Platinum-based heterogeneous nanomaterials via wet-chemistry approaches toward electrocatalytic applications

Advances in Colloid and Interface Science

Volumn 230, Issue , 2016, Pages 29-53

  Qu, Jianglan ^a,b   Ye, Feng ^b   Chen, Dong ^b   Feng, Yan ^b   Yao, Qiaofeng ^c   Liu, Hui ^b   Xie, Jianping ^c   Yang, Jun ^b  

^a BEIJING UNIVERSITY OF AGRICULTURE   (China)

^b INSTITUTE OF GEOLOGY AND GEOPHYSICS   (China)

^c NATIONAL UNIVERSITY OF SINGAPORE   (Singapore)

Author keywords

Direct methanol fuel cell; Heterogeneous structure; Methanol oxidation reaction; Nanomaterials; Oxygen reduction reaction; Platinum

Indexed keywords

CONCRETE SLABS; ELECTROCATALYSTS; ELECTROLYTIC REDUCTION; ENERGY CONVERSION; FUEL CELLS; METHANOL; METHANOL FUELS; NANOSTRUCTURED MATERIALS; PLATINUM;

CATALYTIC PROPERTIES; COMPOSITE CONSTRUCTION; CONSTITUENT MATERIALS; HETEROGENEOUS STRUCTURES; METHANOL OXIDATION REACTIONS; OXYGEN REDUCTION REACTION; RESEARCH DEVELOPMENT; WET CHEMISTRY METHOD;

DIRECT METHANOL FUEL CELLS (DMFC);

EID: 84960084042     PISSN: 00018686     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.cis.2015.12.010     Document Type: Review

References (274)

1. E. Antolini Formation of carbon-supported PtM alloys for low temperature fuel cells: a review Mater Chem Phys 78 3 2003 563 573
2. L. Liu, C. Song, L. Zhang, J. Zhang, H. Wang, and D.P. Wilkinson A review of anode catalysis in the direct methanol fuel cell J Power Sources 155 2 2006 95 110
3. B.C.H. Steele, and A. Heinzel Review article materials for fuel-cell technologies Nature 414 6861 2001 345 352
4. M.L. Perry, and T.F. Fuller A historical perspective of fuel cell technology in the 20th century J Electrochem Soc 149 7 2002 S59 S67
5. J. Chen, B. Lim, E.P. Lee, and Y. Xia Shape-controlled synthesis of platinum nanocrystals for catalytic and electrocatalytic applications Nano Today 4 1 2009 81 95
6. Z. Peng, and H. Yang Designer platinum nanoparticles: control of shape, composition in alloy, nanostructure and electrocatalytic property Nano Today 4 2 2009 143 164
7. M. Yuasa, A. Yamaguchi, H. Itsuki, K. Tanaka, M. Yamamoto, and K. Oyaizu Modifying carbon particles with polypyrrole for adsorption of cobalt ions as electrocatatytic site for oxygen reduction Chem Mater 17 17 2005 4278 4281
8. S. Pylypenko, S. Mukherjee, S.T. Olson, and P. Atanassov Non-platinum oxygen reduction electrocatalysts based on pyrolyzed transition metal macrocycles Electrochim Acta 53 27 2008 7875 7883
9. M. Lefèvre, E. Proietti, F. Jaouen, and J.-P. Dodelet Iron-based catalysts with improved oxygen reduction activity in polymer electrolyte fuel cells Science 324 5923 2009 71 74
10. F. Jaouen, E. Proietti, M. Lefèvre, R. Chenitz, J.-P. Dodelet, G. Wu, and et al. Recent advances in non-precious metal catalysis for oxygen-reduction reaction in polymer electrolyte fuel cells Energy Environ Sci 4 1 2011 114 130
11. R.W. Reeve, P.A. Christensen, A. Hamnett, S.A. Haydock, and S.C. Roy Methanol tolerant oxygen reduction catalysts based on transition metal sulfides J Electrochem Soc 145 10 1998 3463 3471
12. 4, Ru/carbon, and Pt/carbon in pure and methanol-containing electrolytes J Electrochem Soc 147 7 2000 2620 2624
13. 2 electroreduction J Phys Chem C 111 28 2007 10508 10513
14. R. Parsons, and T. VanderNoot The oxidation of small organic molecules: a survey of recent fuel cell related research J Electroanal Soc 257 1 1988 9 45
15. E. Antolini, T. Lopes, and E.R. Gonzalez An overview of platinum-based catalysts as methanol-resistant oxygen reduction materials for direct methanol fuel cells J Alloys Compd 461 1 2008 253 262
16. N.M. Marković, and P.N. Ross Surface science studies of model fuel cell electrocatalysts Surf Sci Rep 45 4 2002 117 229
17. F.A. De Bruijn, V.A.T. Dam, and G.J.M. Janssen Review: durability and degradation issues of PEM fuel cell components Fuel Cells 8 1 2008 3 22
18. W. Chen, J. Kim, S. Sun, and S. Chen Electrocatalytic reduction of oxygen by FePt alloy nanoparticles J Phys Chem C 112 10 2008 3891 3898
19. C. Wang, H. Daimon, T. Onodera, T. Koda, and S. Sun A general approach to the size-and shape-controlled synthesis of platinum nanoparticles and their catalytic reduction of oxygen Angew Chem Int Ed 47 19 2008 3588 3591
20. Y. Kang, and C.B. Murray Synthesis and electrocatalytic properties of cubic Mn - Pt nanocrystals (nanocubes) J Am Chem Soc 132 22 2010 7568 7569
21. A. Chen, and P. Holt-Hindle Platinum-based nanostructured materials: synthesis, properties, and applications Chem Rev 110 6 2010 3767 3804
22. P.D. Cozzoli, T. Pellegrino, and L. Manna Synthesis, properties and perspectives of hybrid nanocrystal structures Chem Soc Rev 35 11 2006 1195 1208
23. J. Zhang, K. Sasaki, E. Sutter, and R.R. Adzic Stabilization of platinum oxygen-reduction electrocatalysts using gold clusters Science 315 5809 2007 220 222
24. L.-F. Zhang, S.-L. Zhong, and A.-W. Xu Highly branched concave Au/Pd bimetallic nanocrystals with superior electrocatalytic activity and highly efficient SERS enhancement Angew Chem Int Ed 52 2 2013 645 649
25. C.B. Murray, C.R. Kagan, and M.G. Bawendi Synthesis and characterization of monodisperse nanocrystals and close-packed nanocrystal assemblies Annu Rev Mater Sci 30 1 2000 545 610
26. M.C. Daniel, and D. Astruc Gold nanoparticles: assembly, supramolecular chemistry, quantum-size-related properties, and applications toward biology, catalysis, and nanotechnology Chem Rev 104 1 2004 293 346
27. C. Burda, X. Chen, R. Narayanan, and M.A. El-Sayed Chemistry and properties of nanocrystals of different shapes Chem Rev 105 4 2005 1025 1102
28. R. Ferrando, J. Jellinek, and R.L. Johnston Nanoalloys: from theory to applications of alloy clusters and nanoparticles Chem Rev 108 3 2008 845 910
29. S. Laurent, D. Forge, M. Port, A. Roch, C. Robic, L.V. Elst, and et al. Magnetic iron oxide nanoparticles: synthesis, stabilization, vectorization, physicochemical characterizations and biological applications Chem Rev 108 6 2008 2064 2110
30. R.W. Murray Nanoelectrochemistry: metal nanoparticles, nanoelectrodes, and nanopores Chem Rev 108 7 2008 2688 2720
31. Y. Xia, Y. Xiong, B. Lim, and S.E. Skrabalak Shape-controlled synthesis of metal nanocrystals: simple chemistry meets complex physics? Angew Chem Int Ed 48 1 2009 60 103
32. T. Novet, and D.C. Johnson New synthetic approach to extended solids: selective synthesis of iron silicides via the amorphous state J Am Chem Soc 113 9 1991 3398 3403
33. C. Suryanarayana Mechanical alloying and milling Prog Mater Sci 46 1 2001 1 184
34. J. Zhang, J. Teo, X. Chen, H. Asakura, T. Tanaka, K. Teramura, and et al. A series of NiM (M = Ru, Rh, and Pd) bimetallic catalysts for effective lignin hydrogenolysis in water ACS Catal 4 5 2014 1574 1583
35. J. Zhang, H. Asakura, J. van Rijn, J. Yang, P. Duchesne, B. Zhang, and et al. Highly efficient, NiAu-catalyzed hydrogenolysis of lignin into phenolic chemicals Green Chem 16 5 2014 2432 2437
36. S. Siankevich, G. Savoglidis, Z. Fei, G. Laurenczy, D.T.L. Alexander, N. Yang, and et al. A novel platinum nanocatalyst for the oxidation of 5-hydroxymethylfurfural into 2,5-furandicarboxylic acid under mild conditions J Catal 315 2014 67 74
37. L.A. Kibler, A.M. El-Aziz, R. Hoyer, and D.M. Kolb Tuning reaction rates by lateral strain in a palladium monolayer Angew Chem Int Ed 44 14 2005 2080 2084
38. V.R. Stamenkovic, B. Fowler, B.S. Mun, G. Wang, P.N. Ross, C.A. Lucas, and et al. Improved oxygen reduction activity on Pt3Ni (111) via increased surface site availability Science 315 5811 2007 493 497
39. V.R. Stamenkovic, B.S. Mun, M. Arenz, K.J. Mayrhofer, C.A. Lucas, G. Wang, and et al. Trends in electrocatalysis on extended and nanoscale Pt-bimetallic alloy surfaces Nat Mater 6 3 2007 241 247
40. D.F. van der Vliet, C. Wang, D. Li, A.P. Paulikas, J. Greeley, R.B. Rankin, and et al. Unique electrochemical adsorption properties of Pt-skin surfaces Angew Chem Int Ed 124 13 2012 3193 3196
41. C. Chen, Y. Kang, Z. Huo, Z. Zhu, W. Huang, H.L. Xin, and et al. Highly crystalline multimetallic nanoframes with three-dimensional electrocatalytic surfaces Science 343 6177 2014 1339 1343
42. V. Mazumder, M. Chi, K.L. More, and S. Sun Core/shell Pd/FePt nanoparticles as an active and durable catalyst for the oxygen reduction reaction J Am Chem Soc 132 23 2010 7848 7849
43. H. Yang Platinum-based electrocatalysts with core-shell nanostructures Angew Chem Int Ed 50 12 2011 2674 2676
44. W. Annan, P. Qing, and Y. Li Rod-shaped Au-Pd core-shell nanostructures Chem Mater 23 13 2011 3217 3222
45. M.J. Weber, A.J.M. Mackus, M.A. Verheijen, C. van der Marel, and W.M.M. Kessels Supported core/shell bimetallic nanoparticles synthesis by atomic layer deposition Chem Mater 24 15 2012 2973 2977
46. M.F. Cardinal, D. Mongin, A. Crut, P. Maioli, B. Rodríguez-González, J. Pérez-Juste, and et al. Acoustic vibrations in bimetallic Au@ Pd core-shell nanorods J Phys Chem Lett 3 5 2012 613 619
47. T.Y. Chen, T.J.M. Luo, Y.W. Yang, Y.-C. Wei, K.-W. Wang, T.-L. Lin, and et al. Core dominated surface activity of core-shell nanocatalysts on methanol electrooxidation J Phys Chem C 116 32 2012 16969 16978
48. K.A. Kuttiyiel, K. Sasaki, Y.M. Choi, D. Su, P. Liu, and R.R. Adzic Nitride stabilized PtNi core-shell nanocatalyst for high oxygen reduction activity Nano Lett 12 12 2012 6266 6271
49. 1-x nanoparticles and their impact on oxygen reduction catalysis Nano Lett 12 10 2012 5423 5430
50. M. Heggen, M. Oezaslan, L. Houben, and P. Strasser Formation and analysis of core-shell fine structures in Pt bimetallic nanoparticle fuel cell electrocatalysts J Phys Chem C 116 36 2012 19073 19083
51. M. Oezaslan, F. Hasché, and P. Strasser Pt-based core-shell catalyst architectures for oxygen fuel cell electrodes J Phys Chem Lett 4 19 2013 3273 3291
52. Q. Zhang, I. Lee, J.B. Joo, F. Zaera, and Y. Yin Core-shell nanostructured catalysts Acc Chem Res 46 8 2012 1816 1824
53. S.W. Kang, Y.W. Lee, Y. Park, B.S. Choi, J.W. Hong, K.H. Park, and et al. One-pot synthesis of trimetallic Au@PdPt core-shell nanoparticles with high catalytic performance ACS Nano 7 9 2013 7945 7955
54. S. Guo, S. Zhang, and S. Sun Tuning nanoparticle catalysis for the oxygen reduction reaction Angew Chem Int Ed 52 33 2013 8526 8544
55. L. Gan, C. Cui, S. Rudi, and P. Strasser Core-shell and nanoporous particle architectures and their effect on the activity and stability of Pt ORR electrocatalysts Top Catal 57 1-4 2014 236 244
56. X. Sun, D. Li, Y. Ding, W. Zhu, S. Guo, Z.L. Wang, and et al. Core/shell Au/CuPt nanoparticles and their dual electrocatalysis for both reduction and oxidation reactions J Am Chem Soc 136 15 2014 5745 5749
57. K. Tedsree, T. Li, S. Jones, C.W.A. Chan, K.M.K. Yu, P.A.J. Bagot, and et al. Hydrogen production from formic acid decomposition at room temperature using a Ag-Pd core-shell nanocatalyst Nat Nanotechnol 6 5 2011 302 307
58. S. Alayoglu, A.U. Nilekar, M. Mavrikakis, and B. Eichhorn Ru-Pt core-shell nanoparticles for preferential oxidation of carbon monoxide in hydrogen Nat Mater 7 4 2008 333 338
59. C.J. Serpell, J. Cookson, D. Ozkaya, and P.D. Beer Core@shell bimetallic nanoparticle synthesis via anion coordination Nat Chem 3 6 2011 478 483
60. J. Turkevich, and G. Kim Palladium: preparation and catalytic properties of particles of uniform size Science 169 3948 1970 873 879
61. L.O. Paz-Borbon, T.V. Mortimer-Jones, R.L. Johnston, A. Posada-Amarillas, G. Barcaro, and A. Fortunelli Structures and energetics of 98 atom Pd-Pt nanoalloys: potential stability of the Leary tetrahedron for bimetallic nanoparticles Phys Chem Chem Phys 9 38 2007 5202 5208
62. 3 nanoparticles as highly durable electrocatalyst Nano Lett 11 3 2011 919 926
63. R. Narayanan, and M.A. El-Sayed Shape-dependent catalytic activity of platinum nanoparticles in colloidal solution Nano Lett 4 7 2004 1343 1348
64. S.E. Habas, H. Lee, V. Radmilovic, G.A. Somorjai, and P. Yang Shaping binary metal nanocrystals through epitaxial seeded growth Nat Mater 6 9 2007 692 697
65. C. Wang, H. Daimon, Y. Lee, J. Kim, and S. Sun Synthesis of monodisperse Pt nanocubes and their enhanced catalysis for oxygen reduction J Am Chem Soc 129 22 2007 6974 6975
66. R. Narayanan, and M.A. El-Sayed Changing catalytic activity during colloidal platinum nanocatalysis due to shape changes: electron-transfer reaction J Am Chem Soc 126 23 2004 7194 7195
67. N. Tian, Z.Y. Zhou, S.G. Sun, Y. Ding, and Z.L. Wang Synthesis of tetrahexahedral platinum nanocrystals with high-index facets and high electro-oxidation activity Science 316 5825 2007 732 735
68. C. Li, R. Sato, M. Kanehara, H. Zeng, Y. Bando, and T. Teranishi Controllable polyol synthesis of uniform palladium icosahedra: effect of twinned structure on deformation of crystalline lattices Angew Chem Int Ed 121 37 2009 7015 7019
69. J.X. Wang, H. Inada, L. Wu, Y. Zhu, Y. Choi, P. Liu, and et al. Oxygen reduction on well-defined core-shell nanocatalysts: particle size, facet, and Pt shell thickness effects J Am Chem Soc 131 47 2009 17298 17302
70. Y. Tang, and M. Ouyang Tailoring properties and functionalities of metal nanoparticles through crystallinity engineering Nat Mater 6 10 2007 754 759
71. Q. Zhang, J. Xie, J. Yang, and J.Y. Lee Monodisperse icosahedral Ag, Au, and Pd nanoparticles: size control strategy and superlattice formation ACS Nano 3 1 2008 139 148
72. J. Yang, J. Yang, and J.Y. Ying Morphology and lateral strain control of Pt nanoparticles via core-shell construction using alloy AgPd core toward oxygen reduction reaction ACS Nano 6 11 2012 9373 9382
73. H. Li, Q. Xin, W. Li, Z.H. Zhou, L.H. Jiang, S.H. Yang, and et al. An improved palladium-based DMFCs cathode catalyst Chem Commun 23 2004 2776 2777
74. T. Bligaard, and J.K. Norskov Ligand effects in heterogeneous catalysis and electrochemistry Electrochim Acta 52 18 2007 5512 5516
75. 2 on Pt-Co and Pt-Fe alloys J Am Chem Soc 126 14 2004 4717 4725
76. H. Ataee-Esfahani, L. Wang, Y. Nemoto, and Y. Yamauchi Synthesis of bimetallic Au@ Pt nanoparticles with Au core and nanostructured Pt shell toward highly active electrocatalysts Chem Mater 22 23 2010 6310 6318
77. D. Aberdam, R. Durand, R. Faure, and F. El-Omar Structural changes of a Pt(111) electrode induced by electrosorption of oxygen in acidic solutions: a coupled voltammetry, LEED and AES study Surf Sci 171 2 1986 303 330
78. F.T. Wagner, and P.N. Ross Long-range structural effects in the anomalous voltammetry on ultra-high vacuum prepared Pt(111) J Electroanal Chem Interfacial Electrochem 250 2 1988 301 320
79. B.E. Conway Electrochemical oxide film formation at noble metals as a surface-chemical process Prog Surf Sci 49 4 1995 331 452
80. N. Furuya, and M. Shibata Structural changes at various Pt single crystal surfaces with potential cycles in acidic and alkaline solutions J Electroanal Chem 467 1999 85 91
81. A. Björling, E. Ahlberg, and J.M. Feliu Kinetics of surface modification induced by submonolayer electrochemical oxygen adsorption on Pt(111) Electrochem Commun 12 2010 359 361
82. A.M. Gómez-Marín, and J.M. Feliu Pt(111) surface disorder kinetics in perchloric acid solutions and the influence of specific anion adsorption Electrochim Acta 82 2012 558 569
83. F. Rubio-Marcos, A. Del Campo, P. Marchet, and J.F. Fernández Ferroelectric domain wall motion induced by polarized light Nat Commun 6 2015 6594
84. H. Liang, H. Zhang, J. Hu, Y. Guo, L. Wan, and C. Bai Pt hollow nanospheres: facile synthesis and enhanced electrocatalysts Angew Chem Int Ed 43 12 2004 1540 1543
85. J. Yang, J.Y. Lee, H.P. Too, and S. Valiyaveettil A bis (p-sulfonatophenyl) phenylphosphine-based synthesis of hollow Pt nanospheres J Phys Chem B 110 1 2006 125 129
86. G. Chen, D. Xia, Z. Nie, Z. Wang, L. Wang, L. Zhang, and et al. Facile synthesis of Co-Pt hollow sphere electrocatalyst Chem Mater 19 7 2007 1840 1844
87. H.M. Chen, R.S. Liu, M.Y. Lo, S.C. Chang, L.D. Tsai, Y.M. Peng, and et al. Hollow platinum spheres with Nano-channels: synthesis and enhanced catalysis for oxygen reduction J Phys Chem C 112 20 2008 7522 7526
88. S. Guo, S. Dong, and E. Wang A general method for the rapid synthesis of hollow metallic or bimetallic nanoelectrocatalysts with urchinlike morphology Chem Eur J 14 15 2008 4689 4695
89. C. Xu, L. Wang, R. Wang, K. Wang, Y. Zhang, F. Tian, and et al. Nanotubular mesoporous bimetallic nanostructures with enhanced electrocatalytic performance Adv Mater 21 21 2009 2165 2169
90. J. Yang, E. Sargent, S. Kelley, and J.Y. Ying A general phase-transfer protocol for metal ions and its application in nanocrystal synthesis Nat Mater 8 8 2009 683 689
91. Z. Peng, J. Wu, and H. Yang Synthesis and oxygen reduction electrocatalytic property of platinum hollow and platinum-on-silver nanoparticles Chem Mater 22 3 2009 1098 1106
92. F. Bai, Z. Sun, H. Wu, R.E. Haddad, X. Xiao, and H. Fan Templated photocatalytic synthesis of well-defined platinum hollow nanostructures with enhanced catalytic performance for methanol oxidation Nano Lett 11 9 2011 3759 3762
93. 2 yolk/shell structure for catalytic reduction of p-nitrophenol Adv Mater 20 8 2008 1523 1528
94. D. Van Gough, A. Wolosiuk, and P.V. Braun Mesoporous ZnS nanorattles: programmed size selected access to encapsulated enzymes Nano Lett 9 5 2009 1994 1998
95. J. Liu, S.Z. Qiao, S. Budi Hartono, and G.Q.M. Lu Monodisperse yolk-shell nanoparticles with a hierarchical porous structure for delivery vehicles and nanoreactors Angew Chem Int Ed 122 29 2010 5101 5105
96. 2 yolk-shell nanocrystals as a potent agent to kill HeLa cells J Am Chem Soc 129 5 2007 1428 1433
97. W. Zhao, H. Chen, Y. Li, L. Li, M. Lang, and J. Shi Uniform rattle-type hollow magnetic mesoporous spheres as drug delivery carriers and their sustained-release property Adv Funct Mater 18 18 2008 2780 2788
98. 2 hollow mesoporous spheres as carriers for drug delivery Small 6 3 2010 471 478
99. W.M. Zhang, J.S. Hu, Y.G. Guo, S.F. Zheng, L.S. Zhong, W.G. Song, and et al. Tin-nanoparticles encapsulated in elastic hollow carbon spheres for high-performance anode material in lithium-ion batteries Adv Mater 20 6 2008 1160 1165
100. 2@carbon hollow nanospheres for highly reversible lithium storage Adv Mater 21 2009 2536 2539
101. 2nanorattles with large void space and their lithium storage properties Nanoscale 1 2 2009 280 285
102. 2 nanosheets with enhanced lithium storage properties Chem Commun 46 43 2010 8252 8254
103. 2 hollow structures with enhanced lithium storage capabilities Nanoscale 3 5 2011 2158 2161
104. H. Li, Z. Bian, J. Zhu, D. Zhang, G. Li, Y. Huo, and et al. Mesoporous titania spheres with tunable chamber structure and enhanced photocatalytic activity J Am Chem Soc 129 27 2007 8406 8407
105. F. Benabid, F. Couny, J.C. Knight, T.A. Birks, and P.J. Russell Compact, stable and efficient all-fibre gas cells using hollow-core phoyonic crystal fibres Nature 434 7032 2005 488 491
106. F. Caruso, R.A. Caruso, and H. Möhwald Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating Science 282 5391 1998 1111 1114
107. F. Caruso, X. Shi, R.A. Caruso, and A. Susha Hollow titania spheres from layered precursor deposotion on sacrificial colloidal core particles Adv Mater 13 10 2001 740 744
108. Z. Yang, Z. Niu, Y. Lu, Z. Hu, and C.C. Han Templated synthesis of inorganic hollow spheres with a tunable cavity size onto core-shell gel particles Agnew Chem Int Ed 115 17 2003 1987 1989
109. X.W. Lou, C. Yuan, and L.A. Archer Shell-by-shell synthesis of tin oxide hollow colloids with nanoarchitectured walls: cavity size tuning and functionalization Small 3 2 2007 261 265
110. 2 nanoboxes with enhanced lithium storage capability J Am Chem Soc 133 13 2011 4738 4741
111. X. Lai, J. Li, B.A. Korgel, Z. Dong, Z. Li, F. Su, and et al. General synthesis and gas-sensing properties of multiple-shell metal oxide hollow microspheres Angew Chem Int Ed 50 12 2011 2738 2741
112. H.T. Schmidt, and A.E. Ostafin Liposome directed growth of calcium phosphate nanoshells Adv Mater 14 7 2002 532 535
113. D.H.W. Hubert, M. Jung, and A.L. German Vesicle templating Adv Mater 12 17 2000 1291 1294
114. X. Gao, J. Zhang, and L. Zhang Hollow sphere selenium nanoparticles: their in-vitro anti hydroxyl radical effect Adv Mater 14 4 2002 290 293
115. 2 microspheres in ionic liquids J Am Chem Soc 125 21 2003 6386 6387
116. L. Qi, J. Li, and J. Ma Biomimetic morphogenesis of calcium carbonate in mixed solutions if surfactants and double-hydrophilic block copolymers Adv Mater 14 4 2002 300 303
117. D. Zhang, L. Qi, J. Ma, and H. Cheng Synthesis of submicrometer-sized hollow silver spheres in mixed polymer-surfactant solutions Adv Mater 14 20 2002 1499 1502
118. M.S. Wong, J.N. Cha, K.-S. Choi, T.J. Deming, and G.D. Stucky Assembly of nanoparticles into hollow spheres using block copolypeptides Nano Lett 2 6 2002 583 587
119. X.W.D. Lou, L.A. Archer, and Z. Yang Hollow micro -/nanostructures: synthesis and applications Adv Mater 20 21 2008 3987 4019
120. Y. Zhao, and L. Jiang Hollow micro/nanomaterials with multilevel interior structures Adv Mater 21 36 2009 3621 3638
121. Y. Sun, B.T. Mayers, and Y. Xia Template-engaged replacement reaction: a one-step approach to the large-scale synthesis of metal nanostructures with hollow interiors Nano Lett 2 5 2002 481 485
122. Y. Sun, and Y. Xia Mechanistic study on the replacement reaction between silver nanostructures and chloroauric acid in aqueous medium J Am Chem Soc 126 12 2004 3892 3901
123. J. Chen, B. Wiley, J. McLellan, Y. Xiong, Z.-Y. Li, and Y. Xia Optical properties of Pd-Ag and Pt-Ag nanoboxes synthesized via galvanic replacement reactions Nano Lett 5 10 2005 2058 2062
124. M. Chen, and L. Gao Synthesis and characterization of Ag nanoshells by a facile sacrificial template route through in situ replacement reaction Inorg Chem 45 13 2006 5145 5149
125. S.E. Skrabalak, J. Chen, Y. Sun, X. Lu, L. Au, C.M. Cobley, and et al. Gold nanocages: synthesis, properties, and applications Acc Chem Res 41 12 2008 1587 1595
126. H. Zhang, M. Jin, J. Wang, W. Li, P.H. Camargo, M.J. Kim, and et al. Synthesis of Pd-Pt bimetallic nanocrystals with a concave structure through a bromide-induced galvanic replacement reaction J Am Chem Soc 133 15 2011 6078 6089
127. M. Mohl, D. Dobo, A. Kukovecz, Z. Konya, K. Kordas, J. Wei, and et al. Formation of CuPd and CuPt bimetallic nanotubes by galvanic replacement reaction J Phys Chem C 115 19 2011 9403 9409
128. E. González, J. Arbiol, and V.F. Puntes Carving at the nanoscale: sequential galvanic exchange and kirkendall growth at room temperature Science 334 6061 2011 1377 1380
129. Y. Yin, R.M. Rioux, C.K. Erdonmez, S. Hughes, G.A. Somorjai, and A.P. Alivisatos Formation of hollow nanocrystals through the nanoscale kirkendall effect Science 304 5671 2004 711 714
130. H.C. Zeng Synthetic architecture of interior space for inorganic nanostructures J Mater Chem 16 7 2006 649 662
131. Z.H. Chun Ostwald ripening: a synthetic approach for hollow nanomaterials Curr Nanosci 3 2 2007 177 181
132. F. Caruso Hollow capsule processing through colloidal templating and self - assembly Chem Eur J 6 3 2000 413 419
133. J.E. Macdonald, M.B. Sadan, L. Houben, I. Popov, and U. Banin Hybrid nanoscale inorganic cages Nat Mater 9 10 2010 810 815
134. C. Chen, Y. Kang, Z. Huo, Z. Zhu, W. Huang, H.L. Xin, and et al. Highly crystalline multimetallic nanoframes with three-dimensional electrocatalytic surfaces Science 343 6177 2014 1339 1343
135. 3Pt nanoframes through the structure evolution in Cu-Pt nanoparticles with a core-shell construction Sci Rep 4 2014 6414
136. 2 shell structures using surfactant mixtures as template J Am Chem Soc 131 8 2009 2774 2775
137. G. Li, Q. Shi, S. Yuan, K. Neoh, E. Kang, and X. Yang Alternating silica/polymer multilayer hybrid microspheres templates for double-shelled polymer and inorganic hollow microstructures Chem Mater 22 4 2010 1309 1317
138. H. Liu, J. Qu, Y. Chen, J. Li, F. Ye, J.Y. Lee, and et al. Hollow and cage-bell structured nanomaterials of noble metals J Am Chem Soc 134 28 2012 11602 11610
139. H.A. Gasteiger, N. Marković, P.N. Ross, and E.J. Cairns Methanol electrooxidation on well-characterized platinum-ruthenium bulk alloys J Phys Chem 97 46 1993 12020 12029
140. J. Wang, S. Brankovic, Y. Zhu, J. Hanson, and R. Adžić Kinetic characterization of PtRu fuel cell anode catalysts made by spontaneous Pt deposition on Ru nanoparticles J Electrochem Soc 150 8 2003 A1108-A1117
141. 25 (M = Co, Ni) alloys as anode and cathode electrocatalysts for direct methanol fuel cells J Electroanal Chem 580 1 2005 145 154
142. H. Liu, F. Ye, and J. Yang A universal and cost-effective approach to the synthesis of carbon-supported noble metal nanoparticles with hollow interiors Ind Eng Chem Res 53 14 2014 5925 5931
143. L. Wang, and Y. Yamauchi Metallic nanocages: synthesis of bimetallic Pt-Pd hollow nanoparticles with dendritic shells by selective chemical etching J Am Chem Soc 135 45 2013 16762 16765
144. K. Beard, D. Borrelli, A.M. Cramer, D. Blom, J. Van Zee, and J.R. Monnier Preparation and structural analysis of carbon-supported Co core/Pt shell electrocatalysts using electroless deposition methods ACS Nano 3 9 2009 2841 2853
145. M.R. Langille, J. Zhang, and C.A. Mirkin Plasmon-mediated synthesis of heterometallic nanorods and icosahedra Angew Chem Int Ed 50 15 2011 3543 3547
146. S. Zhou, K. McIlwrath, G. Jackson, and B. Eichhorn Enhanced CO tolerance for hydrogen activation in Au-Pt dendritic heteroaggregate nanostructures J Am Chem Soc 128 6 2006 1780 1781
147. H. Lee, S.E. Habas, G.A. Somorjai, and P. Yang Localized Pd overgrowth on cubic Pt nanocrystals for enhanced electrocatalytic oxidation of formic acid J Am Chem Soc 130 16 2008 5406 5407
148. Z. Peng, and H. Yang PtAu bimetallic heteronanostructures made by post-synthesis modification of Pt-on-Au nanoparticles Nano Res 2 5 2009 406 415
149. B. Lim, H. Kobayashi, T. Yu, J. Wang, M.J. Kim, Z.-Y. Li, and et al. Synthesis of Pd-Au bimetallic nanocrystals via controlled overgrowth J Am Chem Soc 132 8 2010 2506 2507
150. F. Wang, C. Li, L.-D. Sun, H. Wu, T. Ming, J. Wang, and et al. Heteroepitaxial growth of high-index-faceted palladium nanoshells and their catalytic performance J Am Chem Soc 133 4 2010 1106 1111
151. F.-R. Fan, D.-Y. Liu, Y.-F. Wu, S. Duan, Z.-X. Xie, Z.-Y. Jiang, and et al. Epitaxial growth of heterogeneous metal nanocrystals: from gold nano-octahedra to palladium and silver nanocubes J Am Chem Soc 130 22 2008 6949 6951
152. J. Zeng, C. Zhu, J. Tao, M. Jin, H. Zhang, Z.Y. Li, and et al. Controlling the nucleation and growth of silver on palladium nanocubes by manipulating the reaction kinetics Angew Chem Int Ed 51 10 2012 2354 2358
153. B. Lim, M. Jiang, P.H. Camargo, E.C. Cho, J. Tao, X. Lu, and et al. Pd-Pt bimetallic nanodendrites with high activity for oxygen reduction Science 324 5932 2009 1302 1305
154. Z. Peng, and H. Yang Synthesis and oxygen reduction electrocatalytic property of Pt-on-Pd bimetallic heteronanostructures J Am Chem Soc 131 22 2009 7542 7543
155. S. Guo, S. Dong, and E. Wang Three-dimensional Pt-on-Pd bimetallic nanodendrites supported on graphene nanosheet: facile synthesis and used as an advanced nanoelectrocatalyst for methanol oxidation ACS Nano 4 1 2009 547 555
156. L. Wang, Y. Nemoto, and Y. Yamauchi Direct synthesis of spatially-controlled Pt-on-Pd bimetallic nanodendrites with superior electrocatalytic activity J Am Chem Soc 133 25 2011 9674 9677
157. Y. Kim, J.W. Hong, Y.W. Lee, M. Kim, D. Kim, W.S. Yun, and et al. Synthesis of AuPt heteronanostructures with enhanced electrocatalytic activity toward oxygen reduction Angew Chem Int Ed 122 52 2010 10395 10399
158. L. Wang, and Y. Yamauchi Block copolymer mediated synthesis of dendritic platinum nanoparticles J Am Chem Soc 131 26 2009 9152 9153
159. Y. Feng, H. Liu, and J. Yang Bimetallic nanodendrites via selective overgrowth of noble metals on multiply twinned Au seeds J Mater Chem A 2 17 2014 6130 6137
160. H. Liu, F. Ye, Q. Yao, H. Cao, J. Xie, J.Y. Lee, and et al. Stellated Ag-Pt bimetallic nanoparticles: an effective platform for catalytic activity tuning Sci Rep 4 2014 3969
161. Z. Wang Transmission electron microscopy of shape-controlled nanocrystals and their assemblies J Phys Chem B 104 6 2000 1153 1175
162. S.H. Brodersen, U. Gronbjerg, B. Hvolbæk, and J. Schiotz Understanding the catalytic activity of gold nanoparticles through multi-scale simulations J Catal 284 1 2011 34 41
163. B. Wiley, T. Herricks, Y. Sun, and Y. Xia Polyol synthesis of silver nanoparticles: use of chloride and oxygen to promote the formation of single-crystal, truncated cubes and tetrahedrons Nano Lett 4 9 2004 1733 1739
164. 3-Au nanocrystals with tunable domain size J Am Chem Soc 128 20 2006 6690 6698
165. J.-S. Choi, H.J. Choi, D.C. Jung, J.-H. Lee, and J. Cheon Nanoparticle assisted magnetic resonance imaging of the early reversible stages of amyloid β self-assembly Chem Commun 19 2008 2197 2199
166. C. Wang, W. Tian, Y. Ding, Y. Ma, Z.L. Wang, N.M. Markovic, and et al. Rational synthesis of heterostructured nanoparticles with morphology control J Am Chem Soc 132 18 2010 6524 6529
167. L. Bai, Y. Kuang, J. Luo, D.G. Evans, and X. Sun Ligand-manipulated selective transformations of Au-Ni bimetallic heteronanostructures in an organic medium Chem Commun 48 55 2012 6963 6965
168. S.I. Lim, M. Varon, I. Ojea-Jiménez, J. Arbiol, and V. Puntes Pt nanocrystal evolution in the presence of Au (III)-salts at room temperature: spontaneous formation of AuPt heterodimers J Mater Chem 21 31 2011 11518 11523
169. J. Yang, J.Y. Lee, L. Chen, and H.-P. Too A phase-transfer identification of core-shell structures in Ag-Pt nanoparticles J Phys Chem B 109 12 2005 5468 5472
170. J. Luo, L. Wang, D. Mott, P.N. Njoki, Y. Lin, T. He, and et al. core/shell nanoparticles as electrocatalysts for fuel cell reactions Adv Mater 20 22 2008 4342 4347
171. 3Fe (111) single-crystal alloy J Am Chem Soc 131 35 2009 12755 12762
172. J. Yang, X. Chen, X. Yang, and J.Y. Ying Stabilization and compressive strain effect of AuCu core on Pt shell for oxygen reduction reaction Energy Environ Sci 5 10 2012 8976 8981
173. H. Liu, and J. Yang Bimetallic Ag-hollow Pt heterodimers via inside-out migration of Ag in core-shell Ag-Pt nanoparticles at elevated temperature J Mater Chem A 2 19 2014 7075 7081
174. J. Zhang, M.B. Vukmirovic, K. Sasaki, A.U. Nilekar, M. Mavrikakis, and R.R. Adzic Mixed-metal Pt monolayer electrocatalysts for enhanced oxygen reduction kinetics J Am Chem Soc 127 36 2005 12480 12481
175. J. Zhang, M.B. Vukmirovic, Y. Xu, M. Mavrikakis, and R.R. Adzic Controlling the catalytic activity of platinum-monolayer electrocatalysts for oxygen reduction with different substrates Angew Chem Int Ed 44 14 2005 2132 2135
176. T. Mokari, E. Rothenberg, I. Popov, R. Costi, and U. Banin Selective growth of metal tips onto semiconductor quantum rods and tetrapods Science 304 5678 2004 1787 1790
177. W. Shi, H. Zeng, Y. Sahoo, T.Y. Ohulchanskyy, Y. Ding, Z.L. Wang, and et al. A general approach to binary and ternary hybrid nanocrystals Nano Lett 6 4 2006 875 881
178. J. Yang, L. Levina, E.H. Sargent, and S.O. Kelley Heterogeneous deposition of noble metals on semiconductor nanoparticles in organic or aqueous solvents J Mater Chem 16 41 2006 4025 4028
179. R. Costi, A.E. Saunders, E. Elmalem, A. Salant, and U. Banin Visible light-induced charge retention and photocatalysis with hybrid CdSe-Au nanodumbbells Nano Lett 8 2 2008 637 641
180. E. Elmalem, A.E. Saunders, R. Costi, A. Salant, and U. Banin Growth of photocatalytic CdSe-Pt nanorods and nanonets Adv Mater 20 22 2008 4312 4317
181. S.E. Habas, P. Yang, and T. Mokari Selective growth of metal and binary metal tips on CdS nanorods J Am Chem Soc 130 11 2008 3294 3295
182. 2S and its nanocomposites with gold Chem Commun 22 2009 3187 3189
183. 2S nanocrystals J Am Chem Soc 132 7 2010 2114 2115
184. J. Zhang, Y. Tang, K. Lee, and M. Ouyang Tailoring light-matter-spin interactions in colloidal hetero-nanostructures Nature 466 7302 2010 91 95
185. J. Zhang, Y. Tang, K. Lee, and M. Ouyang Nonepitaxial growth of hybrid core-shell nanostructures with large lattice mismatches Science 327 5973 2010 1634 1638
186. N. Zhao, L. Li, T. Huang, and L. Qi Controlled synthesis of PbS-Au nanostar-nanoparticle heterodimers and cap-like Au nanoparticles Nanoscale 2 11 2010 2418 2423
187. L. Carbone, and P.D. Cozzoli Colloidal heterostructured nanocrystals: synthesis and growth mechanisms Nano Today 5 5 2010 449 493
188. M. Li, X.F. Yu, S. Liang, X.N. Peng, Z.J. Yang, Y.L. Wang, and et al. Synthesis of Au-CdS core-shell hetero-nanorods with efficient exciton-Plasmon interactions Adv Funct Mater 21 10 2011 1788 1794
189. 2S and Au nanocrystals at room temperature J Mater Chem 21 32 2011 11750 11753
190. 2S and noble metals Angew Chem Int Ed 50 20 2011 4637 4643
191. J. Yang, X. Chen, F. Ye, C. Wang, Y. Zheng, and J. Yang Core-shell CdSe@ Pt nanocomposites with superior electrocatalytic activity enhanced by lateral strain effect J Mater Chem 21 25 2011 9088 9094
192. W. Hu, H. Liu, F. Ye, Y. Ding, and J. Yang A facile solution route for the synthesis of PbSe-Au nanocomposites with different morphologies CrystEngComm 14 20 2012 7049 7054
193. K.K. Haldar, G. Sinha, J. Lahtinen, and A. Patra Hybrid colloidal Au-CdSe pentapod heterostructures synthesis and their photocatalytic properties ACS Appl Mater Interfaces 4 11 2012 6266 6272
194. 2S heterodimer formation via oxidization of AuCu alloy nanoparticles and in situ formed copper thiolate J Mater Chem 22 43 2012 23169 23174
195. 2S heterodimers via chemically triggered phase segregation of AuCu nanoparticles Chem Mater 24 9 2012 1552 1554
196. 2S nanoparticles: from cages to nanonets Chem Mater 24 10 2012 1822 1827
197. D. Wang, X. Li, H. Li, L. Li, X. Hong, Q. Peng, and et al. Semiconductor-noble metal hybrid nanomaterials with controlled structures J Mater Chem A 1 5 2013 1587 1590
198. X. Ding, Y. Zou, F. Ye, J. Yang, and J. Jiang Pt-CuS heterodimers by sulfidation of CuPt alloy nanoparticles and their selective catalytic activity toward methanol oxidation J Mater Chem A 1 38 2013 11880 11886
199. A. Sitt, I. Hadar, and U. Banin Band-gap engineering, optoelectronic properties and applications of colloidal heterostructured semiconductor nanorods Nano Today 8 5 2013 494 513
200. Q. Zhao, M. Ji, H. Qian, B. Dai, L. Weng, J. Gui, and et al. Controlling structural symmetry of a hybrid nanostructure and its effect on efficient photocatalytic hydrogen evolution Adv Mater 26 9 2014 1387 1392
201. 2S nanocrystals yielding hybrid nanoscale inorganic cages and their synergistic properties CrystEngComm 16 40 2014 9506 9512
202. U. Banin, Y. Ben-Shahar, and K. Vinokurov Hybrid semiconductor-metal nanoparticles: from architecture to function Chem Mater 26 1 2013 97 110
203. T. Mokari, C.G. Sztrum, A. Salant, E. Rabani, and U. Banin Formation of asymmetric one-sided metal-tipped semiconductor nanocrystal dots and rods Nat Mater 4 11 2005 855 863
204. A.E. Saunders, I. Popov, and U. Banin Synthesis of hybrid CdS-Au colloidal nanostructures J Phys Chem B 110 50 2006 25421 25429
205. T. Mokari, A. Aharoni, I. Popov, and U. Banin Diffusion of gold into InAs nanocrystals Angew Chem Int Ed 45 47 2006 8001 8005
206. J. Yang, H.I. Elim, Q. Zhang, J.Y. Lee, and W. Ji Rational synthesis, self-assembly, and optical properties of PbS-Au heterogeneous nanostructures via preferential deposition J Am Chem Soc 128 36 2006 11921 11926
207. D.V. Talapin, H. Yu, E.V. Shevchenko, A. Lobo, and C.B. Murray Synthesis of colloidal PbSe/PbS core-shell nanowires and PbS/Au nanowire-nanocrystal heterostructures J Phys Chem C 111 38 2007 14049 14054
208. G. Menagen, D. Mocatta, A. Salant, I. Popov, D. Dorfs, and U. Banin Selective gold growth on CdSe seeded CdS nanorods Chem Mater 20 22 2008 6900 6902
209. S. Huang, J. Huang, J. Yang, J.J. Peng, Q. Zhang, F. Peng, and et al. Chemical synthesis, structure characterization, and optical properties of hollow PbSx-solid Au heterodimer nanostructures Chem Eur J 16 20 2010 5920 5926
210. J. Yang, J.Y. Lee, and J.Y. Ying Phase transfer and its applications in nanotechnology Chem Soc Rev 40 3 2011 1672 1696
211. M. Brust, M. Walker, D. Bethell, D.J. Schiffrin, and R. Whyman Synthesis of thiol-derivatised gold nanoparticles in a two-phase liquid-liquid system J Chem Soc Chem Commun 7 1994 801 802
212. H. Liu, Y. Feng, D. Chen, C. Li, P. Cui, and J. Yang Noble metal-based composite nanomaterials fabricated via solution-based approaches J Mater Chem A 3 7 2015 3182 3223
213. G. Dukovic, M.G. Merkle, J.H. Nelson, S.M. Hughes, and A.P. Alivisatos Photodeposition of Pt on colloidal CdS and CdSe/CdS semiconductor nanostructures Adv Mater 20 22 2008 4306 4311
214. J.R. Harbour, R. Wolkow, and M.L. Hair Effect of platinization on the photoproperties of cadmium sulfide pigments in dispersion. Determination by hydrogen evolution, oxygen uptake, and electron spin resonance spectroscopy J Phys Chem 85 26 1981 4026 4029
215. J.F. Reber, and M. Rusek Photochemical hydrogen production with platinized suspensions of cadmium sulfide and cadmium zinc sulfide modified by silver sulfide J Phys Chem 90 5 1986 824 834
216. A.J. Frank, Z. Goren, and I. Willner Photohydrogenation of acetylene and ethylene by Pt and Rh supported on CdS semiconductor particles J Chem Soc Chem Commun 15 1985 1029 1030
217. J.-S. Lee, E.V. Shevchenko, and D.V. Talapin Au-PbS core-shell nanocrystals: plasmonic absorption enhancement and electrical doping via intra-particle charge transfer J Am Chem Soc 130 30 2008 9673 9675
218. H.B. Michaelson The work function of the elements and its periodicity J Appl Phys 48 11 1977 4729 4733
219. 2 reduction Electrochim Acta 29 11 1984 1527 1537
220. A. Arico, S. Srinivasan, and V. Antonucci DMFCs: from fundamental aspects to technology development Fuel Cells 1 2 2001 133 161
221. T. Toda, H. Igarashi, H. Uchida, and M. Watanabe Enhancement of the electroreduction of oxygen on Pt alloys with Fe, Ni, and Co J Electrochem Soc 146 10 1999 3750 3756
222. C. Xu, and D. Goodman Adsorption and reaction of formic acid on a pseudomorphic palladium monolayer on Mo (110) J Phys Chem 100 1 1996 245 252
223. M. Baldauf, and D. Kolb Formic acid oxidation on ultrathin Pd films on Au (hkl) and Pt (hkl) electrodes J Phys Chem 100 27 1996 11375 11381
224. L. Kibler, and D. Kolb Physical electrochemistry: recent developments Z Phys Chem 217 10 2003 1265 1280
225. S. Kumar, and S. Zou Electrooxidation of carbon monoxide and methanol on platinum-overlayer-coated gold nanoparticles: effects of film thickness Langmuir 23 13 2007 7365 7371
226. H. Naohara, S. Ye, and K. Uosaki Electrocatalytic reactivity for oxygen reduction at epitaxially grown Pd thin layers of various thickness on Au (111) and Au (100) Electrochim Acta 45 20 2000 3305 3309
227. H. Naohara, S. Ye, and K. Uosaki Thickness dependent electrochemical reactivity of epitaxially electrodeposited palladium thin layers on Au (111) and Au (100) surfaces J Electroanal Chem 500 1 2001 435 445
228. A. El-Aziz, and L. Kibler Influence of steps on the electrochemical oxidation of CO adlayers on Pd (111) and on Pd films electrodeposited onto Au (111) J Electroanal Chem 534 2 2002 107 114
229. L. Kibler, A. El-Aziz, and D. Kolb Electrochemical behaviour of pseudomorphic overlayers: Pd on Au (111) J Mol Catal A Chem 199 1 2003 57 63
230. J. Yang, C. Cheng, W. Zhou, J. Lee, and Z. Liu Methanol-tolerant heterogeneous PdCo@PdPt/C electrocatalyst for the oxygen reduction reaction Fuel Cells 10 6 2010 907 913
231. J. Yang, J.Y. Lee, Q. Zhang, W. Zhou, and Z. Liu Carbon-supported pseudo-core-shell Pd-Pt nanoparticles for ORR with and without methanol J Electrochem Soc 155 7 2008 [B776-B81]
232. J. Yang, W. Zhou, C.H. Cheng, J.Y. Lee, and Z. Liu Pt-decorated PdFe nanoparticles as methanol-tolerant oxygen reduction electrocatalyst ACS Appl Mater Interfaces 2 1 2009 119 126
233. Y. Shemesh, J.E. Macdonald, G. Menagen, and U. Banin Synthesis and photocatalytic properties of a family of CdS-PdX hybrid nanoparticles Angew Chem Int Ed 123 5 2011 1217 1221
234. E. Shaviv, O. Schubert, M. Alves-Santos, G. Goldoni, R. Di Felice, F. Vallee, and et al. Absorption properties of metal-semiconductor hybrid nanoparticles ACS Nano 5 6 2011 4712 4719
235. S.-W. Kim, M. Kim, W.Y. Lee, and T. Hyeon Fabrication of hollow palladium spheres and their successful application to the recyclable heterogeneous catalyst for Suzuki coupling reactions J Am Chem Soc 124 26 2002 7642 7643
236. Y. Li, P. Zhou, Z. Dai, Z. Hu, P. Sun, and J. Bao A facile synthesis of PdCo bimetallic hollow nanospheres and their application to sonogashira reaction in aqueous media New J Chem 30 6 2006 832 837
237. x (x = 0-0.12) hollow spheres as catalysts for hydrogen generation from ammonia borane Inorg Chem 46 3 2007 788 794
238. H. Liu, F. Ye, H. Cao, G. Ji, J.Y. Lee, and J. Yang A core-shell templated approach to the nanocomposites of silver sulfide and noble metal nanoparticles with hollow/cage-bell structures Nanoscale 5 15 2013 6901 6907
239. W.Z. Ostwald Studies on formation and transformation of solid materials Z Phys Chem 22 1987 289 330
240. Y. Feng, H. Liu, P. Wang, F. Ye, Q. Tan, and J. Yang Enhancing the electrocatalytic property of hollow structured platinum nanoparticles for methanol oxidation through a hybrid construction Sci Rep 4 2014 6204
241. M. Valden, X. Lai, and D.W. Goodman Onset of catalytic activity of gold clusters on titania with the appearance of nonmetallic properties Science 281 5383 1998 1647 1650
242. M. Chen, and D. Goodman The structure of catalytically active gold on titania Science 306 5694 2004 252 255
243. C. Milone, R. Ingoglia, and S. Galvagno Gold supported on iron oxy-hydroxides: a versatile tool for the synthesis of fine chemicals Gold Bull 39 2 2006 54 65
244. 2 supported Au Phys Rev Lett 91 26 2003 266102
245. N. Zheng, and G.D. Stucky A general synthetic strategy for oxide-supported metal nanoparticle catalysts J Am Chem Soc 128 44 2006 14278 14280
246. M. Comotti, W.C. Li, and B. Spliethoff Support effect in high activity gold catalysts for CO oxidation J Am Chem Soc 128 3 2006 917 924
247. J.-D. Grunwaldt, and A. Baiker Gold/titania interfaces and their role in carbon monoxide oxidation J Phys Chem 103 6 1999 1002 1012
248. L. Molina, and B. Hammer Active role of oxide support during CO oxidation at Au/MgO Phys Rev Lett 90 20 2003 206102
249. M. Haruta, N. Yamada, T. Kobayashi, and S. Iijima Gold catalysts prepared by coprecipitation for low-temperature oxidation of hydrogen and of carbon monoxide J Catal 115 2 1989 301 309
250. A.S.K. Hashmi, and G.J. Hutchings Gold catalysis Angew Chem Int Ed 45 47 2006 7896 7936
251. X. Wang, N. Na, S. Zhang, Y. Wu, and X. Zhang Rapid screening of gold catalysts by chemiluminescence-based array imaging J Am Chem Soc 129 19 2007 6062 6063
252. A.A. Herzing, C.J. Kiely, A.F. Carley, P. Landon, and G.J. Hutchings Identification of active gold nanoclusters on iron oxide supports for CO oxidation Science 321 5894 2008 1331 1335
253. S. Laursen, and S. Linic Oxidation catalysis by oxide-supported Au nanostructures: the role of supports and the effect of external conditions Phys Rev Lett 97 2 2006 026101
254. C. Wang, C. Xu, H. Zeng, and S. Sun Recent progress in syntheses and applications of dumbbell-like nanoparticles Adv Mater 21 30 2009 3045 3052
255. 4 nanoparticles and their enhanced catalysis for oxygen reduction reaction Nano Lett 9 4 2009 1493 1496
256. X. Wang, M. Waje, and Y. Yan Methanol resistant cathodic catalyst for direct methanol fuel cells J Electrochem Soc 151 12 2004 [A2183-A8]
257. B. Xia, H. Wu, and Y. Yan Ultrathin and ultralong single-crystal platinum nanowire assemblies with highly stable electrocatalytic activity J Am Chem Soc 135 25 2013 9480 9485
258. F. Liu, G. Lu, and C.-Y. Wang Low crossover of methanol and water through thin membranes in direct methanol fuel cells J Electrochem Soc 153 3 2006 [A543-A53]
259. C. Du, T. Zhao, and W. Yang Effect of methanol crossover on the cathode behavior of a DMFC: a half-cell investigation Electrochim Acta 52 16 2007 5266 5271
260. N. Jia, M.C. Lefebvre, J. Halfyard, Z. Qi, and P.G. Pickup Modification of nafion proton exchange membranes to reduce methanol crossover in PEM fuel cells Electrochem Solid-State Lett 3 12 2000 529 531
261. B. Gurau, and E.S. Smotkin Methanol crossover in direct methanol fuel cells: a link between power and energy density J Power Sources 112 2 2002 339 352
262. Y.-M. Kim, K.-W. Park, J.-H. Choi, I.-S. Park, and Y.-E. Sung A Pd-impregnated nanocomposite nafion membrane for use in high-concentration methanol fuel in DMFC Electrochem Commun 5 7 2003 571 574
263. A. Sahu, S. Pitchumani, P. Sridhar, and A. Shukla Nafion and modified-nafion membranes for polymer electrolyte fuel cells: an overview Bull Mater Sci 32 3 2009 285 294
264. H. Zhang, H. Huang, and P.K. Shen Methanol-blocking nafion composite membranes fabricated by layer-by-layer self-assembly for direct methanol fuel cells Int J Hydrogen Energy 37 8 2012 6875 6879
265. Y. Zhang, W. Cai, F. Si, J. Ge, L. Liang, C. Liu, and et al. A modified nafion membrane with extremely low methanol permeability via surface coating of sulfonated organic silica Chem Commun 48 23 2012 2870 2872
266. C. Beauger, G. Lainé, A. Burr, A. Taguet, B. Otazaghine, and A. Rigacci Nafion®-sepiolite composite membranes for improved proton exchange membrane fuel cell performance J Membr Sci 430 2013 167 179
267. Y. Feng, J. Yang, H. Liu, F. Ye, and J. Yang Selective electrocatalysts toward a prototype of the membraneless direct methanol fuel cell Sci Rep 4 2014 3813
268. D. Cameron, G. Hards, B. Harrison, and R. Potter Direct methanol fuel cells Platin Met Rev 31 1987 173 181
269. R. Ferrigno, A.D. Stroock, T.D. Clark, M. Mayer, and G.M. Whitesides Membraneless vanadium redox fuel cell using laminar flow J Am Chem Soc 124 2002 12930 12931
270. R.S. Jayashree, D. Egas, J.S. Spendelow, D. Natarajan, L.J. Markoski, and P.J. Kenis Air-breathing laminar flow-based direct methanol fuel cell with alkaline electrolyte Solid-State Lett 9 5 2006 [A252-A6]
271. A. Lam, D.P. Wilkinson, and J. Zhang Novel approach to membraneless direct methanol fuel cells using advanced 3D anodes Electrochim Acta 53 23 2008 6890 6898
272. A. Lam, D.P. Wilkinson, and J. Zhang Control of variable power conditions for a membraneless direct methanol fuel cell J Power Sources 194 2 2009 991 996
273. A. Lam, M.S. Dara, D.P. Wilkinson, and K. Fatih Aerobic and anaerobic operation of an active membraneless direct methanol fuel cell Electrochem Commun 17 2012 22 25
274. S. Tominaka, S. Ohta, H. Obata, T. Momma, and T. Osaka On-chip fuel cell: micro direct methanol fuel cell of an air-breathing, membraneless, and monolithic design J Am Chem Soc 130 32 2008 10456 10457