High-energy resolution X-ray absorption and emission spectroscopy reveals insight into unique selectivity of La-based nanoparticles for CO2

Proceedings of the National Academy of Sciences of the United States of America

Volumn 112, Issue 52, 2015, Pages 15803-15808

  Hirsch, Ofer ^a   Kvashnina, Kristina O ^b,c   Luo, Li ^a   Süess, Martin J ^a   Glatzel, Pieter ^b   Koziej, Dorota ^a  

^a ETH ZURICH   (Switzerland)

^b EUROPEAN SYNCHROTRON RADIATION FACILITY   (France)

^c INSTITUTE OF ION BEAM PHYSICS AND MATERIALS RESEARCH   (Germany)

Author keywords

CO2 sensing; HERFD XAS; Lanthanum oxycarbonate; Structure; Valence to core XES

Indexed keywords

CARBON DIOXIDE; LANTHANUM; LANTHANUM OXYCARBONATE NANOPARTICLE; NANOPARTICLE; OXYGEN; UNCLASSIFIED DRUG; WATER;

ADSORPTION; ARTICLE; CHEMICAL INTERACTION; CHEMICAL STRUCTURE; CORRELATIONAL STUDY; ELECTRIC RESISTANCE; ELECTROCHEMISTRY; HIGH ENERGY RESOLUTION FLUORESCENCE INFORMATION DETECTED XRAY ABSORPTION NEAR EDGE STRUCTURE SPECTROSCOPY; PRIORITY JOURNAL; SENSOR; SPECTRAL SENSITIVITY; SPECTROSCOPY; VALENCE TO CORE X RAY EMISSION SPECTROSCOPY; WATER VAPOR;

EID: 84952701155     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.1516192113     Document Type: Article

References (68)

1. Furukawa H, et al. (2010) Ultrahigh porosity in metal-organic frameworks. Science 329(5990):424-428.
2. Millward AR, Yaghi OM (2005) Metal-organic frameworks with exceptionally high capacity for storage of carbon dioxide at room temperature. J AmChem Soc 127(51):17998-17999.
3. 0.2O3 (Ln = La, Sm, Nd). Appl Catal, A 255(1):45-57.
4. 2 adsorption energetics and uptake. J Am Chem Soc 135(20):7660-7667.
5. Alezi D, et al. (2015) Quest for highly connected metal-organic framework platforms: Rare-earth polynuclear clusters versatility meets net topology needs. J Am Chem Soc 137(16):5421-5430.
6. 2 reforming of methane. ACS Catal 3(7):1537-1544.
7. 7 (Ln = La, Pr, Nd, and Sm). Chem Mater 12(3):812-817.
8. 4 polymorph for multiple energy applications. Chem Mater 21(19):4731-4737.
9. Alonso-Mori R, et al. (2012) Energy-dispersive X-ray emission spectroscopy using an X-ray free-electron laser in a shot-by-shot mode. Proc Natl Acad Sci USA 109(47):19103-19107.
10. Schmitt T, De Groot FMF, Rubensson J-E (2014) Prospects of high-resolution resonant X-ray inelastic scattering studies on solid materials, liquids and gases at diffractionlimited storage rings. J Synchrotron Radiat 21(Pt 5):1065-1076.
11. Glatzel P, Singh J, Kvashnina KO, Van Bokhoven JA (2010) In situ characterization of the 5d density of states of Pt nanoparticles upon adsorption of CO. J Am Chem Soc 132(8):2555-2557.
12. Smolentsev N, Sikora M, Soldatov AV, Kvashnina KO, Glatzel P (2011) Spin-orbit sensitive hard x-ray probe of the occupied and unoccupied 5d density of states. Phys Rev B 84(23):235113.
13. Singh J, Lamberti C, Van Bokhoven JA (2010) Advanced X-ray absorption and emission spectroscopy: In situ catalytic studies. Chem Soc Rev 39(12):4754-4766.
14. Merte LR, et al. (2012) Electrochemical oxidation of size-selected Pt nanoparticles studied using in situ high-energy-resolution X-ray absorption spectroscopy. ACS Catal 2(11):2371-2376.
15. 2 by XAS in operando conditions. Chem Commun (41):5202-5204.
16. 2 based sensors. Phys Chem Chem Phys 11(38):8620-8625.
17. Boubnov A, et al. (2014) Selective catalytic reduction of NO over Fe-ZSM-5: Mechanistic insights by operando HERFD-XANES and valence-to-core X-ray emission spectroscopy. J Am Chem Soc 136(37):13006-13015.
18. Radu D, et al. (2008) Geometric and electronic structure of α-oxygen sites in Mn-ZSM-5 zeolites. J Phys Chem C 112(32):12409-12416.
19. 2 sensing. Chem Mater 21(22):5375-5381.
20. 2 sensing at room temperature. Adv Funct Mater 25(17):2537-2542.
21. 2 gas sensors. Procedia Eng 5(0):139-142.
22. 2 reduction catalysts. Chem Soc Rev 41(6):2036-2051.
23. Turcotte RP, Sawyer JO, Eyring L (1969) Rare earth dioxymonocarbonates and their decomposition. Inorg Chem 8(2):238-246.
24. 3 II. J Mater Chem 9(10):2697-2702.
25. 3. Acta Chem Scand 24:2440-2446.
26. Werner P-E, Eriksson L, Westdahl M (1985) TREOR, a semi-exhaustive trial-and-error powder indexing program for all symmetries. J Appl Cryst 18(5):367-370.
27. Toby B (2005) CMPR - a powder diffraction toolkit. J Appl Cryst 38(6):1040-1041.
28. 2013: A kit of tools for phasing crystal structures from powder data. J Appl Cryst 46(4):1231-1235.
29. Rietveld H (1969) A profile refinement method for nuclear and magnetic structures. J Appl Cryst 2(2):65-71.
30. Larson AC, Von Dreele RB (1994) General Structure Analysis System (GSAS). (Los Alamos Natl Lab, Los Alamos, NM), Report LAUR 86-748.
31. Toby B (2001) EXPGUI, a graphical user interface for GSAS. J Appl Cryst 34(2):210-213.
32. Young RA (1993) The Rietveld Method (Oxford Univ Press, Oxford).
33. Suortti P (1972) Effects of porosity and surface roughness on the X-ray intensity reflected from a powder specimen. J Appl Cryst 5(5):325-331.
34. Von Dreele R (1997) Quantitative texture analysis by Rietveld refinement. J Appl Cryst 30(4):517-525.
35. cctbx - Change space group setting. cci.lbl.gov/cctbx/change-setting.html. Accessed December 9, 2014.
36. 3-ZnO catalysts. Catal Sci Technol 3(10):2801-2809.
37. 3 catalysts used in a membrane reactor for hydrogen production. Appl Catal, A 263(1):91-101.
38. 2 reforming of methane on Rh supported on lanthanum-based solid. J Catal 245(1):25-34.
39. Krause MO, Oliver JH (1979) Natural widths of atomic K and L levels, Kα X-ray lines and several KLL Auger lines. J Phys Chem Ref Data 8(2):329-338.
40. Journel L, et al. (2002) Resonant inelastic x-ray scattering at the lanthanum L3 edge. Phys Rev B 66(4):045106.
41. 3-MgO catalysts for oxidative coupling of methane. J Synchrotron Radiat 8(Pt 2):593-595.
42. 3-edge XANES spectra of lanthanum complex oxides. Inorg Chem 53(12):6048-6053.
43. Peacock PW, Robertson J (2002) Band offsets and Schottky barrier heights of high dielectric constant oxides. J Appl Phys 92(8):4712-4721.
44. 3, R=La, Pr, and Nd). J Appl Phys 100(8):083525.
45. Kvashnina KO, Butorin SM, Glatzel P (2011) Direct study of the f-electron configuration in lanthanide systems. J Anal At Spectrom 26(6):1265-1272.
46. Glatzel P, et al. (2005) Range-extended EXAFS at the L edge of rare earths using highenergyresolution fluorescence detection: A study of La in LaOCl. Phys Rev B 72(1):014117.
47. De Groot F, Vanko G, Glatzel P (2009) The 1s x-ray absorption pre-edge structures in transition metal oxides. J Phys Condens Matter 21(10):104207.
48. Sunding MF, et al. (2011) XPS characterisation of in situ treated lanthanum oxide and hydroxide using tailored charge referencing and peak fitting procedures. J Electron Spectrosc Relat Phenom 184(7):399-409.
49. Mikami M, Nakamura S (2006) Electronic structure of rare-earth sesquioxides and oxysulfides. J Alloys Compd 408-412(0):687-692.
50. Jiang H, Gomez-Abal RI, Rinke P, Scheffler M (2009) Localized and itinerant states in lanthanide oxides united by GW@LDA+U. Phys Rev Lett 102(12):126403.
51. 7 thin film. RSC Advances 4(22):11420-11422.
52. Szlachetko J, Sa J (2013) Rational design of oxynitride materials: From theory to experiment. CrystEngComm 15(14):2583-2587.
53. Chiou JW, et al. (2008) Mg-induced increase of band gap in Zn1.xMgxO nanorods revealed by X-ray absorption and emission spectroscopy. J Appl Phys 104(1):013709.
54. Bar M, et al. (2008) Depth-resolved band gap in Cu (In, Ga) (S, Se) 2 thin films. Appl Phys Lett 93(24):244103.
55. 3 nanorods. J Alloys Compd 509(2):396-401.
56. Mu Q, Wang Y (2011) A simple method to prepare Ln (OH) 3 (Ln = La, Sm, Tb, Eu, and Gd) nanorods using CTAB micelle solution and their room temperature photoluminescence properties. J Alloys Compd 509(5):2060-2065.
57. Barsan N, Simion C, Heine T, Pokhrel S, Weimar U (2010) Modeling of sensing and transduction for p-type semiconducting metal oxide based gas sensors. J Electroceram 25(1):11-19.
58. Erbil A, Cargill III, Frahm R, Boehme RF (1988) Total-electron-yield current measurements for near-surface extended x-ray-absorption fine structure. Phys Rev B Condens Matter 37(5):2450-2464.
59. Vlachos D, Craven AJ, McComb DW (2005) Specimen charging in X-ray absorption spectroscopy: Correction of total electron yield data from stabilized zirconia in the energy range 250-915 eV. J Synchrotron Radiat 12(Pt 2):224-233.
60. 2. Phys Chem Chem Phys 15(26):11128-11138.
61. Schroeder S, Moggridge G, Lambert R, Rayment T (1998) Spectroscopy for Surface Science (Wiley, Hoboken, NJ).
62. Safonova OV, et al. (2014) Electronic and geometric structure of Ce3+ forming under reducing conditions in shaped ceria nanoparticles promoted by platinum. J Phys Chem C 118(4):1974-1982.
63. 2 (100). J Phys Chem C 118(17):9042-9050.
64. Dell'Angela M, et al. (2013) Real-time observation of surface bond breaking with an x-ray laser. Science 339(6125):1302-1305.
65. Glatzel P, Bergmann U (2005) High resolution 1s core hole X-ray spectroscopy in 3d transition metal complexes.electronic and structural information. Coord Chem Rev 249(1-2):65-95.
66. Glatzel P, Sikora M, Smolentsev G, Fernandez-Garcia M (2009) Hard X-ray photon-in photon-out spectroscopy. Catal Today 145(3-4):294-299.
67. Rehr J, Albers R (2000) Theoretical approaches to x-ray absorption fine structure. Rev Mod Phys 72(3):621-654.
68. Rehr JJ, Kas JJ, Vila FD, Prange MP, Jorissen K (2010) Parameter-free calculations of X-ray spectra with FEFF9. Phys Chem Chem Phys 12(21):5503-5513.