Modelling marine emissions and atmospheric distributions of halocarbons and dimethyl sulfide: The influence of prescribed water concentration vs. prescribed emissions

Atmospheric Chemistry and Physics

Volumn 15, Issue 20, 2015, Pages 11753-11772

  Lennartz, S T ^a   Krysztofiak, G ^b,i   Marandino, C A ^a   Sinnhuber, B M ^b   Tegtmeier, S ^a   Ziska, F ^a   Hossaini, R ^c   Kruger K ^d   Montzka, S A ^e   Atlas, E ^f   Oram, D E ^g   Keber, T ^h   Bonisch H ^h   Quack, B ^a  

^a GEOMAR HELMHOLTZ CENTRE FOR OCEAN RESEARCH KIEL   (Germany)

^b KARLSRUHE INSTITUTE OF TECHNOLOGY   (Germany)

^c UNIVERSITY OF LEEDS   (United Kingdom)

^d UNIVERSITY OF OSLO   (Norway)

^e NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^f UNIVERSITY OF MIAMI   (United States)

^g UNIVERSITY OF EAST ANGLIA   (United Kingdom)

^h GOETHE UNIVERSITY   (Germany)

ⁱ UNIVERSITÉ D'ORLÉANS   (France)

Author keywords

[No Author keywords available]

Indexed keywords

ATMOSPHERIC CHEMISTRY; CONCENTRATION (COMPOSITION); DIMETHYLSULFIDE; EMISSION; HALOCARBON; MIXING RATIO; MODELING; OZONE DEPLETION; STRATOSPHERE; TRACE GAS; TROPOSPHERE; WIND VELOCITY;

EID: 84945948346     PISSN: 16807316     EISSN: 16807324     Source Type: Journal    
DOI: 10.5194/acp-15-11753-2015     Document Type: Article

References (85)

1. Aschmann, J., Sinnhuber, B.-M., Atlas, E. L., and Schauffler, S. M. : Modeling the transport of very short-lived substances into the tropical upper troposphere and lower stratosphere, Atmos. Chem. Phys., 9, 9237-9247, doi:10. 5194/acp-9-9237-2009, 2009.
2. Asher, W. E. and Wanninkhof, R. : The effect of bubblemediated gas transfer on purposeful dual-gaseous tracer experiments, J. Geophys. Res.-Oceans, 103, 10555-10560, doi:10. 1029/98jc00245, 1998.
3. Ayers, G. P., Bentley, S. T., Ivey, J. P., and Forgan, B. W. : Dimethylsulfide in marine air at cape grim, 41- s, J. Geophysical Res.-Atmos., 100, 21013-21021, doi:10. 1029/95jd02144, 1995.
4. Barnes, I., Hjorth, J., and Mihalopoulos, N. : Dimethyl sulfide and dimethyl sulfoxide and their oxidation in the atmosphere, Chemical Rev., 106, 940-975, doi:10. 1021/cr020529+, 2006.
5. Bates, T. S., Lamb, B. K., Guenther, A., Dignon, J., and Stoiber, R. E. : Sulfur emissions to the atmosphere from natural sources, J. Atmos. Chem., 14, 315-337, doi:10. 1007/bf00115242, 1992.
6. Bell, N., Hsu, L., Jacob, D. J., Schultz, M. G., Blake, D. R., Butler, J. H., King, D. B., Lobert, J. M., and Maier-Reimer, E. : Methyl iodide: Atmospheric budget and use as a tracer of marine convection in global models, J. Geophys. Res.-Atmos., 107, 4340, doi:10. 1029/2001jd001151, 2002.
7. Bell, T. G., De Bruyn, W., Miller, S. D., Ward, B., Christensen, K. H., and Saltzman, E. S. : Air-sea dimethylsulfide (DMS) gas transfer in the North Atlantic: evidence for limited interfacial gas exchange at high wind speed, Atmos. Chem. Phys., 13, 11073-11087, doi:10. 5194/acp-13-11073-2013, 2013.
8. Brinckmann, S., Engel, A., Bönisch, H., Quack, B., and Atlas, E. : Short-lived brominated hydrocarbons -observations in the source regions and the tropical tropopause layer, Atmos. Chem. Phys., 12, 1213-1228, doi:10. 5194/acp-12-1213-2012, 2012.
9. Burrows, S. M., Ogunro, O., Frossard, A. A., Russell, L. M., Rasch, P. J., and Elliott, S. M. : A physically based framework for modeling the organic fractionation of sea spray aerosol from bubble film Langmuir equilibria, Atmos. Chem. Phys., 14, 13601-13629, doi:10. 5194/acp-14-13601-2014, 2014.
10. Cameron-Smith, P., Elliott, S., Maltrud, M., Erickson, D., and Wingenter, O. : Changes in dimethyl sulfide oceanic distribution due to climate change, Geophys. Res. Lett., 38, L07704, doi:10. 1029/2011GL047069, 2011.
11. Chameides, W. L. and Davis, D. D. : Iodine -its possible role in tropospheric photochemistry, J. Geophys. Res.-Oceans Atmos., 85, 7383-7398, doi:10. 1029/JC085iC12p07383, 1980.
12. Charlson, R. J., Lovelock, J. E., Andreae, M. O., and Warren, S. G. : Oceanic phytoplankton, atmospheric sulfur, cloud albedo and climate, Nature, 326, 655-661, doi:10. 1038/326655a0, 1987
13. De Bruyn, W. J., Swartz, E., Hu, J. H., Shorter, J. A., Davidovits, P., Worsnop, D. R., Zahniser, M. S., and Kolb, C. E. : Henrys law solubilities and setcheniw coefficients for biogenic reduced sulphur species obtained from gas-liquid uptake measurements, J. Geophys. Res.-Atmos., 100, 7245-7251, doi:10. 1029/95JD00217, 1995.
14. Dee, D. P., Uppala, S. M., Simmons, A. J., Berrisford, P., Poli, P., Kobayashi, S., Andrae, U., Balmaseda, M. A., Balsamo, G., Bauer, P., Bechtold, P., Beljaars, A. C. M., van de Berg, L., Bidlot, J., Bormann, N., Delsol, C., Dragani, R., Fuentes, M., Geer, A. J., Haimberger, L., Healy, S. B., Hersbach, H., Holm, E. V., Isaksen, L., Kallberg, P., Köhler, M., Matricardi, M., McNally, A. P., Monge-Sanz, B. M., Morcrette, J. J., Park, B. K., Peubey, C., de Rosnay, P., Tavolato, C., Thepaut, J. N., and Vitart, F. : The erainterim reanalysis: Configuration and performance of the data assimilation system, Q. J. Roy. Meteorol. Soc., 137, 553-597, doi:10. 1002/qj. 828, 2011.
15. Elliott, S., Burrows, S. M., Deal, C., Liu, X., Long, M., Ogunro, O., Russell, L. M., and Wingenter, O. : Prospects for simulating macromolecular surfactant chemistry at the ocean-atmosphere boundary, Environ. Res. Lett., 9, 064012, doi:10. 1088/1748-9326/9/6/064012, 2014.
16. Hall, B. D., Engel, A., Muhle, J., Elkins, J. W., Artuso, F., Atlas, E., Aydin, M., Blake, D., Brunke, E.-G., Chiavarini, S., Fraser, P. J., Happell, J., Krummel, P. B., Levin, I., Loewenstein, M., Maione, M., Montzka, S. A., ODoherty, S., Reimann, S., Rhoderick, G., Saltzman, E. S., Scheel, H. E., Steele, L. P., Vollmer, M. K., Weiss, R. F., Worthy, D., and Yokouchi, Y. : Results from the International Halocarbons in Air Comparison Experiment (IHALACE), Atmos. Meas. Tech., 7, 469-490, doi:10. 5194/amt-7-469-2014, 2014.
17. Hayduk, W. and Laudie, H. : Prediction of diffusion coefficients for nonelectrolytes in dilute aqueous solutions, AIChE Journal, 20, 611-615, doi:10. 1002/aic. 690200329, 1974.
18. Hepach, H., Quack, B., Raimund, S., Fischer, T., Atlas, E. L., and Bracher, A. : Halocarbon emissions and sources in the equatorial Atlantic Cold Tongue, Biogeosciences Discuss., 12, 5559-5608, doi:10. 5194/bgd-12-5559-2015, 2015.
19. Ho, D. T., Bliven, L. F., Wanninkhof, R., and Schlosser, P. : The effect of rain on air-water gas exchange, Tellus B, 49, 149-158, 1997.
20. Ho, D. T., Zappa, C. J., McGillis, W. R., Bliven, L. F., Ward, B., Dacey, J. W. H., Schlosser, P., and Hendricks, M. B. : Influence of rain on air-sea gas exchange: Lessons from a model ocean, J. Geophys. Res.-Oceans, 109, C08S18, doi:10. 1029/2003jc001806, 2004.
21. Ho, D. T., Law, C. S., Smith, M. J., Schlosser, P., Harvey, M., and Hill, P. : Measurements of air-sea gas exchange at high wind speeds in the southern ocean: Implications for global parameterizations, Geophys. Res. Lett., 33, L16611, doi:10. 1029/2006gl026817, 2006.
22. Hopkins, F. E. and Archer, S. D. : Consistent increase in dimethyl sulfide (DMS) in response to high CO2 in five shipboard bioassays from contrasting NW European waters, Biogeosciences, 11, 4925-4940, doi:10. 5194/bg-11-4925-2014, 2014.
23. Hossaini, R., Chipperfield, M. P., Monge-Sanz, B. M., Richards, N. A. D., Atlas, E., and Blake, D. R. : Bromoform and dibromomethane in the tropics: a 3-D model study of chemistry and transport, Atmos. Chem. Phys., 10, 719-735, doi:10. 5194/acp-10-719-2010, 2010.
24. Hossaini, R., Mantle, H., Chipperfield, M. P., Montzka, S. A., Hamer, P., Ziska, F., Quack, B., Kruger, K., Tegtmeier, S., Atlas, E., Sala, S., Engel, A., Bönisch, H., Keber, T., Oram, D., Mills, G., Ordoñez, C., Saiz-Lopez, A., Warwick, N., Liang, Q., Feng, W., Moore, F., Miller, B. R., Marecal, V., Richards, N. A. D., Dorf, M., and Pfeilsticker, K. : Evaluating global emission inventories of biogenic bromocarbons, Atmos. Chem. Phys., 13, 11819-11838, doi:10. 5194/acp-13-11819-2013, 2013.
25. Hossaini, R., Chipperfield, M. P., Montzka, S. A., Rap, A., Dhomse, S., and Feng, W. : Efficiency of short-lived halogens at influencing climate through depletion of stratospheric ozone, Nat. Geosci., 8, 186-190, doi:10. 1038/ngeo2363, 2015.
26. Hough, A. : The calculation of photolysis rates for use in global tropospheric modelling studies, UKAEA Atomic Energy Research Establishment Environmental and Medical Sciences Division, UK, 54 pp., 1988.
27. Jöckel, P. : Technical note: Recursive rediscretisation of geoscientific data in the Modular Earth Submodel System (MESSy), Atmos. Chem. Phys., 6, 3557-3562, doi:10. 5194/acp-6-3557-2006, 2006.
28. Jöckel, P., Tost, H., Pozzer, A., Bruhl, C., Buchholz, J., Ganzeveld, L., Hoor, P., Kerkweg, A., Lawrence, M. G., Sander, R., Steil, B., Stiller, G., Tanarhte, M., Taraborrelli, D., van Aardenne, J., and Lelieveld, J. : The atmospheric chemistry general circulation model ECHAM5/MESSy1: consistent simulation of ozone from the surface to the mesosphere, Atmos. Chem. Phys., 6, 5067-5104, doi:10. 5194/acp-6-5067-2006, 2006.
29. Jöckel, P., Kerkweg, A., Pozzer, A., Sander, R., Tost, H., Riede, H., Baumgaertner, A., Gromov, S., and Kern, B. : Development cycle 2 of the Modular Earth Submodel System (MESSy2), Geosci. Model Dev., 3, 717-752, doi:10. 5194/gmd-3-717-2010, 2010.
30. Karlsson, A., Theorin, M., and Abrahamsson, K. : Distribution, transport, and production of volatile halocarbons in the upper waters of the ice-covered high arctic ocean, Global Biogeochem. Cy., 27, 1246-1261, doi:10. 1002/2012gb004519, 2013.
31. Kerkweg, A., Buchholz, J., Ganzeveld, L., Pozzer, A., Tost, H., and Jöckel, P. : Technical Note: An implementation of the dry removal processes DRY DEPosition and SEDImentation in the Modular Earth Submodel System (MESSy), Atmos. Chem. Phys., 6, 4617-4632, doi:10. 5194/acp-6-4617-2006, 2006a.
32. Kerkweg, A., Sander, R., Tost, H., and Jöckel, P. : Technical note: Implementation of prescribed (OFFLEM), calculated (ONLEM), and pseudo-emissions (TNUDGE) of chemical species in the Modular Earth Submodel System (MESSy), Atmos. Chem. Phys., 6, 3603-3609, doi:10. 5194/acp-6-3603-2006, 2006b.
33. Kloster, S., Feichter, J., Maier-Reimer, E., Six, K. D., Stier, P., and Wetzel, P. : DMS cycle in the marine ocean-atmosphere system -a global model study, Biogeosciences, 3, 29-51, doi:10. 5194/bg-3-29-2006, 2006.
34. Kondo, J. : Air-sea bulk transfer coefficients in diabatic conditions, Bound.-Lay. Meteorol., 9, 91-112, doi:10. 1007/bf00232256, 1975.
35. Lana, A., Bell, T. G., Simo, R., Vallina, S. M., Ballabrera-Poy, J., Kettle, A. J., Dachs, J., Bopp, L., Saltzman, E. S., Stefels, J., Johnson, J. E., and Liss, P. S. : An updated climatology of surface dimethlysulfide concentrations and emission fluxesin the global ocean, Global Biogeochem. Cy., 25, GB1004, doi:10. 1029/2010gb003850, 2011.
36. Liang, Q., Stolarski, R. S., Kawa, S. R., Nielsen, J. E., Douglass, A. R., Rodriguez, J. M., Blake, D. R., Atlas, E. L., and Ott, L. E. : Finding the missing stratospheric Bry: a global modeling study of CHBr3 and CH2Br2, Atmos. Chem. Phys., 10, 2269-2286, doi:10. 5194/acp-10-2269-2010, 2010.
37. Lin, S. J. and Rood, R. B. : Multidimensional fluxform semi-lagrangian transport schemes, Mon. Weather Rev., 124, 2046-2070, doi:10. 1175/1520-0493(1996)1242. 0. CO;2, 1996.
38. Liss, P. and Slater, P. : Flux of gases across the air-sea interface, Nature, 247, 181-184, 1974.
39. Liss, P. S. and Merlivat, L. : Air-sea gas exchange rates: Introduction and synthesis, in: The role of air-sea gas exchange in geochemical cycling, edited by: Buat-Menard, P., Reidel, D., Norwell, Mass., 113-127, 1986.
40. Lovelock, J. E. and Maggs, R. J. : Halogenated hydrocarbons in and over the atlantic, Nature, 241, 194-196, doi:10. 1038/241194a0, 1973.
41. Lyman, W., Reehl, W., and Rosenblatt, D. : Handbook of chemical property estimation mehods, American Chemical Society, Washington DC, USA, 1990.
42. Marandino, C. A., De Bruyn, W. J., Miller, S. D., and Saltzman, E. S. : Eddy correlation measurements of the air/sea flux of dimethylsulfide over the north pacific ocean, J. Geophys. Res.-Atmos., 112, D03301, doi:10. 1029/2006jd007293, 2007.
43. Marandino, C. A., De Bruyn, W. J., Miller, S. D., and Saltzman, E. S. : DMS air/sea flux and gas transfer coefficients from the north atlantic summertime coccolithophore bloom, Geophys. Res. Lett., 35, L23812, doi:10. 1029/2008gl036370, 2008.
44. Marandino, C. A., De Bruyn, W. J., Miller, S. D., and Saltzman, E. S. : Open ocean DMS air/sea fluxes over the eastern South Pacific Ocean, Atmos. Chem. Phys., 9, 345-356, doi:10. 5194/acp-9-345-2009, 2009.
45. Marandino, C. A., Tegtmeier, S., Kruger, K., Zindler, C., Atlas, E. L., Moore, F., and Bange, H. W. : Dimethylsulphide (DMS) emissions from the western Pacific Ocean: a potential marine source for stratospheric sulphur?, Atmos. Chem. Phys., 13, 8427-8437, doi:10. 5194/acp-13-8427-2013, 2013a.
46. Marandino, C. A., Tegtmeier, S., Kruger, K., Zindler, C., Atlas, E. L., Moore, F., and Bange, H. W. : Corrigendum to Dimethylsulphide (DMS) emissionsfrom the West Pacific Ocean: a potential marine source for stratospheric sulphur? published in Atmos. Chem. Phys., 13, 8427-8437, 2013, Atmos. Chem. Phys., 13, 8813-8814, doi:10. 5194/acp-13-8813-2013, 2013b.
47. McGillis, W. R., Dacey, J. W. H., Frew, N. M., Bock, E. J., and Nelson, R. K. : Water-air flux of dimethylsulfide, J. Geophys. Res.-Oceans, 105, 1187-1193, doi:10. 1029/1999jc900243, 2000.
48. Moore, R. M., Geen, C. E., and Tait, V. K. : Determination of henry law constants for a suite of naturally-occurring halogenated methanes in seawater, Chemosphere, 30, 1183-1191, doi:10. 1016/0045-6535(95)00009-w, 1995.
49. Nightingale, P. D., Malin, G., Law, C. S., Watson, A. J., Liss, P. S., Liddicoat, M. I., Boutin, J., and Upstill-Goddard, R. C. : In situ evaluation of air-sea gas exchange parameterizations using novel conservative and volatile tracers, Global Biogeochem. Cy., 14, 373-387, doi:10. 1029/1999gb900091, 2000.
50. ODowd, C. D. and De Leeuw, G. : Marine aerosol production: A review of the current knowledge, Philos. Trans. R. Soc. A-Math. Phys. Eng. Sci., 365, 1753-1774, doi:10. 1098/rsta. 2007. 2043, 2007.
51. Ordoñez, C., Lamarque, J.-F., Tilmes, S., Kinnison, D. E., Atlas, E. L., Blake, D. R., Sousa Santos, G., Brasseur, G., and Saiz-Lopez, A. : Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources, Atmos. Chem. Phys., 12, 1423-1447, doi:10. 5194/acp-12-1423-2012, 2012.
52. Orkin, V. L., Khamaganov, V. G., Kozlov, S. N., and Kurylo, M. J. : Measurements of rate constants for the oh reactions with bromoform (chbr3), chbr2cl, chbrcl2, and epichlorohydrin (c3h5clo), J. Phys. Chem. A, 117, 3809-3818, doi:10. 1021/jp3128753, 2013.
53. Osthoff, H. D., Bates, T. S., Johnson, J. E., Kuster, W. C., Goldan, P., Sommariva, R., Williams, E. J., Lerner, B. M., Warneke, C., de Gouw, J. A., Pettersson, A., Baynard, T., Meagher, J. F., Fehsenfeld, F. C., Ravishankara, A. R., and Brown, S. S. : Regional variation of the dimethyl sulfide oxidation mechanism in the summertime marine boundary layer in the gulf of maine, J. Geophys. Res.-Atmos., 114, D07301, doi:10. 1029/2008jd010990, 2009.
54. Papanastasiou, D. K., McKeen, S. A., and Burkholder, J. B. : The very short-lived ozone depleting substance CHBr3 (bromoform): revised UV absorption spectrum, atmospheric lifetime and ozone depletion potential, Atmos. Chem. Phys., 14, 3017-3025, doi:10. 5194/acp-14-3017-2014, 2014.
55. Patra, P. K., Krol, M. C., Montzka, S. A., Arnold, T., Atlas, E. L., Lintner, B. R., Stephens, B. B., Xiang, B., Elkins, J. W., Fraser, P. J., Ghosh, A., Hintsa, E. J., Hurst, D. F., Ishijima, K., Krummel, P. B., Miller, B. R., Miyazaki, K., Moore, F. L., Muehle, J., ODoherty, S., Prinn, R. G., Steele, L. P., Takigawa, M., Wang, H. J., Weiss, R. F., Wofsy, S. C., and Young, D. : Observational evidence for interhemispheric hydroxyl-radical parity, Nature, 513, 219-223, doi:10. 1038/nature13721, 2014.
56. Penkett, S. A., Jones, B. M. R., Rycroft, M. J., and Simmons, D. A. : An interhemispheric comparison of the concentrations of bromine compounds in the atmosphere, Nature, 318, 550-553, doi:10. 1038/318550a0, 1985.
57. Pozzer, A., Jöckel, P., Sander, R., Williams, J., Ganzeveld, L., and Lelieveld, J. : Technical Note: The MESSy-submodel AIRSEA calculating the air-sea exchange of chemical species, Atmos. Chem. Phys., 6, 5435-5444, doi:10. 5194/acp-6-5435-2006, 2006.
58. Quack, B. and Wallace, D. W. R. : Air-sea flux of bromoform: Controls, rates, and implications, Global Biogeochem. Cy., 17, 1023, doi:10. 1029/2002gb001890, 2003.
59. Saiz-Lopez, A., Plane, J. M. C., Baker, A. R., Carpenter, L. J., von Glasow, R., Martin, J. C. G., McFiggans, G., and Saunders, R. W. : Atmospheric chemistry of iodine, Chemical Rev., 112, 1773-1804, doi:10. 1021/cr200029u, 2012.
60. Sala, S., Bönisch, H., Keber, T., Oram, D. E., Mills, G., and Engel, A. : Deriving an atmospheric budget of total organic bromine using airborne in situ measurements from the western Pacific area during SHIVA, Atmos. Chem. Phys., 14, 6903-6923, doi:10. 5194/acp-14-6903-2014, 2014.
61. Salawitch, R. J. : Atmospheric chemistry: Biogenic bromine, Nature, 439, 275-277, doi:10. 1038/439275a, 2006.
62. Salawitch, R. J., Weisenstein, D. K., Kovalenko, L. J., Sioris, C. E., Wennberg, P. O., Chance, K., Ko, M. K. W., and McLinden, C. A. : Sensitivity of ozone to bromine in the lower stratosphere, Geophys. Res. Lett., 32, L05811, doi:10. 1029/2004gl021504, 2005.
63. Saltzman, E. S., King, D. B., Holmen, K., and Leck, C. : Experimental determination of the diffusion coefficient of dimethylsulfide in water, J. Geophys. Res.-Oceans, 98, 16481-16486, doi:10. 1029/93jc01858, 1993.
64. Sander, R., Baumgaertner, A., Gromov, S., Harder, H., Jöckel, P., Kerkweg, A., Kubistin, D., Regelin, E., Riede, H., Sandu, A., Taraborrelli, D., Tost, H., and Xie, Z.-Q. : The atmospheric chemistry box model CAABA/MECCA-3. 0, Geosci. Model Dev., 4, 373-380, doi:10. 5194/gmd-4-373-2011, 2011.
65. Sciare, J., Mihalopoulos, N., and Dentener, F. J. : Interannual variability of atmospheric dimethylsulfide in the southern indian ocean, J. Geophys. Res.-Atmos., 105, 26369-26377, doi:10. 1029/2000jd900236, 2000.
66. Sheng, J.-X., Weisenstein, D. K., Luo, B.-P., Rozanov, E., Stenke, A., Anet, J., Bingemer, H., and Peter, T. : Global atmospheric sulfur budget under volcanically quiescent conditions: Aerosolchemistry-climate model predictions and validation, J. Geophys. Res.-Atmos., 120, 2014JD021985, doi:10. 1002/2014jd021985, 2015.
67. Shi, Q., Petrick, G., Quack, B., Marandino, C., and Wallace, D. : Seasonal variability of methyl iodide in the kiel fjord, J. Geophys. Res.-Oceans, 119, 1609-1620, doi:10. 1002/2013jc009328, 2014.
68. Sinnhuber, B.-M. and Meul, S. : Simulating the impact of emissions of brominated very short lived substances on past stratospheric ozone trends, Geophys. Res. Lett., 42, 2449-2456, doi:10. 1002/2014gl062975, 2015.
69. Sinnhuber, B.-M., Sheode, N., Sinnhuber, M., Chipperfield, M. P., and Feng, W. : The contribution of anthropogenic bromine emissions to past stratospheric ozone trends: a modelling study, Atmos. Chem. Phys., 9, 2863-2871, doi:10. 5194/acp-9-2863-2009, 2009.
70. Solomon, S., Garcia, R. R., and Ravishankara, A. R. : On the role of iodine in ozone depletion, J. Geophys. Res.-Atmos., 99, 20491-20499, doi:10. 1029/94jd02028, 1994.
71. Taylor, K. E. : Summarizing multiple aspects of model performance in a single diagram, J. Geophys. Res.-Atmos., 106, 7183-7192, doi:10. 1029/2000jd900719, 2001.
72. Tegtmeier, S., Kruger, K., Quack, B., Atlas, E., Blake, D. R., Boenisch, H., Engel, A., Hepach, H., Hossaini, R., Navarro, M. A., Raimund, S., Sala, S., Shi, Q., and Ziska, F. : The contribution of oceanic methyl iodide to stratospheric iodine, Atmos. Chem. Phys., 13, 11869-11886, doi:10. 5194/acp-13-11869-2013, 2013.
73. Tiedtke, M. : A comprehensive mass flux scheme for cumulus parameterization in large-scale models, Mon. Weather Rev., 117, 1779-1800, doi:10. 1175/1520-0493(1989)1172. 0. CO;2, 1989.
74. Tsai, W. T. and Liu, K. K. : An assessment of the effect of sea surface surfactant on global atmosphere-ocean co2 flux, J. Geophys. Res.-Oceans, 108, 3127, doi:10. 1029/2000jc000740, 2003.
75. von Glasow, R., von Kuhlmann, R., Lawrence, M. G., Platt, U., and Crutzen, P. J. : Impact of reactive bromine chemistry in the troposphere, Atmos. Chem. Phys., 4, 2481-2497, doi:10. 5194/acp-4-2481-2004, 2004.
76. Wanninkhof, R. : Relationship between wind speed and gas exchange over the ocean, J. Geophys. Res., 97, 7373-7382, 1992.
77. Wanninkhof, R. and McGillis, W. R. : A cubic relationship between air-sea co2 exchange and wind speed, Geophys. Res. Lett., 26, 1889-1892, doi:10. 1029/1999gl900363, 1999.
78. Wanninkhof, R., Asher, W. E., Ho, D. T., Sweeney, C., and McGillis, W. R. : Advances in quantifying air-sea gas exchange and environmental forcing, Ann. Rev. Marine Sci., 1, 213-244, doi:10. 1146/annurev. marine. 010908. 163742, 2009.
79. Warwick, N. J., Pyle, J. A., Carver, G. D., Yang, X., Savage, N. H., OConnor, F. M., and Cox, R. A. : Global modeling of biogenic bromocarbons, J. Geophys. Res.-Atmos., 111, D24305, doi:10. 1029/2006jd007264, 2006.
80. Watts, S. F. : The mass budgets of carbonyl sulfide, dimethyl sulfide, carbon disulfide and hydrogen sulfide, Atmos. Environ., 34, 761-779, doi:10. 1016/s1352-2310(99)00342-8, 2000.
81. Wilke, C. R. and Chang, P. : Some measurements of diffusion in liquids, J. Phys. Chem., 59, 592-596, 1955.
82. Wisher, A., Oram, D. E., Laube, J. C., Mills, G. P., van Velthoven, P., Zahn, A., and Brenninkmeijer, C. A. M. : Very short-lived bromomethanes measured by the CARIBIC observatory over the North Atlantic, Africa and Southeast Asia during 2009-2013, Atmos. Chem. Phys., 14, 3557-3570, doi:10. 5194/acp-14-3557-2014, 2014.
83. Wofsy, S. C., B. C. Daube, R. Jimenez, Kort, E., Pittman, J. V., Park, S., Commane, R., Xiang, B., Santoni, G., Jacob, D., Fisher, J., Pickett-Heaps, C., Wang, H., Wecht, K., Wang, Q.-Q., B. Stephens, B., Shertz, S., Watt, A. S., Romashkin, P., Campos, T., Haggerty, J., Cooper, W. A., Rogers, D., Beaton, S., Hendershot, R., Elkins, J. W., Fahey, D. W., Gao, R. S., Moore, F., Montzka, S. A., Schwarz, J. P., Perring, A. E., Hurst, D., Miller, B. R., Sweeney, C., Oltmans, S., D. Nance, Hintsa, E., Dutton, G., Watts, L. A., Spackman, J. R., Rosenlof, K. H., Ray, E. A., B. Hall, Zondlo, M. A., Diao, M., Keeling, R., Bent, J., Atlas, E. L., Lueb, R., and Mahoney, M. J. : Hippo combined discrete flask and gc sample ghg, halo-, hydrocarbon data (r-20121129), Center, C. d. I. A., Oak Ridge National Laboratory, Oak Ridge, Tenessee, USA, 2012.
84. Yu, S., Eder, B., Dennis, R., Chu, S.-H., and Schwartz, S. E. : New unbiased symmetric metrics for evaluation of air quality models, Atmos. Sci. Lett., 7, 26-34, doi:10. 1002/asl. 125, 2006.
85. Ziska, F., Quack, B., Abrahamsson, K., Archer, S. D., Atlas, E., Bell, T., Butler, J. H., Carpenter, L. J., Jones, C. E., Harris, N. R. P., Hepach, H., Heumann, K. G., Hughes, C., Kuss, J., Kruger, K., Liss, P., Moore, R. M., Orlikowska, A., Raimund, S., Reeves, C. E., Reifenhauser, W., Robinson, A. D., Schall, C., Tanhua, T., Tegtmeier, S., Turner, S., Wang, L., Wallace, D., Williams, J., Yamamoto, H., Yvon-Lewis, S., and Yokouchi, Y. : Global sea-toair flux climatology for bromoform, dibromomethane and methyl iodide, Atmos. Chem. Phys., 13, 8915-8934, doi:10. 5194/acp-13-8915-2013, 2013.