EPR and affinity studies of mannose-TEMPO functionalized PAMAM dendrimers

Organic and Biomolecular Chemistry

Volumn 2, Issue 21, 2004, Pages 3075-3079

  Samuelson, Lynn E ^a   Sebby, Karl B ^a   Walter, Eric D ^a   Singel, David J ^a   Cloninger, Mary J ^a  

^a MONTANA STATE UNIVERSITY   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AFFINITY CHROMATOGRAPHY; BINDING ENERGY; CARBOHYDRATES; HYDROXYLATION; PARAMAGNETIC RESONANCE; PROTEINS; SYNTHESIS (CHEMICAL);

CONCANAVALIN; MANNOSE; PAMAM DENDRIMERS; TEMPO;

DENDRIMERS;

AMINE OXIDE; CONCANAVALIN A; MANNOSE; PAMAM STARBURST; POLYAMINE; TEMPO;

AFFINITY CHROMATOGRAPHY; ARTICLE; CHEMISTRY; ELECTRON SPIN RESONANCE; HEMAGGLUTINATION TEST; MASS SPECTROMETRY; SPIN LABELING; SYNTHESIS;

CHROMATOGRAPHY, AFFINITY; CONCANAVALIN A; CYCLIC N-OXIDES; ELECTRON SPIN RESONANCE SPECTROSCOPY; HEMAGGLUTINATION TESTS; MANNOSE; POLYAMINES; SPECTROMETRY, MASS, MATRIX-ASSISTED LASER DESORPTION-IONIZATION; SPIN LABELS;

EID: 9144273963     PISSN: 14770520     EISSN: None     Source Type: Journal    
DOI: 10.1039/b411643g     Document Type: Article

References (40)

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3. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
4. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
5. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
6. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
7. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
8. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
9. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
10. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
11. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
12. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
13. For some examples, see: Linear polymer: (a) Z. Yang, E. B. Pugger, J. K. Pontrello and L. Kiessling, Carbohydrate Res., 2002, 337, 1605-1613; (b) L. L. Kiessling, in Recent Trends in Molecular Recognition; ed. F. Diederich and H. Kunzer, Springer-Verlag, Berlin Heidelberg: Berlin, 1998, p. 183-212; (c) G. B. Sigal, M. Mammen, G. Dahmann and G. M. Whitesides, J. Am. Chem. Soc., 1996, 118, 3789-3800; (d) Virus cage: K. S. Raja, Q. Wang and M. G. Finn, ChemBioChem, 2003, 4, 1348-1351; (e) Gold nanoparticle: J. Rojo, V. Diaz, J. M. de la Fuente, I. Segura, A. G. Barrientos, H. H. Riese, A. Bernad and S. Penades, ChemBioChem, 2004, 5, 291-297; (f) C.-C. Lin, Y.-C. Yeh, C.-Y. Yang, G.-F. Chen, Y.-C. Chen, Y.-C. Wu and C.-C. Chen, Chem. Commun., 2003, 2920-2921; (g) Cyclodextrin: A. Mazzaglia, D. Forde, D. Garozzo, P. Malvagna, B. J. Ravoo and D. Darcy, Org. Biomol. Chem., 2004, 2, 957-960; (h) T. Ooya, M. Eguchi and N. Yui, J. Am. Chem. Soc., 2003, 125, 13016-13017; (i) A. Nelson and J. F. Stoddart, Org. Lett., 2003, 5, 3783-3786; (j) C. O. Mellet, J. Defaye and J. M. G. Fernandez, Chem. Eur. J., 2002, 8, 1983-1990; (k) F. Ortega-Caballero, J. J. Gimenez-Martinez, L. Garcia-Fuentes, E. Ortiz-Salmeron, F. Santoyo-Gonzalez and A. Vargas-Berenguel, J. Org. Chem., 2001, 66, 7786-6695; (l) S. Andre, H. Kaltner, T. Furuike, S.-I. Nishimura and H.-J. Gabius, Bioconjugate Chem., 2004, 15, 87-98.
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37. 1/d" ratio introduced in A. I. Korkorin, K. I. Zamarayev, G. L. Grigoryan and E. G. Rozantsev, Biofizika, 1972, 17, 34-41; and recently employed in M. Persson, J. R. Harbridge, P. Hammarstrom, R. Mitri, L. G. Martensson, U. Carlsson, G. R. Eaton and S. S. Eaton, Biophys. J., 2001, 80, 2886-97.
38. Comparison of the double integral signal intensity values for 3-9 with their equivalently-functionalized deacetylated dendrimers 10-16 gives results analogous to those obtained from comparison of A/B peak height ratios. The integral areas and the EPR absorbance spectra are provided in the supporting informationt.
39. T. Osawa and I. Matsumoto, Methods Enzymol., 1972, 28, 323-327.
40. H. O. Hankoxszky, K. Hideg and L. Lex, Synthesis, 1981, 147-149.