Galvanic replacement reaction: A simple and powerful route to hollow and porous metal nanostructures

Proceedings of the Institution of Mechanical Engineers, Part N: Journal of Nanoengineering and Nanosystems

Volumn 221, Issue 1, 2007, Pages 1-16

  Lu, Xianmao ^a   Chen, Jingyi ^a   Skrabalak, S E ^a   Xia, Younan ^a  

^a UNIVERSITY OF WASHINGTON   (United States)

Author keywords

applications; galvanic replacement reaction; hollow nanostructures; noble metals

Indexed keywords

EID: 84990357521     PISSN: 17403499     EISSN: 20413092     Source Type: Journal    
DOI: 10.1243/17403499JNN111     Document Type: Article

References (68)

1. Sanders A. W. Routenberg D. A. Wiley B. J. Xia Y. Dufresne E. R. Reed M. A. Observation of plasmon propagation, redirection, and fan-out in silver nanowires. Nano Lett., 2006, 6, 1822–1826.
2. Chen S. W. Yang Y. Y. Magnetoelectrochemistry of gold nanoparticle quantized capacitance charging. J. Am. Chem. Soc., 2002, 124, 5280–5281.
3. Li Y. Hong X. M. Collard D. M. El-Sayed M. A. Suzuki cross-coupling reactions catalyzed by palladium nanoparticles in aqueous solution. Org. Lett., 2000, 2, 2385–2388.
4. Willets K. A. Van Duyne R. P. Localized surface plasmon resonance spectroscopy and sensing. A. Rev. Phys. Chem., 2007, 58, 267–297.
5. Ditlbacher H. Krenn J. R. Lamprecht B. Leitner A. Aussenegg F. R. Spectrally coded optical data storage by metal nanoparticles. Opt. Lett., 2000, 25, 563–565.
6. Kamat P. V. Meeting the clean energy demand: Nano-structure architectures for solar energy conversion. J. Phys. Chem. C, 2007, 111, 2834–2860.
7. Xia Y. Yang P. Sun Y. Wu Y. Mayers B. Gates B. Yin Y. Kim F. Yan Y. One-dimensional nano-structures: Synthesis, characterization, and applications. Adv. Mater., 2003, 15, 353–389.
8. Sun Y. Tao Z. Chen J. Herricks T. Xia Y. Ag nanowires coated with Ag/Pd alloy sheaths and their use as substrates for reversible absorption and desorption of hydrogen. J. Am. Chem. Soc., 2004, 126, 5940–5941.
9. Sun Y. Mayers B. Herricks T. Xia Y. Polyol synthesis of uniform silver nanowires: A plausible growth mechanism and the supporting evidence. Nano Lett., 2003, 3, 955–960.
10. Jana N. R. Gearheart L. Murphy C. J. Wet chemical synthesis of silver nanorods and nanowires of controllable aspect ratio. Chem. Communs, 2001, 7, 617–618.
11. Kim F. Song J. H. Yang P. D. Photochemical synthesis of gold nanorods. J. Am. Chem. Soc., 2002, 124, 14316–14317.
12. Brust M. Walker M. Bethell D. Schiffrin D. J. Whyman R. Synthesis of thiol-derivatized gold nanoparticles in a 2-phase liquid-liquid system. Chem. Communs, 1994, 7, 801–802.
13. Sun Y. Xia Y. Shape-controlled synthesis of gold and silver nanoparticles. Science, 2002, 298, 2176–2179.
14. Yu D. B. Yam V. W. W. Controlled synthesis of monodisperse silver nanocubes in water. J. Am. Chem. Soc., 2004, 126, 13200–13201.
15. Seo D. Park J. C. Song H. Polyhedral gold nanocrystals with O-h symmetry: From octahedra to cubes. J. Am. Chem. Soc., 2006, 128, 14863–14870.
16. Xiong Y. Washio I. Chen J. Cai H. Li Z.-Y. Xia Y. Poly(vinyl pyrrolidone): A dual functional reductant and stabilizer for the facile synthesis of noble metal nanoplates in aqueous solutions. Langmuir, 2006, 22, 8563–8570.
17. Jin R. C. Cao Y. W. Mirkin C. A. Kelly K. L. Schatz G. C. Zheng J. G. Photoinduced conversion of silver nanospheres to nanoprisms. Science, 2001, 294, 1901–1903.
18. Sun Y. Xia Y. Triangular nanoplates of silver: Synthesis, characterization, and use as sacrificial templates for generating triangular nanorings of gold. Adv. Mater., 2003, 15, 695–699.
19. Pastoriza-Santos I. Perez-Juste J. Carregal-Romero S. Herves P. Liz-Marzan L. M. Metallo-dielectric hollow shells: Optical and catalytic properties. Chem.-Asian J., 2006, 1, 730–736.
20. Liao H. Nehl C. L. Hafner J. H. Biomedical applications of plasmon resonant metal nanoparticles. Nanomedicine, 2006, 1, 201–208.
21. Chen J. Saeki F. Wiley B. J. Cang H. Cobb M. J. Li Z. Y. Au L. Zhang H. Kimmey M. B. Li X. Xia Y. Gold nanocages: Bioconjugation and their potential use as optical imaging contrast agents. Nano Lett., 2005, 5, 473–477.
22. Chen J. Wiley B. J. Li Z.-Y. Campbell D. Saeki F. Cang H. Au L. Lee J. Li X. Xia Y. Gold nanocages: Engineering their structure for biomedical applications. Adv. Mater., 2005, 17, 2255–2261.
23. Chen J. Wang D. Xi J. Au L. Siekkinen A. Warsen A. Li Z.-Y. Zhang H. Xia Y. Li X. Immuno gold nanocages with tailored optical properties for targeted photothermal destruction of cancer cells. Nano Lett., 2007, 7, 1318–1322.
24. Im S. H. Lee Y. T. Wiley B. Xia Y. Large-scale synthesis of silver nanocubes: The role of HCl in promoting cube perfection and monodispersity. Angew. Chem.-Int. Edit., 2005, 44, 2154–2157.
25. Wiley B. Sun Y. Xia Y. Polyol synthesis of silver nanostructures: Control of product morphology with Fe(II) or Fe(III) species. Langmuir, 2005, 21, 8077–8080.
26. Siekkinen A. R. McLellan J. M. Chen J. Xia Y. Rapid synthesis of small silver nanocubes by mediating polyol reduction with a trace amount of sodium sulfide or sodium hydrosulfide. Chem. Phys. Lett., 2006, 432, 491–496.
27. Sun Y. Xia Y. Mechanistic study on the replacement reaction between silver nanostructures and chloroauric acid in aqueous medium. J. Am. Chem. Soc., 2004, 126, 3892–3901.
28. Wang Z.-L. Transmission electron microscopy of shape-controlled nanocrystals and their assemblies. J. Phys. Chem. B, 2000, 104, 1153–1175.
29. Szklarska-Smialowska Z. Pitting corrosion of metals, 1986 (National Association of Corrosion Engineers, Houston, Texas).
30. Wonnell S. K. Delaye J. M. Bibole M. Limoge Y. Activation volume for the interdiffusion of Ag-Au multilayers. J. Appl. Phys., 1992, 72, 5195–5205.
31. Shibata T. Bunker B. A. Zhang Z. Y. Meisel D. Vardeman C. F. Gezelter J. D. Size-dependent spontaneous alloying of Au-Ag nanoparticles. J. Am. Chem. Soc., 2002, 124, 11989–11996.
32. Bukaluk A. Auger electron spectroscopy investigations of the effect of degradation of depth resolution and its influence on the interdiffusion data in thin film Au/Ag, Cu/Ag, Pd/Au and Pd/Cu multilayer structures. Appl. Surf. Sci., 2001, 175, 790–796.
33. Mallard W. C. Gardner A. B. Bass R. F. Slifkin L. M. Self-diffusion in silver-gold solid solutions. Phys. Rev., 1963, 129, 617–625.
34. Sun Y. Mayers B. Xia Y. Template-engaged replacement reaction: A one-step approach to the large-scale synthesis of metal nanostructures with hollow interiors. Nano Lett., 2002, 2, 481–485.
35. Erlebacher J. Aziz M. J. Karma A. Dimitrov N. Sieradzki K. Evolution of nanoporosity in dealloying. Nature, 2001, 410, 450–453.
36. Shahrabi T. Newman R. C. Sieradzki K. Stress-corrosion cracking of alpha-brass without copper oxidation. J. Electrochem. Soc., 1993, 140, 348–352.
37. Roosen A. R. Carter W. C. Simulations of microstructural evolution: Anisotropic growth and coarsening. Physica A, 1998, 261, 232–247.
38. Chen J. McLellan J. M. Siekkinen A. Xiong Y. Li Z.-Y. Xia Y. Facile synthesis of gold-silver nanocages with controllable pores on the surface. J. Am. Chem. Soc., 2006, 128, 14776–14777.
39. Sun Y. G. Mayers B. Herricks T. Xia Y. N. Polyol synthesis of uniform silver nanowires: A plausible growth mechanism and the supporting evidence. Nano Lett., 2003, 3, 955–960.
40. McLellan J. M. Siekkinen A. Chen J. Xia Y. Comparison of the surface-enhanced Raman scattering on sharp and truncated silver nanocubes. Chem. Phys. Lett., 2006, 427, 122–126.
41. Haes A. J. Van Duyne R. P. A unified view of propagating and localized surface plasmon resonance biosensors. Anal. Bioanal. Chem., 2004, 379, 920–930.
42. Caruso F. Nanoengineering of particle surfaces. Adv. Mater., 2001, 13, 11–22.
43. Huang H. Y. Remsen E. E. Kowalewski T. Wooley K. L. Nanocages derived from shell cross-linked micelle templates. J. Am. Chem. Soc., 1999, 121, 3805–3806.
44. Wiley B. J. Sun Y. Mayers B. Xia Y. Shape-controlled synthesis of metal nanostructures: The case of silver. Chem.-Eur. J., 2005, 11, 454–463.
45. Sun Y. Mayers B. Xia Y. Metal nanostructures with hollow interiors. Adv. Mater., 2003, 15, 641–646.
46. Lu X. Tuan H.-Y. Chen J. Li Z.-Y. Korgel B. A. Xia Y. Mechanistic studies on the galvanic replacement reaction between multiply twinned particles of Ag and HAuCl4 in an organic medium. J. Am. Chem. Soc., 2007, 129, 1733–1742.
47. Kim Y. J. Johnson R. C. Li J. G. Hupp J. T. Schatz G. C. Synthesis, linear extinction, and preliminary resonant hyper-Rayleigh scattering studies of gold-core/silver-shell nanoparticles: Comparisons of theory and experiment. Chem. Phys. Lett., 2002, 352, 421–428.
48. Sun Y. Wiley B. J. Li Z.-Y. Xia Y. Synthesis and optical properties of nanorattles and multiple-walled nanoshells/nanotubes made of metal alloys. J. Am. Chem. Soc., 2004, 126, 9399–9406.
49. Sun Y. Xia Y. Multiple-walled nanotubes made of metals. Adv. Mater., 2004, 16, 264–268.
50. Chen J. Wiley B. J. McLellan J. M. Xiong Y. Li Z.-Y. Xia Y. Optical properties of Pd-Ag and Pt-Ag nanoboxes synthesized via galvanic replacement reactions. Nano Lett., 2005, 5, 2058–2062.
51. Batzill M. Koel B. E. Silver on Pt(100) - room temperature growth and high temperature alloying. Surf. Sci., 2004, 553, 50–60.
52. Kim S. W. Kim M. Lee W. Y. Hyeon T. Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for Suzuki coupling reactions. J. Am. Chem. Soc., 2002, 124, 7642–7643.
53. Mulvaney P. Surface plasmon spectroscopy of nano-sized metal particles. Langmuir, 1996, 12, 788–800.
54. Oldenburg S. J. Jackson J. B. Westcott S. L. Halas N. J. Infrared extinction properties of gold nano-shells. Appl. Phys. Lett., 1999, 75, 2897–2899.
55. Nie S. M. Emery S. R. Probing single molecules and single nanoparticles by surface-enhanced Raman scattering. Science, 1997, 275, 1102–1106.
56. Dick L. A. McFarland A. D. Haynes C. L. Van Duyne R. P. Metal film over nanosphere (MFON) electrodes for surface-enhanced Raman spectroscopy (SERS): Improvements in surface nanostructure stability and suppression of irreversible loss. J. Phys. Chem. B, 2002, 106, 853–860.
57. Sokolov K. Chumanov G. Cotton T. M. Enhancement of molecular fluorescence near the surface of colloidal metal films. Anal. Chem., 1998, 70, 3898–3905.
58. Das P. Metiu H. Enhancement of molecular fluorescence and photochemistry by small metal particles. J. Phys. Chem., 1985, 89, 4680–4687.
59. Hirsch L. R. Stafford R. J. Bankson J. A. Sershen S. R. Rivera B. Price R. E. Hazle J. D. Halas N. J. West J. L. Nanoshell-mediated near-infrared thermal therapy of tumors under magnetic resonance guidance. Proc. Natl. Acad. Sci. USA, 2003, 100, 13549–13554.
60. Storhoff J. J. Elghanian R. Mucic R. C. Mirkin C. A. Letsinger R. L. One-pot colorimetric differentiation of polynucleotides with single base imperfections using gold nanoparticle probes. J. Am. Chem. Soc., 1998, 120, 1959–1964.
61. Kreibig U. Gartz M. Hilger A. Mie resonances: Sensors for physical and chemical cluster interface properties. Ber. Bunsen-Ges. Phys. Chem. Chem. Phys., 1997, 101, 1593–1604.
62. Sun Y. Xia Y. Gold and silver nanoparticles: A class of chromophores with colors tunable in the range from 400 to 750 nm. Analyst, 2003, 128, 686–691.
63. Jensen T. Kelly L. Lazarides A. Schatz G. C. Electrodynamics of noble metal nanoparticles and nanoparticle clusters. J. Clust. Sci., 1999, 10, 295–317.
64. Hu M. Petrova H. Chen J. McLellan J. M. Siekkinen A. R. Marquez M. Li X. Xia Y. Hartland G. V. Ultrafast laser studies of the photothermal properties of gold nanocages. J. Phys. Chem. B, 2006, 110, 1520–1524.
65. Huang X. H. El-Sayed I. H. Qian W. El-Sayed M. A. Cancer cell imaging and photothermal therapy in the near-infrared region by using gold nano-rods. J. Am. Chem. Soc., 2006, 128, 2115–2120.
66. Mook W. M. Jungk J. M. Cordill M. J. Moody N. R. Sun Y. Xia Y. Gerberich W. W. Geometry and surface state effects on the mechanical response of Au nanostructures. Z. Metallk., 2004, 95, 416–424.
67. Lin W. B. Warren T. H. Nuzzo R. G. Girolami G. S. Surface-selective deposition of palladium and silver films from metal-organic precursors - a novel metal-organic chemical-vapor-deposition redox transmetalation process. J. Am. Chem. Soc., 1993, 115, 11644–11645.
68. Porter L. A. Choi H. C. Ribbe A. E. Buriak J. M. Controlled electroless deposition of noble metal nano-particle films on germanium surfaces. Nano Lett., 2002, 2, 1067–1071.