. Polym. Sci. 2003, 161, 157-193.
2. Renn, A.; Wild, U. P.; Rebane, A. J. Phys. Chem. A 2002, 106, 3045-3060.
3. (a) Drobizhev, M.; Karotki, A.; Kruk, M.; Rebane, A. Chem. Phys. Lett. 2002, 355, 175-182.
4. (b) Drobizhev, M.; Karotki, A.; Kruk, M.; Mamardashvili, N. Zh.; Rebane, A. Chem. Phys. Lett. 2002, 361, 504-512.
5. (c) Karotki, A.; Drobizhev, M.; Kruk, M.; Spangler, C.; Nickel, E.; Mamardashvili, N.; Rebane, A. J. Opt. Soc. Am. B 2003, 20, 321-332.
6. (d) Drobizhev, M.; Karotki, A.; Kruk, M.; Krivokapic, A.; Anderson, H. L.; Rebane, A. Chem. Phys. Lett. 2003, 370, 690-699.
7. (e) Drobizhev, M.; Karotki, A.; Kruk, M.; Dzenis, Y.; Rebane, A.; Meng, F.; Nickel, E.; Spangler, C. W. Proc. SPIE 2003, 5211, 63-74.
8. (f) Karotki, A.; Drobizhev, M.; Dzenis, Y.; Taylor, P. N.; Anderson, H. L.; Rebane, A. Phys. Chem. Chem. Phys. 2004, 6, 7-10.
9. (a) Lin, V. S.-Y.; DiMagno, S. G.; Therien, M. J. Science 1994, 264, 1105-1111.
10. (b) Taylor, P. N.; Wylie, A. P.; Huuskonen, J.; Anderson, H. L. Angew. Chem., Int. Ed. 1998, 37, 986-989.
11. (a) Albota, M.; Beljonne, D.; Brédas, J.-L.; Ehrlich, J. E.; Fu, J.-Y.; Heikal, A. A.; Hess, S. E.; Kogej, T.; Levin, M. D.; Marder, S. R.; McCord-Maughon, D.; Perry, J. W.; Röckel, H.; Rumi, M.; Subramaniam, G.; Webb, W. W.; Wu, X.-L.; Xu, C. Science 1998, 281, 1653-1656.
12. (b) Drobizhev, M.; Karotki, A.; Rebane, A.; Spangler, C. W. Opt. Lett. 2001, 26, 1081-1083.
13. 2, was excited with pulses of 100-fs duration and 5-10 μJ energy; fluorescence intensity was measured with a LN-cooled CCD, coupled with a Jobin Yvon Triax 550 spectrometer. 2PA excitation spectra were calibrated against the known 2PA spectrum of Lucifer Yellow in water, and 2PA cross sections were measured relative to rhodamine B in methanol. See: Xu, C.; Webb, W. W. J. Opt. Soc. Am. B 1996, 13, 481-491.
14. 3 GM have been measured in related conjugated porphyrin dimers, in the same spectral region, using the femtosecond z-scan method: Ogawa, K.; Ohashi, A.; Kobuke, Y.; Kamada, K.; Ohta, K. J. Am. Chem. Soc. 2003, 125, 13356-13357.
15. Beljonne, D.; O'Keefe, G. E.; Hamer, P. J.; Friend, R. H.; Anderson, H. L.; Brédas, J. L. J. Chem. Phys. 1997, 106, 9439-9460.
16. Rubtsov, I. V.; Susumu, K.; Rubtsov, G. I.; Therien, M. J. J. Am. Chem. Soc. 2003, 125, 2687-2696.
17. Boyd, R. W. Nonlinear Optics; Academic Press: Amsterdam, 2003; Ch. 12.
18. (a) Piet, J. J.; Taylor, P. N.; Anderson, H. L.; Osuka, A.; Warman, J. M. J. Am. Chem. Soc. 2000, 122, 1749-1757.
19. (b) Shediac, R.; Gray, M. H. B.; Uyeda, H. T.; Johnson, R. C.; Hupp, J. T.; Angiolillo, P. J.; Therien, M. J. J. Am. Chem. Soc. 2000, 122, 7017-7033.
20. (a) Anderson, H. L. Adv. Mater. 1994, 6, 834-836.
21. (b) Stranger, R.; McGrady, J. E.; Arnold, D. P.; Lane, I.; Heath, G. A. Inorg. Chem. 1996, 35, 7791-7797.
22. (a) Dixit, S. N.; Guo, D.; Mazumdar, S. Phys. Rev. B 1991, 43, 6781-6784.
23. (b) Norman, P.; Luo, Y.; Ågren, H. Opt. Commun. 1999, 168, 297-303.
24. (c) Thorne, J. R. G.; Kuebler, S. M.; Denning, R. G.; Blake, I. M.; Taylor, P. N.; Anderson, H. L. Chem. Phys. 1999, 248, 181-193.
25. Rashba, E. I.; Gurgenishvili, G. E. Sov. Phys. Solid State 1962, 4, 759-760.