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Volumn 5, Issue 2, 1999, Pages 759-773

The SHi reaction at silicon - A new entry into cyclic alkoxysilanes

Author keywords

Homolytic substitution reactions; Radical reactions; Silicon; Stereoselective reactions; Tin

Indexed keywords


EID: 85085631699     PISSN: 09476539     EISSN: None     Source Type: Journal    
DOI: 10.1002/(sici)1521-3765(19990201)5:2<759::aid-chem759>3.3.co;2-m     Document Type: Article
Times cited : (1)

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    • Silyl ethers derived from primary alcohols cyclize much slower than their congeners derived from secondary or tertiary alcohols (see below). For the fast cyclizing systems it was difficult to isolate pure radical precursors, because traces of an initiator can start the UMCT reaction and thus lead to decomposition of the starting material.
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    • Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication no. CCDC-102599 (trans-41). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB21EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam. ac.uk). The X-ray analysis was carried out by Dr. V. Gramlich (ETH Zürich).
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