-
3
-
-
0020799930
-
-
Y. YOSHIMURA, J. OSUGI, M. NAKAHAEA, J. Am. Chem. Soc. 1983, 105, 5414.
-
(1983)
J. Am. Chem. Soc.
, vol.105
, pp. 5414
-
-
Yoshimura, Y.1
Osugi, J.2
Nakahaea, M.3
-
9
-
-
0004052160
-
-
John Wiley & Sons, New York,
-
R. VAN ELDIK,C. D. HUBBARD, Chemistry under Extreme and Non-Classic Conditions, John Wiley & Sons, New York, 1997.
-
(1997)
Chemistry Under Extreme And Non-Classic Conditions,
-
-
Van Eldik, C.D.1
Hubbard, R.2
-
13
-
-
85005602994
-
-
K. MATSUMOTO, A. SERA, T. UCHIDA, Synthesis 1985, 1, 999-1027.
-
(1985)
Synthesis
, vol.1
, pp. 999-1027
-
-
Matsumoto, K.1
Sera, A.2
Uchida, T.3
-
15
-
-
0000982776
-
-
K. MATSUMOTO, M. KANEKO, H. KATSURA, N. NAYASHI, T. UCHIDA, R. M. ACHESON, Heterocycles 1998, 47, 1135-1177.
-
(1998)
Heterocycles
, vol.47
, pp. 1135-1177
-
-
Matsumoto, K.1
Kaneko, M.2
Katsura, H.3
Nayashi, N.4
Uchida, T.5
Acheson, R.M.6
-
18
-
-
33845184910
-
-
R. VAN ELDIK, T. ASANO, W. J. LE NOBLE, Chem. Rev. 1989, 89, 549.
-
(1989)
Chem. Rev.
, vol.89
, pp. 549
-
-
Van Eldik, R.1
Asano, T.2
Le Noble, W.J.3
-
19
-
-
0001445415
-
-
A. DRLJACA, C. D. HUBBARD, R. VAN ELDIK, T. ASANO, M. V. BASILEVSKY, W. J. LE NOBLE, Chem. Rev. 1998, 98, 2167-2289.
-
(1998)
Chem. Rev.
, vol.98
, pp. 2167-2289
-
-
Drljaca, A.1
Hubbard, C.D.2
Van Eldik, R.3
Asano, T.4
Basilevsky, M.V.5
Le Noble, W.J.6
-
20
-
-
4244121462
-
-
In 1, Z. Rappoport (Ed.), Wiley, New York,
-
F.-G. KLARNER, M. K. DIEDRICH, in The Chemistry of Dienes and Polyenes, 1, Z. RAPPOPORT (Ed.), Wiley, New York, 1997, 547-617.
-
(1997)
The Chemistry Of Dienes And Polyenes,
, pp. 547-617
-
-
Klarner, F.-G.1
Diedrich, M.K.2
-
22
-
-
84956775118
-
-
K. SEGUCHI, A. SERA, K. MARUYAMA, Bull. Chem. Soc. Jpn. 1974, 47, 2252.
-
(1974)
Bull. Chem. Soc. Jpn.
, vol.47
, pp. 2252
-
-
Seguchi, K.1
Sera, A.2
Maruyama, K.3
-
27
-
-
0001626316
-
-
K. BECK, S. HUNIG, F.-G. KLARNER, P. KRAFT, U. ARTSCHWAGER-PERL, Chem. Ber. 1987, 120, 2041.
-
(1987)
Chem. Ber.
, vol.120
, pp. 2041
-
-
Beck, K.1
Hunig, S.2
Klarner, F.-G.3
Kraft, P.4
Artschwager-Perl, U.5
-
29
-
-
0001678259
-
-
B. S. EL'YANONV, E. M. GONIKBERG, J. Chem. Soc, Faraday Trans 1 1979, 75, 172
-
(1979)
J. Chem. Soc, Faraday Trans 1
, vol.75
, pp. 172
-
-
El'yanonv, B.S.1
Gonikberg, E.M.2
-
35
-
-
33748960439
-
-
K. N. HOUR, Y. Li, J D. EVANSECK, Angew. Chem. Int. Ed. F.ngl. 1992, 31, 682.
-
(1992)
Angew. Chem. Int. Ed. F.Ngl.
, vol.31
, pp. 682
-
-
Hour, K.N.1
Li, Y.2
Evanseck, J.D.3
-
37
-
-
84985569618
-
-
F.-G. KLARNER, B. M. J. DOGAN, O. ERMER, W. V. E. DOERING, M. P. COHEN, Angew. Chem. Int. Ed. Engl. 1986, 25, 110.
-
(1986)
Angew. Chem. Int. Ed. Engl.
, vol.25
, pp. 110
-
-
Klarner, F.-G.1
Dogan, B.M.J.2
Ermer, O.3
Doering, W.V.E.4
Cohen, M.P.5
-
38
-
-
84956827577
-
-
U. DEITERS, F.-G. KLARNER, B. KRAWCZYK, V. RUSTER, J. Am. Chem. Soc. 1994, 216,7646.
-
(1994)
J. Am. Chem. Soc
, vol.216
, pp. 7646
-
-
Deiters, U.1
Klarner, F.-G.2
Krawczyk, B.3
Ruster, V.4
-
39
-
-
84982076770
-
-
W. R. ROTH, S. B. P., Chem. Ber. 1981, 114, 3741.
-
(1981)
Chem. Ber.
, vol.114
, pp. 3741
-
-
Roth, W.R.1
-
40
-
-
84956709527
-
-
Phd Thesis, Ruhr-Universitat Bochum
-
M. BARTMANN, PhD Thesis, Ruhr-Universitat Bochum, 1980.
-
(1980)
-
-
Bartmann, M.1
-
41
-
-
0001336887
-
-
J. BARAN, H. MAYR, V. RUSTER, F.-G. KLARNER, J. Org. Chem. 1989, 54, 5016.
-
(1989)
J. Org. Chem.
, vol.54
, pp. 5016
-
-
Baran, J.1
Mayr, H.2
Ruster, V.3
Klarner, F.-G.4
-
43
-
-
84956791295
-
Diploma Thesis, Ruhr-Universitat Bochum, 1987
-
Phd Thesis, Ruhr-Universitat Bochum
-
V. RUSTER, Diploma Thesis, Ruhr-Universitat Bochum, 1987; PhD Thesis, Ruhr-Universitat Bochum, 1991.
-
(1991)
-
-
Ruster, V.1
-
47
-
-
84956724958
-
-
Ruhr-Universitat Bochum
-
B. M. J. DOGAN, PhD Thesis, Ruhr-Universitat Bochum, 1984.
-
(1984)
Phd Thesis
-
-
Dogan, B.M.J.1
-
48
-
-
0007555514
-
-
M. R. DE CAMP, R. H. LEVIN, M. J. JONES, Tetrahedron Lett. 1974, 15, 3575.
-
(1974)
Tetrahedron Lett.
, vol.15
, pp. 3575
-
-
De Camp, M.R.1
Levin, R.H.2
Jones, M.J.3
-
50
-
-
30244500634
-
-
H. D. MARTIN, S. KAGABU, H. J. SHIWEK, Tetrahedron Lett. 1975, 41, 3311.
-
(1975)
Tetrahedron Lett.
, vol.41
, pp. 3311
-
-
Martin, H.D.1
Kagabu, S.2
Shiwek, H.J.3
-
52
-
-
84956724672
-
-
The Surprisingly Small Activation Volume Found For The Formation Of The Very Minor [4 + 4] Cyclodimer 16 In The 1,3-Butadiene Dimerization Seems To Be Inconsistent With A Stepwise Mechanism. The Small Ratio 0 = Av5≠ /Av = 0.54 Which Is Substantially Smaller Than That Of The Formation Of 14, 0 = 0.79, And Almost Equal To That Of The Formation Of 15, 0 = 0.59, May Indicate That 13 Is Formed Via A Stepwise [4 + 4] Cycloadditionpassing Through A (Z,Z)-Configured Diradical Intermediate.
-
The surprisingly small activation volume found for the formation of the very minor [4 + 4] cyclodimer 16 in the 1,3-butadiene dimerization seems to be inconsistent with a stepwise mechanism. The small ratio 0 = AV5≠/AV = 0.54 which is substantially smaller than that of the formation of 14, 0 = 0.79, and almost equal to that of the formation of 15, 0 = 0.59, may indicate that 13 is formed via a stepwise [4 + 4] cycloadditionpassing through a (Z,Z)-configured diradical intermediate.
-
-
-
-
53
-
-
84972990663
-
-
F.-G. KLARNER, V. RUSTER, B. ZIMNY, D. HOCHSTRATE, High Press. Res. 1991, 7, 133.
-
(1991)
High Press. Res.
, vol.7
, pp. 133
-
-
Klarner, F.-G.1
Ruster, V.2
Zimny, B.3
Hochstrate, D.4
-
54
-
-
0346128292
-
-
L. N. KOWA, D. SCHWARZER, J. TROE, J. SCHROEDER, J. Chem. Phys. 1992, 97, 4827.
-
(1992)
J. Chem. Phys.
, vol.97
, pp. 4827
-
-
Kowa, L.N.1
Schwarzer, D.2
Troe, J.3
Schroeder, J.4
-
56
-
-
0342340883
-
Serena Software
-
PCMODEL, Serena Software, 1992.
-
(1992)
-
-
-
57
-
-
0342876746
-
-
In W. F. Le Noble (Ed.), Elsevier, Amsterdam,
-
O. EXNER, in Organic High Pressure Chemistry, W. f. LE NOBLE (Ed.), Elsevier, Amsterdam, 1988, 19-49.
-
(1988)
Organic High Pressure Chemistry,
, pp. 19-49
-
-
Exner, O.1
-
58
-
-
0343311829
-
-
Y. YOSHIMURA, J. OSUGI, M.NAKAHARA, Bull. Chem. Soc. Jpn. 1983, 56, 680.
-
(1983)
Bull. Chem. Soc. Jpn.
, vol.56
, pp. 680
-
-
Yoshimura, Y.1
Osugi, J.2
Nakahara, M.3
-
60
-
-
0001431767
-
-
G. JENNER, M. PAPADOPOULOS, J. RIMMELIN, J. Org. Chem. 1983, 48, 748.
-
(1983)
J. Org. Chem.
, vol.48
, pp. 748
-
-
Jenner, G.1
Papadopoulos, M.2
Rimmelin, J.3
-
63
-
-
37049122400
-
-
R. A. GRIEGER, C. A. ECKERT, J. Chem. Soc, Faraday Trans 1 1970, 66, 2579.
-
(1970)
J. Chem. Soc, Faraday Trans 1
, vol.66
, pp. 2579
-
-
Grieger, R.A.1
Eckert, C.A.2
-
64
-
-
0040891969
-
-
F.-G. KLARNER, B. KRAWCZYK, V. RUSTER, U. K. DEITERS,J. Am. Chem. Soc. 1994, 116, 7646-7657.
-
(1994)
J. Am. Chem. Soc.
, vol.116
, pp. 7646-7657
-
-
Klarner, F.-G.1
Krawczyk, B.2
Ruster, V.3
Deitersz, U.K.4
-
69
-
-
85043982996
-
-
And Unpublished Results.
-
V. BREITKOPF, P. BUBENITSCHEK, H. HOPF, P. G. JONES, F.-G. KLARNER, D. SCHOMBURG, B. WITULSKI, B. ZIMNY, Liebigs Ann. Chem. 1997, 127 and unpublished results.
-
(1997)
Liebigs Ann. Chem.
, pp. 127
-
-
Breitkopf, V.1
Bubenitschek, P.2
Hopf, H.3
Jones, P.G.4
Klarner, F.-G.5
Schomburg, D.6
Witulski, B.7
Zimny, B.8
-
70
-
-
0004059527
-
-
Cambridge University Press, Cambridge,
-
G. I. FRAY, R. G. SAXTON, The Chemistry of Cyclooctatetraene and its Deriuatives, Cambridge University Press, Cambridge, 1978.
-
(1978)
The Chemistry Of Cyclooctatetraene And Its Deriuatives,
-
-
Fray, G.I.1
Saxton, R.G.2
-
71
-
-
0000121785
-
-
P. G. WENTHOLT, D. A. HROVAT, W. T. BORDEN, W. C. LINEBERGER, Science 1996, 272, 1456-1459
-
(1996)
Science
, vol.272
, pp. 1456-1459
-
-
Wentholt, P.G.1
Hrovat, D.A.2
Borden, W.T.3
Lineberger, W.C.4
-
75
-
-
0032989140
-
-
F.-G. KLARNER, R. EHRHARDT, H. BANDMANN, R. BOESE, D. BLASER, K. N. HOUR, B. R. BENO, Chem. Eur. J. 1999, 5, 2119.
-
(1999)
Chem. Eur. J.
, vol.5
, pp. 2119
-
-
Klarner, F.-G.1
Ehrhardt, R.2
Bandmann, H.3
Boese, R.4
Blaser, D.5
Hour, K.N.6
Beno, B.R.7
-
77
-
-
84988090453
-
-
V. BREITKOPF, H. HOPF, F.-G. KLARNER, B. WITULSKI, B. ZIMNY, Liebigs Ann. Chem. 1995, 613.
-
(1995)
Liebigs Ann. Chem.
, pp. 613
-
-
Breitkopf, V.1
Hopf, H.2
Klarner, F.-G.3
Witulski, B.4
Zimny, B.5
-
78
-
-
0346758990
-
-
J.-F. LIN, N. KETO, A. MORI, H. TAKESHITA, R. ISOBE, Bull Chem. Soc. Jpn. 1994, 67, 1507.
-
(1994)
Bull Chem. Soc. Jpn.
, vol.67
, pp. 1507
-
-
Lin, J.-F.1
Keto, N.2
Mori, A.3
Takeshita, H.4
Isobe, R.5
-
79
-
-
0010911771
-
-
W. ADAM, C. BARNEVELD VAN, J.-S. GEHRKE, F.-G. KLARNER, J. Chem. Soc, Perkin Trans. 2 1999, 2723-2728.
-
(1999)
J. Chem. Soc, Perkin Trans.
, vol.2
, pp. 2723-2728
-
-
Adam, W.1
Barneveld Van, C.2
Gehrke, J.-S.3
Klarner, F.-G.4
-
80
-
-
0030444987
-
-
K. EXNER, D. HOCHSTRATE. M. KELLER, F.-G. KLARNER, H. PRINZBACH, Angew. Chem. Int. Ed. Engl. 1996, 35, 2256-2259.
-
(1996)
Angew. Chem. Int. Ed. Engl.
, vol.35
, pp. 2256-2259
-
-
Exner, K.1
Hochstrate, M.2
Keller, D.3
Klarner, F.-G.4
Prinzbach, H.5
-
81
-
-
84988091833
-
-
S. HUNIG, P. KRAFT, F.-G. KLARNER, U. ARTSCHWANGER-PERL, K. PETERS, H.-G. SCHNERING, liebigs Ann. Chem. 1995, 351-356.
-
(1995)
Liebigs Ann. Chem.
, pp. 351-356
-
-
Hunig, S.1
Kraft, P.2
Klarner, F.-G.3
Artschwanger-Perl, U.4
Peters, K.5
Schnering, H.-G.6
-
82
-
-
33748584838
-
-
Z. Z. SONG, Z. Y. ZHON, T. C. W. MAK, H. N. C. WONG, Angew. Chem. Int. Ed. Engl. 1993, 32, 432.
-
(1993)
Angew. Chem. Int. Ed. Engl.
, vol.32
, pp. 432
-
-
Song, Z.Z.1
Zhon, Z.Y.2
Mak, T.C.W.3
Wong, H.N.C.4
-
83
-
-
84956123903
-
-
V. M. ZHULIN, E. B. KABOTYANSKAYA, M. V. KEL'TSEVA, V. S. BOGDANOV,Y. D. KORESHKOV, Izv. Akad. Nauk. SSSR, Ser. Khim. 1990, 2651.
-
(1990)
Izv. Akad. Nauk. Sssr, Ser. Khim
, pp. 2651
-
-
Zhulin, V.M.1
Kabotyanskaya, E.B.2
Kel'tseva, M.V.3
Bogdanov, Y.D.4
Koreshkov, V.S.5
-
84
-
-
84985516504
-
-
F. H. KOHNKE, A. M. Z. SLAWIN,J. F. STODDART, D. J. WILLIAMS, Angew. Chem. Int Ed. Engl. 1987, 26, 892.
-
(1987)
Angew. Chem. Int Ed. Engl.
, vol.26
, pp. 892
-
-
Kohnke, F.H.1
Slawin, J.F.2
Stoddart, A.M.Z.3
Williams, D.J.4
-
86
-
-
11944267916
-
-
P. R. ASHTON, G. R. BROWN, N. S. ISAACS, D. GUIFFRIDA, F. H. KOHNKE, J. P. MATHIAS, A. M. Z. SLAWIN, D. R. SMITH, J. F. STODDART, D. J. WILLIAMS, J. Am. Chem. Soc. 1992, 114, 6330
-
(1992)
J. Am. Chem. Soc.
, vol.114
, pp. 6330
-
-
Ashton, P.R.1
Brown, G.R.2
Isaacs, N.S.3
Guiffrida, D.4
Kohnke, F.H.5
Mathias, J.P.6
Slawin, A.M.Z.7
Smith, D.R.8
Stoddart, J.F.9
Williams, D.J.10
-
88
-
-
1542560276
-
-
P. R. ASHTON, U. GIRRESER, D. GUIFFRIDA, F. H. KOHNKE, J. P. MATHIAS, F. M. RAYMO, A. M. Z. SLAWIN, J. F. STODDART, D. J. WILLIAMS, J. Am. Chem. Soc, 1993, 115,5422.
-
(1993)
J. Am. Chem. Soc
, vol.115
, pp. 5422
-
-
Ashton, P.R.1
Girreser, U.2
Guiffrida, D.3
Kohnke, F.H.4
Mathias, J.P.5
Raymo, F.M.6
Slawin, A.M.Z.7
Stoddart, J.F.8
Williams, D.J.9
-
89
-
-
0028157563
-
-
J. BENKHOFF, R. BOESE, F.-G.KLARNER, A. E. WIGGER, TetrahedronLett. 1994, 35, 73.
-
(1994)
Tetrahedronlett.
, vol.35
, pp. 73
-
-
Benkhoff, J.1
Boese, R.2
Klarner, F.-G.3
Wigger, A.E.4
-
94
-
-
84956716965
-
-
J. VEI.KER, J.-P. ROBLIN, A. NEELS, A. TESUORO, H. STOECKLI-EVANS, F.-G. KLARNER, J.-S. GEHRKE, R. NEIER, Synlett 1999, SI, 925-929.
-
(1999)
Synlett
, pp. 925-929
-
-
VeiKer, J.1
Roblin, J.-P.2
Neels, A.3
Tesuoro, A.4
Stoeckli-Evans, H.5
Klarner, F.-G.6
Gehrke, J.-S.7
Neier, R.8
-
97
-
-
0004101860
-
2,3-Dipolar Cycloaddition Chemistry,
-
(Ed.), Wiley Interscience, New York,
-
A. PADWA (Ed.), 2,3-Dipolar Cycloaddition Chemistry, Wiley Interscience, New York, 1984.
-
(1984)
-
-
Padwa, A.1
-
98
-
-
0001187298
-
-
R. HUISGEN, G. MLOSTON, E. LANGHALS,J. Am. Chem. Soc. 1986, 108, 6401-6402.
-
(1986)
J. Am. Chem. Soc.
, vol.108
, pp. 6401-6402
-
-
Huisgen, R.1
Mloston, G.2
Langhals, E.3
-
99
-
-
0346128269
-
-
V. M. ZHULIN, Z. G. MAKAROV, M. M. KRAYUSHKIN, E. B. ZHURAVLEVA, A. M. BESKOPYL'NY, Dokl. Akad. Nauk. SSSR 1985, 280, 917.
-
(1985)
Dokl. Akad. Nauk. Sssr
, vol.280
, pp. 917
-
-
Zhulin, V.M.1
Makarov, Z.G.2
Krayushkin, M.M.3
Zhuravleva, E.B.4
Beskopyl'ny, A.M.5
-
102
-
-
0007355478
-
-
G. T. ANDERSON, J. R. HENRY, S. M. WEINREB,J. Org. Chem. 1991, 56, 6946.
-
(1991)
J. Org. Chem.
, vol.56
, pp. 6946
-
-
Anderson, G.T.1
Henry, J.R.2
Weinreb, S.M.3
-
103
-
-
0028092232
-
-
C. AHN, J. W. KENNINGTON, P. DESHONG,J. Org. Chem. 1994, 21, 6282-6286.
-
(1994)
J. Org. Chem.
, vol.21
, pp. 6282-6286
-
-
Ahn, C.1
Kennington, J.W.2
Deshong, P.3
-
104
-
-
84989432236
-
-
F.-G. KLARNER, D. OEBELS, W. S. SHELDRICK, Chem. Ber. 1993, 126, 473.
-
(1993)
Chem. Ber.
, vol.126
, pp. 473
-
-
Klarner, F.-G.1
Oebels, D.2
Sheldrick, W.S.3
-
105
-
-
0004231256
-
-
In Volume Ii, A. P. Marchand, R. E. Lehr (Eds), Academic Press, New York,
-
L. GHOZEZ, M. J. O'DONNEL, in Pericyclic Reactions, Volume II, A. P. MARCHAND, R. E. LEHR (Eds), Academic Press, New York, 1977.
-
(1977)
Pericyclic Reactions,
-
-
Ghozez, L.1
O'donnel, M.J.2
-
107
-
-
37049106349
-
-
G. SWIETON, J. v. JOUANNE, H. KELM, R. HUISGEN,J. Chem. Soc, Perkin Trans. 2 1983, 37.
-
(1983)
J. Chem. Soc, Perkin Trans.
, vol.2
, pp. 37
-
-
Swieton, G.1
Jouanne, J.V.2
Kelm, H.3
Huisgen, R.4
-
108
-
-
84963440975
-
-
M. CHMIELEVSKI, Z. KALUZA, P. SALANSKI, J. JURCZAK, High Press. Res. 1992, 11, 171.
-
(1992)
High Press. Res.
, vol.11
, pp. 171
-
-
Chmielevski, M.1
Kaluza, Z.2
Salanski, P.3
Jurczak, J.4
-
109
-
-
84963405208
-
-
R. W. M. ABEN,E. P. LIMBURG, H. W. SCHEEREN, High Pres. Res. 1992, 11, 167;
-
(1992)
High Pres. Res.
, vol.11
, pp. 167
-
-
Aben, R.W.M.1
Limburg, E.P.2
Scheeren, H.W.3
-
110
-
-
0029942037
-
-
Y. TAGUCHI, T. TSUCHIYA, A. OISHI, 1. SHIBUYA, Bull. Chem. Soc Jpn. 1996, 69, 1667.
-
(1996)
Bull. Chem. Soc Jpn.
, vol.69
, pp. 1667
-
-
Taguchi, Y.1
Tsuchiya, T.2
Oishi, A.3
Shibuya, L.4
-
112
-
-
84956844393
-
-
Phd Thesis, Universitat Essen,
-
B. KRAWCZYK, PhD Thesis, Universitat Essen, 1996.
-
(1996)
-
-
Krawczyk, B.1
-
113
-
-
84956814189
-
-
(In Press).
-
W. v. E. DOERING, J. EKMANIS, K. D. BELFIELD, F.-G. KLARNER, B. KRAWCZYK, J. Am. Chem. Soc. (in press).
-
J. Am. Chem. Soc.
-
-
Doering, W.V.E.1
Ekmanis, J.2
Belfield, K.D.3
Klarner, F.-G.4
Krawczyk, B.5
-
114
-
-
0000640188
-
-
J. JOUANNE, H. KELM, R. HUISGEN,J. Am. Chem. Soc. 1979, 101, 151.
-
(1979)
J. Am. Chem. Soc.
, vol.101
, pp. 151
-
-
Jouanne, J.1
Kelm, H.2
Huisgen, R.3
-
117
-
-
0027446173
-
-
R. W. M. ABEN, J. GOUDRIAAN,J. M. M. SMITS, H. W. SCHEEREN, Synthesis 1993, 37.
-
(1993)
Synthesis
, pp. 37
-
-
Aben, R.W.M.1
Goudriaan, J.M.M.2
Smits, J.3
Scheeren, H.W.4
-
119
-
-
5844251831
-
-
H. TAKESHITA, S. SUGIYAMA, T. HATSUI, J. Chem. Soc, Perkin Trans. 2 1986,1491
-
(1986)
J. Chem. Soc, Perkin Trans.
, vol.2
, pp. 1491
-
-
Takeshita, H.1
Sugiyama, S.2
Hatsui, T.3
-
121
-
-
84956754001
-
-
The Partial Molar Volumes Of Tropone, 1,3-Butadiene And The [6 + 4] Cycloadduct Were Measured By Dogan [35] To Be V = 88.8, 83.1 And 153.2 Cm3 Mol-1, Respectively, At 21 °C And Extrapolated To Be 99.8, 87.9, 154.1 Cm' Mol-1, Respectively, At 60 °C Using The Values Give By Takeshita Et Al. [92] For The Reaction Of Tropone With 2,3-Dimethylbutadiene.
-
The partial molar volumes of tropone, 1,3-butadiene and the [6 + 4] cycloadduct were measured by Dogan [35] to be V = 88.8, 83.1 and 153.2 cm3 mol-1, respectively, at 21 °C and extrapolated to be 99.8, 87.9, 154.1 cm' mol-1, respectively, at 60 °C using the values give by Takeshita et al. [92] for the reaction of tropone with 2,3-dimethylbutadiene.
-
-
-
-
122
-
-
1542746915
-
-
H. TAKESHITA, H. NAKASHIMA, S. SUGIYAMA, A. MORI, Bull. Chem. Soc. Jpn. 1988, 61, 573.
-
(1988)
Bull. Chem. Soc. Jpn.
, vol.61
, pp. 573
-
-
Takeshita, H.1
Nakashima, H.2
Sugiyama, S.3
Mori, A.4
-
123
-
-
0347237567
-
-
Z. Li, A. MORI, H. TAKESHITA, Y. NAGANO, Chem. Express 1992, 7, 213.
-
(1992)
Chem. Express
, vol.7
, pp. 213
-
-
Li, Z.1
Mori, A.2
Takeshita, H.3
Nagano, Y.4
-
124
-
-
0039752336
-
-
A. MORI, Y. NUKII, H. TAKESHITA, T. NOZOE, Heterocycles 1993, 35, 863.
-
(1993)
Heterocycles
, vol.35
, pp. 863
-
-
Mori, A.1
Nukii, Y.2
Takeshita, H.3
Nozoe, T.4
-
126
-
-
0348020008
-
-
N. J. TURRO, M. OKAMOTO, I. R. GOULD, R. A. Moss, W. LAWRYNOWICZ, L. M. HADEL, J. Am. Chem. Soc. 1987, 109, 4973.
-
(1987)
J. Am. Chem. Soc.
, vol.109
, pp. 4973
-
-
Turro, N.J.1
Okamoto, M.2
Gould, I.R.3
Moss, R.A.4
Lawrynowicz, W.5
Hadel, L.M.6
-
128
-
-
0024827392
-
-
Tetrahedron 1989, 45, 7083-7092.
-
N. S. ISAACS, G. N. EL-DIN, Synthesis 1989, 967; Tetrahedron 1989, 45, 7083-7092.
-
(1989)
Synthesis
, pp. 967
-
-
Isaacs, N.S.1
El-Din, G.N.2
-
129
-
-
84988072787
-
-
F.-G. KLARNER, S. YASLAK, R. DREWES, C. GESENBERG, M. PETER, Liebigs Ann. Chem. 1995, 203-210.
-
(1995)
Liebigs Ann. Chem
, pp. 203-210
-
-
Klarner, F.-G.1
Yaslak, S.2
Drewes, R.3
Gesenberg, C.4
Peter, M.5
-
130
-
-
0000515593
-
-
K. MOROKUMA, W. T. BORDEN, D. A. HROVAT, J. Am. Chem. Soc. 1988, 110, 4474.
-
(1988)
J. Am. Chem. Soc.
, vol.110
, pp. 4474
-
-
Morokuma, K.1
Borden, W.T.2
Hrovat, D.A.3
-
131
-
-
0033579184
-
-
D. A. HROVAT, B. R. BENO, H. LANGF, H.-Y. YOO, K. N. HOUR, W. T. BORDEN, J. Am. Chem. Soc. 1999, 121, 10529.
-
(1999)
J. Am. Chem. Soc.
, vol.121
, pp. 10529
-
-
Hrovat, D.A.1
Beno, B.R.2
Langf, H.3
Yoo, H.-Y.4
Hour, K.N.5
Borden, W.T.6
-
133
-
-
33748632871
-
-
M. K. DIEDRICH, D. HOCHSTRATE, F.-G. KLARNER, B. ZIMNY, Angew. Chem. Int. Ed. Engl. 1994, 33, 1079.
-
(1994)
Angew. Chem. Int. Ed. Engl.
, vol.33
, pp. 1079
-
-
Diedrich, M.K.1
Hochstrate, D.2
Klarner, F.-G.3
Zimny, B.4
-
135
-
-
24244460015
-
-
G. A. STASHINA, E. N. VASIL'VITSKAYA, G. D. GAMELEVICFI, B. S. EL'YANOVE. P. Serebryakov, V. M. Zhulin, Izv. Akad. Nauk Sssr, Ser. Khim. 1986, 329.,
-
(1986)
Izv. Akad. Nauk SSSR, Ser. Khim.
, pp. 329
-
-
Stashina, G.A.1
Vasil'vitskaya, E.N.2
Gamelevicfi, G.D.3
El'yanov, B.S.4
Serebryakov, E.P.5
Zhulin, V.M.6
-
136
-
-
0000334287
-
-
W. v. E. DOERING, L. BIRLADEANU, K. SARMA, J. H. TELES, F.-G. KLARNER, J.-S. GEHRKE, J. Am. Chem. Soc. 1994, 116,4289-4297.
-
(1994)
J. Am. Chem. Soc
, vol.116
, pp. 4289-4297
-
-
Doering, W.V.E.1
Birladeanu, L.2
Sarma, K.3
Teles, J.H.4
Klarner, F.-G.5
Gehrke, J.-S.6
-
140
-
-
0001694036
-
-
The Temperature-Dependent Kinetic Analysis Was Carried Out For This Rearrangement In The Gas Phase Between 142 And 173 °C Leading To The Arrhenius Equation Log K - (11.1 ± 0.3) - (29.3 ± 0.5) Kcal Mol-1'/Rt. In The Gas Phase The Resulting Activation Enthalpy And Entropy, Ah≠= 28.5 Kcal Mol-1 And As≠ = -10.6 Cal Mol-1 K"1, Are Larger Than Those In Benzene Solution (80 °C: Ah≠ = 25.4 Kcal Mol"1 And As≠ = -15.9 Cal Mol-1 K"1: J. Burrows, B. K. Carpenter,
-
The temperature-dependent kinetic analysis was carried out for this rearrangement in the gas phase between 142 and 173 °C leading to the Arrhenius equation log k - (11.1 ± 0.3) - (29.3 ± 0.5) kcal mol-1'/RT. In the gas phase the resulting activation enthalpy and entropy, AH≠= 28.5 kcal mol-1 and AS≠ = -10.6 cal mol-1 K"1, are larger than those in benzene solution (80 °C: AH≠ = 25.4 kcal mol"1 and AS≠= -15.9 cal mol-1 K"1: J. BURROWS, B. K. CARPENTER, J. Am. Chem. Soc. 1981, 103, 6983).
-
(1981)
J. Am. Chem. Soc.
, vol.103
, pp. 6983
-
-
-
141
-
-
0020766405
-
-
E. M. SCHULMAN, A. E. MERBACH, M. TURIN, R. WEDINGER, W. J. LE NOBLE, J. Am. Chem. Soc. 1983, 105, 3988.
-
(1983)
J. Am. Chem. Soc.
, vol.105
, pp. 3988
-
-
Schulman, E.M.1
Merbach, A.E.2
Turin, M.3
Wedinger, R.4
Le Noble, W.J.5
-
142
-
-
0033978664
-
-
W. v. E. DOERING, L. BIRLADEANU, K. SARMA, G. BIASCHKE, U.U. SCHEIDEMANTEL, R. BoESE, J. BENET-BUCHOLZ, F.-G. KLARNER, J.-S. GEHRKE, B. ZIMNY, H.-G. KORTH,J. Am. Chem. Soc. 2000, 122, 193-203.
-
(2000)
J. Am. Chem. Soc.
, vol.122
, pp. 193-203
-
-
Doering, W.V.E.1
Birladeanu, L.2
Sarma, K.3
Biaschke, G.4
Scheidemantel, U.U.5
Boese, R.6
Benet-Bucholz, J.7
Klarner, F.-G.8
Gehrke, J.-S.9
Zimny, B.10
Korth, H.-G.11
-
143
-
-
84956715976
-
-
Phd Thesis, Universitatessen,
-
J.-S. GEHRKE, PhD Thesis, UniversitatEssen, 1999.
-
(1999)
-
-
Gehrke, J.-S.1
-
146
-
-
9444264454
-
-
W. J. LE NOBLE, K. R. BROWER, C. BROWER, C. S., J. Am. Chem. Soc. 1982, 104, 3150.
-
(1982)
J. Am. Chem. Soc.
, vol.104
, pp. 3150
-
-
Le Noble, W.J.1
Brower, K.R.2
Brower, C.S.C.3
-
148
-
-
33748232595
-
-
L. F. TIETZE, C. On, K. GERKE, M. BUBACK, Angew. Chem. Int. Ed. Engl. 1993, 32, 1485.
-
(1993)
Angew. Chem. Int. Ed. Engl.
, vol.32
, pp. 1485
-
-
Tietze, L.F.1
On, C.2
Gerke, K.3
Buback, M.4
-
149
-
-
0347389221
-
-
S. JAROSZ, E. KOZLOWSKA, A. JERZEWSKI, Tetrahedron 1997, 31, 10775-10782.
-
(1997)
Tetrahedron
, vol.31
, pp. 10775-10782
-
-
Jarosz, S.1
Kozlowska, E.2
Jerzewski, A.3
-
155
-
-
84956779540
-
-
M. BUBACK, J. ABELN, T. HUBSCH, C. OTT, L. F. TIETZE, Liehigs Ann. 1995, 9
-
(1995)
Liehigs Ann.
, pp. 9
-
-
Buback, M.1
Abeln, J.2
Hubsch, T.3
Ott, C.4
Tietze, L.F.5
-
156
-
-
85039385224
-
-
T. HEINER, K. MICHALSKY, K. GERKE, G. KUCHTA, M. BUBACK, A. DE MEIJERE, Synlett 1995, 355
-
(1995)
Synlett
, pp. 355
-
-
Heiner, T.1
Michalsky, K.2
Gerke, K.3
Kuchta, G.4
Buback, M.5
De Meijere, A.6
-
157
-
-
0001063663
-
-
A. C. BRICKWOOD, M. G. B. DREW, L. M. HARWOOD, T. ISHIKAWA, P. MARAIS, V. MORRISON, J. Chem. Soc, Perkin Trans 1 1999, 913-921
-
(1999)
J. Chem. Soc, Perkin Trans
, vol.1
, pp. 913-921
-
-
Brickwood, A.C.1
Drew, M.G.B.2
Harwood, L.M.3
Ishikawa, T.4
Marais, P.5
Morrison, V.6
-
158
-
-
0030576867
-
-
T. HEINER, S. I. KOZHUSHKOV, K. GERKE, T. HAUMANN, R. BOESE, A. DE MEIJERE, Tetrahedron 1996, 37, 12185-12196
-
(1996)
Tetrahedron
, vol.37
, pp. 12185-12196
-
-
Heiner, T.1
Kozhushkov, S.I.2
Gerke, K.3
Haumann, T.4
Boese, R.5
De Meijere, A.6
-
160
-
-
84989486107
-
-
M. BUBACK, K. GERKE, C. OTT, L. F. TIETZE, Chem. Ber. 1994, 127, 2241.
-
(1994)
Chem. Ber.
, vol.127
, pp. 2241
-
-
Buback, M.1
Gerke, K.2
Ott, C.3
Tietze, L.F.4
-
161
-
-
0042804773
-
-
G. JENNER, M. PAPADOPOULOS, B. S. EL'YANONV, E. M. GONIKBERG, J. Org. Chem. 1982, 47, 4201.
-
(1982)
J. Org. Chem.
, vol.47
, pp. 4201
-
-
Jenner, G.1
Papadopoulos, M.2
El'yanonv, B.S.3
Gonikberg, E.M.4
-
164
-
-
84956761661
-
-
Although The New C-C Bond Is Only Partially Formed In The Transition Structure, The C-H-C Distances Are Obviously Both Within The Range Of Van Der Waals Distances, Whereasin The Product The Non-Bonding (=H2C--H-Ch3-) Distance Is, according to the most stable geometry, larger than the van der Waals distance.
-
Although the new C-C bond is only partially formed in the transition structure, the C-H-C distances are obviously both within the range of van der Waals distances, whereasin the product the non-bonding (=H2C--H-CH3-) distance is,according To The Most Stable Geometry, Larger Than The Van Der Waals Distance.
-
-
-
-
165
-
-
0346758925
-
-
G. SWIETON, J. JOUANNE, H. KELM,J. Org. Chem. 1983, 48, 1035.
-
(1983)
J Org. Chem.
, vol.48
, pp. 1035
-
-
Swieton, G.1
Jouanne, J.2
Kelm, H.3
-
166
-
-
0346128229
-
-
U. B. IMASHEV, V. V. ZORIN, S. M. KALASHNIKOV, S. S. ZLOTSKII, V. M. ZHULIN, D. L. RAKHMANKULOV, Dokl. Akad. Nauk. SSSR 1978, 242, 140.
-
(1978)
Dokl. Akad. Nauk. Sssr
, vol.242
, pp. 140
-
-
Imashev, U.B.1
Zorin, V.V.2
Kalashnikov, S.M.3
Zlotskii, S.S.4
Zhulin, V.M.5
Rakhmankulov, D.L.6
-
167
-
-
0346758922
-
-
A. A. LAPSHOVA, G. A. STASHINA, V. V. ZORIN, S. S. ZLOTSKII, V. M. ZHULIN, D. L. RAKHMANKULOV, Zh. Org. Khim 1980, 16, 1251.
-
(1980)
Zh. Org. Khim
, vol.16
, pp. 1251
-
-
Lapshova, A.A.1
Stashina, G.A.2
Zorin, V.V.3
Zlotskii, S.S.4
Zhulin, V.M.5
Rakhmankulov, D.L.6
-
168
-
-
0038198009
-
-
M. Y. BOTNIKOV,S. S. ZLOTSKII, V. V. ZORIN, E. K. KRAVETS, V. M. ZHULIN, D. L. RAKHMANKULOV, IZV. Akad. Nauk SSSR, Ser. Khim. 1977, 690
-
(1977)
Izv. Akad. Nauk Sssr, Ser. Khim.
, pp. 690
-
-
Botnikov, S.S.1
Zlotskii, M.Y.2
Zorin, V.V.3
Kravets, E.K.4
Zhulin, V.M.5
Rakhmankulov, D.L.6
-
169
-
-
50849152462
-
-
E. V. PASTUSHENKO, M. Y. BOTNIKOV, S. S. ZLOTSKII, V. M. ZHULIN, D. L. RAKHMANKULOV, React. Kinet. Catal. Lett. 1981, 16, 195.
-
(1981)
React. Kinet. Catal. Lett.
, vol.16
, pp. 195
-
-
Pastushenko, E.V.1
Botnikov, M.Y.2
Zlotskii, S.S.3
Zhulin, V.M.4
Rakhmankulov, D.L.5
-
172
-
-
0009697901
-
-
R. C. NEUMAN, C. T. BERGE, G. A. BINEGAR, W. ADAM, Y. NISHIZAWA, J. Org. Chem. 1990, 55, 4564.
-
(1990)
J. Org. Chem.
, vol.55
, pp. 4564
-
-
Neuman, R.C.1
Berge, C.T.2
Binegar, G.A.3
Adam, W.4
Nishizawa, Y.5
-
175
-
-
26544477947
-
-
V. M. ZHULIN, G. A. STASHINA, E. G. ROZANTSEV, IZV. Akad. Nauk SSSR, Ser. Khim. 1979, 977
-
(1979)
Izv. Akad. Nauk Sssr, Ser. Khim.
, pp. 977
-
-
Zhulin, V.M.1
Stashina, G.A.2
Rozantsev, E.G.3
-
178
-
-
84956830880
-
-
Phd Thesis, Universitat Essen (In Preparation).
-
G. DIERKES, PhD Thesis, Universitat Essen (in preparation).
-
-
-
Dierkes, G.1
-
179
-
-
0000437996
-
-
G. KRATT, H.-D. BECKHAUS, C. RUCHARDT, Chem. Ber. 1984, 117, 1748.
-
(1984)
Chem. Ber.
, vol.117
, pp. 1748
-
-
Kratt, G.1
Beckhaus, H.-D.2
Ruchardt, C.3
-
182
-
-
37049105359
-
-
N. S. ISAACS, K. JAVID, E. RANNALA,J. Chem. Soc, Perkin Trans. 2 1978, 709.
-
(1978)
J. Chem. Soc, Perkin Trans.
, vol.2
, pp. 709
-
-
Isaacs, N.S.1
Javid, K.2
Rannala, E.3
-
184
-
-
84956823976
-
-
Phd Thesis, Universitat Essen (In Preparation).
-
F. WURCHE, PhD Thesis, Universitat Essen (in preparation).
-
-
-
Wurche, F.1
-
189
-
-
0009695415
-
-
T. IBATA, M.-H. SHANG, T. DEMURA, Bull. Chem. Soc.Jpn. 1995, 68, 2941.
-
(1995)
Bull. Chem. Soc.Jpn.
, vol.68
, pp. 2941
-
-
Ibata, T.1
Shang, M.-H.2
Demura, T.3
-
191
-
-
26044455550
-
-
F.-G. KLARNER, U. KALTHOF, J. GANTE, J. Prakt. Chem. 1997, 339, 359.
-
(1997)
J. Prakt. Chem.
, vol.339
, pp. 359
-
-
Klarner, F.-G.1
Kalthof, U.2
Gante, J.3
-
192
-
-
0031852604
-
-
T. YAMADA, Y. OMOTE, Y. YAMANKA, T. MIYAZAWA, S. KUWATA, Synthesis 1998, 991-998.
-
(1998)
Synthesis
, pp. 991-998
-
-
Yamada, T.1
Omote, Y.2
Yamanka, Y.3
Miyazawa, T.4
Kuwata, S.5
-
193
-
-
21144458827
-
-
T. SHIOIRI, T. IMAEDEA, Y. HAMADA, Heterocydes 1997, 46, 421-442.
-
(1997)
Heterocydes
, vol.46
, pp. 421-442
-
-
Shioiri, T.1
Imaedea, T.2
Hamada, Y.3
-
194
-
-
0026756208
-
-
S. PINHEIRO, A.GuiGNANT, D. DESMAELB, J. D'ANGELO, Tetrahedron Assymmetry1992, 3, 1003
-
(1992)
Tetrahedron Assymmetry
, vol.3
, pp. 1003
-
-
Pinheiro, S.1
Guignant, A.2
Desmaelb, D.3
D'angelo, J.4
-
196
-
-
0000015776
-
-
H. KOTSUKI, M. WAKAO, H. HAYAKAWA, T. SHIMANOUCHI, M. SHITOJ. Org. Chem. 1996, 61, 8915.
-
(1996)
M. Shitoj. Org. Chem
, vol.61
, pp. 8915
-
-
Kotsuki, H.1
Wakao, M.2
Hayakawa, H.3
Shimanouchi, T.4
-
197
-
-
0032513696
-
-
And References Cited Therein.
-
D. B. AMABILINO, P. R. ASHTON, V. BALZANI, S. E. BOYD, A. CREDI, J. Y. LEE, S. MENZER, J. F. STODDART, M. VENTURI, D. J. WILLIAMS,J. Am. Chem. Soc, 1998, 120, 4295 and references cited therein.
-
(1998)
J. Am. Chem. Soc,
, vol.120
, pp. 4295
-
-
Amabilino, D.B.1
Ashton, P.R.2
Balzani, V.3
Boyd, S.E.4
Credi, A.5
Lee, J.Y.6
Menzer, S.7
Stoddart, J.F.8
Venturi, M.9
Williams, D.J.10
-
198
-
-
85046522615
-
-
R. BALLARDINI, V. BALZANI, W. DEHAEN, A. E. DELL'ERBA, F. M. RAYMO. J. F. STODDART, M. VENTURI, Eur. J. Org. Chem. 2000, 591.
-
(2000)
Eur. J. Org. Chem
, pp. 591
-
-
Ballardini, R.1
Balzani, V.2
Dehaen, W.3
Dell'erba, A.E.4
Raymo, J.F.5
Stoddart, F.M.6
Venturi, M.7
-
199
-
-
0031011963
-
-
P. R. ASHTON, S. E. BOYD, C. G. CIAESSENS, R. E. GILLARD, S. MENZER, J. F. STODDART, M. S. TOLLEY, A. J. P. WHITE, D. J. WILLIAMS, Chem. Eur. J. 1997, 3, 788.
-
(1997)
Chem. Eur. J.
, vol.3
, pp. 788
-
-
Ashton, P.R.1
Boyd, S.E.2
Ciaessens, C.G.3
Gillard, R.E.4
Menzer, S.5
Stoddart, J.F.6
Tolley, M.S.7
White, A.J.P.8
Williams, D.J.9
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