Asymmetric double proton transfer of excited 1:1 7-Azaindole/Alcohol complexes with anomalously large and temperature-independent kinetic isotope effects

Angewandte Chemie - International Edition

Volumn 43, Issue 43, 2004, Pages 5792-5796

  Kwon, Oh Hoon ^a   Lee, Young Shin ^a   Park, Han Jung ^a   Kim, Yongho ^b   Jang, Du Jeon ^a  

^a Seoul National University   (South Korea)

^b Kyung Hee University   (South Korea)

Author keywords

Hydrogen bonds; Kinetic isotope effects; N heterocycles; Proton transfer; Time resolved spectroscopy

Indexed keywords

COMPLEXATION; ELECTRON ENERGY LEVELS; ISOTOPES; PARAFFINS; PROTONS; REACTION KINETICS; SOLVENTS; SPECTROSCOPIC ANALYSIS; THERMAL EFFECTS;

1:1 7-AZAINDOLE/ALCOHOL; HEAVY ATOMS; LOWEST-LYING EXCITED SINGLET STATES; PROTON TRANSFER; TUNNELING PROTONS;

ALCOHOLS;

7 AZAINDOLE; ALCOHOL; ALKANE; DIMER; DOUBLE STRANDED DNA; HETEROCYCLIC COMPOUND; INDOLE DERIVATIVE; ISOTOPE; SOLVENT; TRYPTOPHAN DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ATOM; BASE PAIRING; CATALYST; CHEMICAL ANALYSIS; CHEMICAL BOND; CHEMICAL INTERACTION; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COMPLEX FORMATION; CONCENTRATION RESPONSE; DECOMPOSITION; DEVICE; ENERGY TRANSFER; FLUORESCENCE; HYDROGEN BOND; LUMINESCENCE; MOLECULAR DYNAMICS; MOTION; POLYMERIZATION; PROTON TRANSPORT; ROOM TEMPERATURE; STRUCTURE ANALYSIS; TECHNIQUE; TEMPERATURE DEPENDENCE; ULTRAVIOLET SPECTROSCOPY; VISCOSITY;

EID: 8844269438     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200461102     Document Type: Article

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