Atomic and molecular magnets on surfaces

Fundamentals of Picoscience

Volumn , Issue , 2013, Pages 447-470

  Brune, Harald ^a   Gambardella, Pietro ^b,c  

^a EPFL   (Switzerland)

^b CATALAN INSTITUTE OF NANOSCIENCE AND NANOTECHNOLOGY ICN2   (Spain)

^c ETH ZURICH   (Switzerland)

Author keywords

[No Author keywords available]

Indexed keywords

DICHROISM; MAGNETISM; MAGNETS; ORGANOMETALLICS; SCANNING TUNNELING MICROSCOPY;

DIFFERENT SUBSTRATES; EXPERIMENTAL TECHNIQUES; FUTURE IMPROVEMENTS; MAGNETIC BEHAVIOR; MOLECULAR MAGNET; MOLECULAR NETWORKS; TEMPERATURE DEPENDENT; X-RAY MAGNETIC CIRCULAR DICHROISM;

ATOMS;

EID: 84974784331     PISSN: None     EISSN: None     Source Type: Book    
DOI: 10.1201/b15523     Document Type: Chapter

References (102)

1. H. Brune and P. Gambardella, Magnetism of individual atoms adsorbed on surfaces, Surf. Sci. 603 (2009) 1812.
2. P. Gambardella, S. Rusponi, M. Veronese, S. S. Dhesi, C. Grazioli, A. Dallmeyer, I. Cabria et al., Giant magnetic anisotropy of single Co atoms and nanoparticles on Pt, Science 300 (2003) 1130.
3. P. Gambardella, S. S. Dhesi, S. Gardonio, C. Grazioli, P. Ohresser, and C. Carbone, Localized magnetic states of Fe, Co, and Ni impurities on alkali metal films, Phys. Rev. Lett. 88 (2002) 047202.
4. P. Gambardella, A. Dallmeyer, K. Maiti, M. C. Malagoli, S. Rusponi, P. Ohresser, W. Eberhardt, C. Carbone, and K. Kern, Oscillatory magnetic anisotropy in one-dimensional atomic wires, Phys. Rev. Lett. 93 (2004) 077203.
5. A. J. Heinrich, J. A. Gupta, C. P. Lutz, and D. M. Eigler, Single-atom spin-flip spectroscopy, Science 306 (2004) 466-469.
6. A. Lodi-Rizzini, C. Krull, T. Balashov, J. J. Kavich, A. Mugarza, P. S. Miedema, P. K. Thakur, V. Sessi, S. Klyatskaya, M. Ruben, S. Stepanow, and P. Gambardella, Coupling single molecule magnets to ferromagnetic substrates, Phys. Rev. Lett. 107 (2011) 177205.
7. A. Mugarza, C. Krull, R. Robles, S. Stepanow, G. Ceballos, and P. Gambardella, Spin coupling and relaxation inside molecule? metal contacts, Nat. Commun. 2 (2011) 490.
8. L. Zhou, J. Wiebe, S. Lounis, E. Vedmedenko, F. Meier, S. Blügel, P. H. Dederichs, and R. Wiesendanger, Strength and directionality of surface RKKY-interaction mapped on the atomic scale, Nat. Phys. 6 (2010) 187.
9. W. Wernsdorfer, Classical and quantum magnetization reversal studied in nanometer-sized particles and clusters, Adv. Chem. Phys. 118 (2001) 99.
10. W. Wernsdorfer, Quantum dynamics in molecular nanomagnets, C. R. Chimie 11 (2008) 1086.
11. J. S. Miller and D. Gatteschi, Molecule-based magnets, Chem. Soc. Rev. 40 (2011) 3065.
12. A. A. Khajetoorians, J. Wiebe, B. Chilian, and R. Wiesendanger, Realizing all-spin-based logic operations atom by atom, Science 332 (2011) 1062.
13. C. Carbone, S. Gardonio, P. Moras, S. Lounis, M. Heide, G. Bihlmayer, N. Atodiresei et al., Self-assembled nanometerscale magnetic networks on surfaces: Fundamental interactions and functional properties, Adv. Funct. Mater. 21 (2011) 1212.
14. P. Gambardella, S. Rusponi, T. Cren, N. Weiss, and H. Brune, Magnetic anisotropy from single atoms to large monodomain islands of Co/Pt(111), C. R. Phys. 6 (2005) 75-87.
15. M. Bode, M. Heide, K. v. Bergmann, P. Ferriani, S. Heinze, G. Bihlmayer, A. Kubetzka, O. Pietzsch, S. Blügel, and R.Wiesendanger, Chiral magnetic order at surfaces driven by inversion asymmetry, Nature 447 (2007) 190.
16. M. A. Ruderman and C. Kittel, Indirect exchange coupling of nuclear magnetic moments by conduction electrons, Phys. Rev. 96 (1954) 99.
17. T. Kasuya, A theory of metallic ferro-and antiferromagnetism on Zener’s model, Prog. Theor. Phys. 16 (1956) 45.
18. K. Yosida, Magnetic properties of Cu-Mn alloys, Phys. Rev. 106 (1957) 893.
19. A. Vindigni, A. Rettori, M. G. Pini, C. Carbone, and P. Gambardella, Finite-sized Heisenberg chains and magnetism of one-dimensional metal systems, Appl. Phys. A 82 (2006) 385.
20. J. Stöhr and H. C. Siegmann, Magnetism-From Fundamentals to Nanoscale Dynamics, Vol. 152, Springer, Berlin, Germany, 2006.
21. R. Wiesendanger, Spin mapping at the nanoscale and atomic scale, Rev. Mod. Phys. 81 (2009) 1495.
22. B. T. Thole, G. v. d. Laan, J. C. Fuggle, G. A. Sawatzky, R. C. Karnatak, and J. M. Esteva, 3d x-ray-absorption lines and the 3d94fn+1 multiplets of the lanthanides, Phys. Rev. B 32 (1985) 5107.
23. G. v. d. Laan and B. T. Thole, Strong magnetic x-ray dichroism in 2p absorption spectra of 3d transition-metal ions, Phys. Rev. B 43 (1991) 13401-13411.
24. B. T. Thole, P. Carra, F. Sette, and G. v. d. Laan, X-ray circular dichroism as a probe of orbital magnetization, Phys. Rev. Lett. 68 (1992) 1943-1946.
25. P. Carra, B. T. Thole, M. Altarelli, and X. Wang, X-ray circular dichroism and local magnetic fields, Phys. Rev. Lett. 70 (1993) 694-697.
26. C. T. Chen, Y. U. Idzerda, H. J. Lin, N. V. Smith, G. Meigs, E. Chaban, G. H. Ho, E. Pellegrin and F. Sette, Experimental confirmation of the X-ray magnetic circular dichroism sum rules for iron and cobalt, Phys. Rev. Lett. 75 (1995) 152-155.
27. S. Stepanow, A. Mugarza, G. Ceballos, P. Moras, J. Cezar, C. Carbone, and P. Gambardella, Giant spin and orbital moment anisotropies of a Cu-phthalocyanine monolayer, Phys. Rev. B 82 (2010) 014405.
28. A. Yazdani, B. A. Jones, C. P. Lutz, M. F. Crommie, and D. M. Eigler, Probing the local effects of magnetic impurities on superconductivity, Science 275 (1997) 1767-1770.
29. 8+delta, Nature 411 (2001) 920-924.
30. L. Bürgi, Scanning Tunneling Microscopy as Local Probe of Electron Density, Dynamics, and Transport at Metal Surfaces, Ph.D. thesis, Swiss Federal Institute of Technology, Lausanne, Switzerland, (1999).
31. J. Li, W. D. Schneider, R. Berndt, and B. Delley, Kondo scattering observed at a single magnetic impurity, Phys. Rev. Lett. 80 (1998) 2893.
32. M. Ternes, A. J. Heinrich, and W. D. Schneider, Spectroscopic manifestations of the Kondo effect on single adatoms, J. Phys.: Condens. Matter 21 (2009) 053001.
33. V. Madhavan, W. Chen, T. Jamneala, M. F. Crommie, and N. S. Wingreen, Tunneling into a single magnetic atom:Spectroscopic evidence of the kondo resonance, Science 280 (1998) 567-569.
34. J. Kröger, N. Néel, and L. Limot, Contact to single atoms and molecules with the tip of a scanning tunnelling microscope, J. Phys.: Condens. Matter 20 (2008) 223001.
35. R. Wiesendanger, H. J. Güntherodt, G. Güntherodt, R. J. Gambino, and R. Ruf, Observation of vaccuum tunneling of spin-polarized electrons with the scanning tunneling microscope, Phys. Rev. Lett. 65 (1990) 247.
36. M. Bode, Spin-polarized scanning tunnelling microscopy, Rep. Prog. Phys. 66 (2003) 523.
37. W. Wulfhekel and J. Kirschner, Spin-polarized scanning tunneling microscopy of magnetic structures and antiferromagnetic thin films, Ann. Rev. Mater. Res. 37 (2007) 69.
38. S. Krause, L. Berbil-Bautista, G. Herzog, M. Bode, and R. Wiesendanger, Current-induced magnetization switching with a spin-polarized scanning tunneling microscope, Science 317 (2007) 1537.
39. S. Rusponi, N. Weiss, T. Cren, M. Epple, and H. Brune, High tunnel magnetoresistance in spin-polarized scanning tunneling microscopy of Co nanoparticles on Pt(111), Appl. Phys. Lett. 87 (2005) 162514.
40. W. A. Hofer, K. Palotás, S. Rusponi, T. Cren, and H. Brune, Role of hydrogen in giant spin polarization observed on magnetic nanostructures, Phys. Rev. Lett. 100 (2008) 026806.
41. F. Meier, L. Zhou, J. Wiebe, and R. Wiesendanger, Revealing magnetic interactions from single-atom magnetization curves, Science 320 (2008) 82-86.
42. G. Rodary, S. Wedekimd, D. Sander, and J. Kirschner, Magnetic hysteresis loop of single co nano-islands, Jpn. J. Appl. Phys. 47 (2008) 9013.
43. A. A. Khajetoorians, J. Wiebe, B. Chilian, S. Lounis, S. Blügel, and R. Wiesendanger, Atom-by-atom engineering and magnetometry of tailored nanomagnets, Nat. Phys. 8 (2012) 497.
44. H. Oka, K. Tao, S. Wedekind, G. Rodary, V. Stepanyuk, D. Sander, and J. Kirschner, Spatially modulated tunnel magnetoresistance on the nanoscale, Phys. Rev. Lett. 107 (2011) 187201.
45. S. Ouazi, S. Wedekind, G. Rodary, H. Oka, D. Sander, and J. Kirschner, Magnetization reversal of individual co nanoislands, Phys. Rev. Lett. 108 (2012) 107206.
46. C. F. Hirjibehedin, C. P. Lutz, and A. J. Heinrich, Spincoupling in engineered atomic structures, Science 312 (2006) 1021.
47. C. F. Hirjibehedin, C. Y. Lin, A. F. Otte, M. Ternes, C. P. Lutz, B. A. Jones, and A. J. Heinrich, Large magnetic anisotropy of a single atomic spin embedded in a surface molecular network, Science 317 (2007) 1199-1203.
48. A. F. Otte, M. Ternes, K. v. Bergmann, S. Loth, H. Brune, C. P. Lutz, C. F. Hirjibehedin, and A. J. Heinrich, The role of magnetic anisotropy in the Kondo effect, Nat. Phys. 4 (2008) 847.
49. T. Balashov, T. Schuh, A. F. Takács, A. Ernst, S. Ostanin, J. Henk, I. Mertig, P. Bruno, T. Miyamachi, S. Suga, and W. Wulfhekel, Magnetic anisotropy and magnetization dynamics of individual atoms and clusters of Fe and Co on Pt(111), Phys. Rev. Lett. 102 (2009) 257203.
50. A. A. Khajetoorians, B. Chilian, J. Wiebe, S. Schuwalow, F. Lechermann, and R. Wiesendanger, Detecting excitation and magnetization of individual dopants in a semiconductor, Nature 467 (2010) 1084.
51. A. A. Khajetoorians, S. Lounis, B. Chilian, A. T. Costa, L. Zhou, D. L. Mills, J. Wiebe, and R. Wiesendanger, Itinerant nature of atom-magnetization excitation by tunneling electrons, Phys. Rev. Lett. 106 (2011) 037205.
52. J. Lambe, R. C. Jaklevic, Molecular vibration spectra by inelastic electron tunneling, Phys. Rev. 165 (1968) 821.
53. E. L. Wolf, Principles of Electron Tunneling Spectroscopy, Oxford University Press, New York, 1989.
54. B. C. Stipe, M. A. Rezaei, and W. Ho, Single molecule vibrational spectroscopy and microscopy, Science 280 (1998) 1732.
55. T. Balashov, A. F. Takacs, W. Wulfhekel, and J. Kirschner, Magnon excitation with spin-polarized Scanning Tunneling Microscopy, Phys. Rev. Lett. 97 (2006) 187201.
56. S. Loth, S. Baumann, C. P. Lutz, D. M. Eigler, and A. J. Heinrich, Bistability in atomic-scale antiferromagnets, Science 335 (2012) 196.
57. S. Loth, K. v. Bergmann, C. P. Lutz, and A. J. Heinrich, Spinpolarized spin excitation spectroscopy, N. J. Phys. 12 (2010) 125021.
58. S. Loth, K. v. Bergmann, M. Ternes, A. F. Otte, C. P. Lutz, and A. J. Heinrich, Controlling the state of quantum spins with electric currents, Nat. Phys. 6 (2010) 340.
59. S. Loth, M. Etzkorn, C. P. Lutz, D. M. Eigler, and A. J. Heinrich, Measurement of fast electron spin relaxation times with atomic resolution, Science 329 (2010) 1628.
60. C. Carbone, M. Veronese, P. Moras, S. Gardonio, C. Grazioli, P. H. Zhou, O. Rader et al., Correlated electrons step by step:Itinerant-to-localized transition of Fe impurities in free-electron metal hosts, Phys. Rev. Lett. 104 (2010) 117601.
61. P. W. Anderson, Localized magnetic states in metals, Phys. Rev. 124 (1961) 41.
62. H. Brune, Microscopic view of epitaxial metal growth:nucleation and aggregation, Surf. Sci. Rep. 31 (1998) 121.
63. S. Blügel, Two-dimensional ferromagnetism of 3d, 4d, and 5d transition metal monolayers on noble metal (001) substrates, Phys. Rev. Lett. 68 (1992) 851.
64. P. Lang, V. S. Stepanyuk, K. Wildberger, R. Zeller, and P. H. Dederichs, Local moments of 3d, 4d, and 5d atoms at Cu and Ag(001) surfaces, Solid State Commun. 92 (1994) 755.
65. B. Nonas, I. Cabria, R. Zeller, P. H. Dederichs, T. Huhne, and H. Ebert, Strongly enhanced orbital moments and anisotropies of adatoms on the Ag(100) surface, Phys. Rev. Lett. 86 (2001) 2146.
66. S. Blügel, Magnetism goes nano: 36th IFF Spring School, In: S. Blügel, T. Brückel, C. M. Schneider eds., Ch. Reduced Dimensions I: Magnetic Moment and Magnetic Structure, Forschungszentrums Jülich, Jülich, 2005.
67. G. J. Nieuwenhuys, Magnetic behaviour of cobalt, iron and manganese dissolved in palladium, Adv. Phys. 24 (1975) 515.
68. Y. Yayon, X. H. Lu, and M. F. Crommie, Bimodal electronic structure of isolated Co atoms on Pt(111), Phys. Rev. B 73 (2006) 155401.
69. G. Kresse, M. Schmid, E. Napetschnig, M. Shishkin, L. Köhler, and P. Varga, Structure of the ultrathin aluminum oxide film on NiAl (110), Science 308 (2005) 1440.
70. H. Ellmer, V. Repain, M. Sotto, and S. Rousset, Prestructured metallic template for the growth of ordered, square-based nanodots, Surf. Sci. 511 (2002) 183.
71. B. Croset, Y. Girard, G. Prévot, M. Sotto, Y. Garreau, R. Pinchaux, and M. Sauvage-Simkin, Measuring surface stress discontinuities in self-organized systems with X rays, Phys. Rev. Lett. 88 (2002) 56103.
72. T. Choi, C. D. Ruggiero, and J. A. Gupta, Incommensurability and atomic structure of c(2 × 2)N/Cu(100): A scanning tunneling microscopy study, Phys. Rev. B 78 (2008) 035430.
73. D. M. Eigler, C. P. Lutz, and W. E. Rudge, An atomic switch realized with the scanning tunneling microscope, Nature 352 (1991) 600-603.
74. L. Bartels, G. Meyer, and K. H. Rieder, Basic steps of lateral manipulation of single atoms and diatomic clusters with a scanning tunneling microscope, Phys. Rev. Lett. 79 (1997) 697-700.
75. H. Brune, Assembly and probing of spin chains of finite size, Science 312 (2006) 1005.
76. N. Tsukahara, K. I. Noto, M. Ohara, S. Shiraki, N. Takagi, Y. Takata, J. Miyawaki, M. Taguchi, A. Chainani, S. Shin, and M. Kawai, Adsorption-induced switching of magnetic anisotropy in a single iron(II) phthalocyanine molecule on an oxidized Cu(110) surface, Phys. Rev. Lett. 102 (2009) 167203.
77. A. Mugarza and P. Gambardella, Orbital specific chirality and homochiral self-assembly of achiral molecules induced by charge transfer and spontaneous symmetry breaking, Phys. Rev. Lett. 105 (2010) 115702.
78. X. Chen, Y. S. Fu, S. H. Ji, T. Zhang, P. Cheng, X. C. Ma, X. L. Zou, W. H. Duan, J. F. Jia, and Q. K. Xue, Probing superexchange interaction in molecular magnets by spinflip spectroscopy and microscopy, Phys. Rev. Lett. 101 (2008) 197208.
79. K. Tao, V. S. Stepanyuk, W. Hergert, I. Rungger, S. Sanvito, and P. Bruno, Switching a single spin on metal surfaces by a STM tip: ab initio studies, Phys. Rev. Lett. 103 (2009) 057202.
80. F. Delgado, J. J. Palacios, and J. Fernandez-Rossier, Spintransfer torque on a single magnetic adatom, Phys. Rev. Lett. 104 (2010) 026601.
81. M. Bode, O. Pietzsch, A. Kubetzka, and R. Wiesendanger, Shape-dependent thermal switching behavior of superparamagnetic nanoislands, Phys. Rev. Lett. 92 (2004) 067201.
82. S. Krause, G. Herzog, T. Stapelfeldt, L. Berbil-Bautista, M. Bode, E. Y. Vedmedenko, and R. Wiesendanger, Magnetization reversal of nanoscale islands: How size and shape affect the arrhenius prefactor, Phys. Rev. Lett. 103 (2009) 127202.
83. S. Rusponi, T. Cren, N. Weiss, M. Epple, P. Buluschek, L. Claude, and H. Brune, The remarkable difference between surface and step atoms in the magnetic anisotropy of 2D nanostructures, Nat. Mater. 2 (2003) 546.
84. P. Gambardella, A. Dallmeyer, K. Maiti, M. C. Malagoli, W. Eberhardt, K. Kern, and C. Carbone, Ferromagnetism in one-dimensional monatomic metal chains, Nature 416 (2002) 301-304.
85. P. Gambardella, S. Stepanow, A. Dmitriev, J. Honolka, F. M. F. d. Groot, M. Lingenfelder, S. S. Gupta et al., Supramolecular control of the magnetic anisotropy in twodimensional high-spin Fe arrays at a metal interface, Nat. Mater. 8 (2009) 189.
86. M. Bernien, J. Miguel, C. Weis, M. E. Ali, J. Kurde, B. Krumme, P. M. Panchmatia et al., Tailoring the nature of magnetic coupling of Fe-porphyrin molecules to ferromagnetic substrates, Phys. Rev. Lett. 102 (2009) 047202.
87. S. Stepanow, J. Honolka, P. Gambardella, L. Vitali, N. Abdurakhmanova, T. C. Tseng, S. Rauschenbach et al., Spin and orbital magnetic moment anisotropies of monodispersed bis(phthalocyaninato) terbium on a copper surface, J. Am. Chem. Soc. 132 (2010) 11900.
88. A. Mugarza, R. Robles, C. Krull, R. Korytr, N. Lorente, and P. Gambardella, Electronic and magnetic properties of molecule-metal interfaces: Transition-metal phthalocyanines adsorbed on Ag(100), Phys. Rev. B 85 (2012) 155437.
89. S. Stepanow, P. S. Miedema, A. Mugarza, G. Ceballos, P. Moras, J. C. Cezar, C. Carbone, F. M. F. d. Groot, and P. Gambardella, Mixed-valence behavior and strong correlation effects of metal phthalocyanines adsorbed on metals, Phys. Rev. B 83 (2011) 220401.
90. M. A. Lingenfelder, H. Spillmann, A. Dmitriev, S. Stepanow, N. Lin, J. V. Barth, and K. Kern, Towards surface-supported supramolecular architectures: Tailored coordination assembly of 1,4-Benzenedicarboxylate and Fe on Cu(100), Chem. Eur. J 10 (2004) 1913.
91. S. Stepanow, N. Lin, and J. V. Barth, Modular assembly of low-dimensional coordination architectures on metal surfaces, J. Phys.: Condens. Matter 20 (2008) 184002.
92. L. Gao, W. Ji, Y. B. Hu, Z. H. Cheng, Z. T. Deng, Q. Liu, N. Jiang et al., Site-specific kondo effect at ambient temperatures in iron-based molecules, Phys. Rev. Lett. 99 (2007) 106402.
93. J. Brede, N. Atodiresei, S. Kuck, P. Lazic, V. Caciuc, Y. Morikawa, G. Hoffmann, S. Blügel, and R. Wiesendanger, Spin-and energy-dependent tunneling through a single molecule with intramolecular spatial resolution, Phys. Rev. Lett. 105 (2010) 047204.
94. R. Sessoli, D. Gatteschi, A. Caneschi, and M. A. Novak, Magnetic bistability in a metal-ion-cluster, Nature 365 (1993) 141.
95. L. Bogani and W. Wernsdorfer, Molecular spintronics using single-molecule magnets, Nat. Mater. 7 (2008) 179.
96. M. N. Leuenberger and D. Loss, Quantum computing in molecular magnets, Nature 410 (2001) 789.
97. N. Ishikawa, M. Sugita, T. Ishikawa, S. Koshihara, and Y. Kaizu, Lanthanide double-decker complexes functioning as magnets at the single-molecular level, J. Am. Chem. Soc. 125 (2003) 8694.
98. L. Margheriti, D. Chiappe, M. Mannini, P. Car, P. Sainctavit, M. A. Arrio, F. B. d. Mongeot et al., X-ray detected magnetic hysteresis of thermally evaporated terbium double-decker oriented films, Adv. Mater. 22 (2010) 5488.
99. R. Biagi, J. Fernandez-Rodriguez, M. Gonidec, A. Mirone, V. Corradini, F. Moro, V. De Renzi, U. del Pennino, J. C. Cezar, D. B. Amabilino, and J. Veciana, X-ray absorption and magnetic circular dichroism investigation of bis(phthalocyaninato) terbium single-molecule magnets deposited on graphite, Phys. Rev. B 82 (2010) 224406.
100. A. Scheybal, T. Ramsvik, R. Bertschinger, M. Putero, F. Nolting, and T. A. Jung, Induced magnetic ordering in a molecular monolayer, Chem. Phys. Lett. 411 (2005) 214.
101. C. Iacovita, M. V. Rastei, B. W. Heinrich, T. Brumme, J. Kortus, L. Limot, and J. P. Bucher, Visualizing the spin of individual cobalt-phthalocyanine molecules, Phys. Rev. Lett. 101 (2008) 116602.
102. S. Javaid, M. Bowen, S. Boukari, L. Joly, J. B. Beaufrand, X. Chen, Y. J. Dappe et al., Impact on interface spin polarization of molecular bonding to metallic surfaces, Phys. Rev. Lett. 105 (2010) 077201.