Hyperconjugative, Secondary Orbital, Electrostatic, and Steric Effects on the Reactivities and Endo and Exo Stereoselectivities of Cyclopropene Diels-Alder Reactions

Journal of the American Chemical Society

Volumn 138, Issue 51, 2016, Pages 16731-16736

  Levandowski, Brian J ^a   Houk, K N ^a  

^a UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

CHEMICAL REACTIONS; ELECTROSTATICS; GROUND STATE; STEREOSELECTIVITY;

AROMATICITIES; CYCLOPROPENES; DIELS-ALDER REACTION; STERIC EFFECT;

DENSITY FUNCTIONAL THEORY;

1,3 BUTADIENE; CYCLOPROPENE; HYDROGEN; PROPYLENE; UNCLASSIFIED DRUG;

AROMATIZATION; ARTICLE; CONJUGATION; CYCLOADDITION; DENSITY FUNCTIONAL THEORY; DIELS ALDER REACTION; ENTHALPY; HYDROGEN BOND; STATIC ELECTRICITY; STEREOSELECTIVITY;

EID: 85008419331     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.6b10463     Document Type: Article

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