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The (formula presented) edge originates from dipole-allowed excitations of electrons from the inner (formula presented) (formula presented) edge) and (formula presented) levels (formula presented) edge) to the unoccupied (formula presented) band. The resulting two white lines are doubled by the action of the Coulomb field imposed by the surrounding O atoms. A perfect octahedral ligand field causes the five degenerate d states in the conduction band to split into the twofold (formula presented) orbitals which are directed at the ligands and the threefold (formula presented) orbitals which are directed between the ligands
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