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33845374708
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0001052025
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18
-
-
85030271818
-
-
note
-
8. Analyzed using a 3.3 mm × 2 m column packed with 10% SE-30 on Chromosorb W under a flow rate of 30 mL/min. Retention time (min) at column temperature = 130 °C: 7a = 6.3, 8a = 7.1, 9a = 7.9. Retention time (min) at column temperature = 140 °C: 7b = 8.5, 8b = 9.4, 9b = 10.5, 15 = 11.6, 18a = 7.8, 19a = 10.5, 20a = 9.4, 18b = 13.2, 19b = 16.0, 21 = 16.9.
-
-
-
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20
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0001496215
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21
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0001330999
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0028070690
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23
-
-
85030273871
-
-
note
-
10. Acylsilane 15 was synthesized using methods similar to the synthesis of 6b as shown in scheme II. Instead of 1,5-dibromopentane, 1-bromopentane was used.
-
-
-
-
24
-
-
85030273408
-
-
note
-
11. We did not determine the exact olefin geometry of 25a and 25b.
-
-
-
-
25
-
-
33947093235
-
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12. (a) Shono, T.; Nishiguchi, I.; Ohmizu, H.; Mitani, M. J. Am. Chem. Soc., 1978, 100, 545-550.
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26
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33845375642
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(b) Belotti, D.; Cossy, J.; Pete, J. P.; Portella, C. J. Org. Chem. 1986, 51, 4196-4200.
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Pete, J.P.3
Portella, C.4
-
27
-
-
85030274722
-
-
note
-
3) δ 12.7, 23.2, 25.0, 27.8, 29.6, 31.1, 33.7, 36.2, 47.1. 81.0 ppm.
-
-
-
-
30
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33845281717
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15. (a) Nozaki, K.; Oshima, K.; Utimoto, K. J. Am. Chem. Soc., 1987, 109, 2547-2549.
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Utimoto, K.3
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31
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0001434093
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(b) Miura, K.; Ichinose, Y.; Nozaki, K.; Fugami, K.; Oshima, K.; Utimoto, K. Bull. Chem. Soc. Jpn. 1989, 62, 143-147.
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Miura, K.1
Ichinose, Y.2
Nozaki, K.3
Fugami, K.4
Oshima, K.5
Utimoto, K.6
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