Regional variation of the dimethyl sulfide oxidation mechanism in the summertime marine boundary layer in the Gulf of Maine

Journal of Geophysical Research Atmospheres

Volumn 114, Issue 7, 2009, Pages

  Osthoff, Hans D ^a,b,c   Bates, Timothy S ^d   Johnson, James E ^d,e   Küster, William C ^a   Goldan, Paul ^a,b   Sommariva, Roberto ^a,b   Williams, Eric J ^a,b   Lerner, Brian M ^a,b   Warneke, Carsten ^a,b   De Gouw, Joost A ^a,b   Pettersson, Anders ^a,b   Baynard, Tahllee ^a,b   Meagher, James F ^a   Fehsenfeld, Frederick C ^a,b   Ravishankara, A R ^a,b   Brown, Steven S ^a  

^a EARTH SYSTEM RESEARCH LABORATORY   (United States)

^b UNIVERSITY OF COLORADO   (United States)

^c UNIVERSITY OF CALGARY   (Canada)

^d NOAA EARTH SYSTEM RESEARCH LABORATORY   (United States)

^e UNIVERSITY OF WASHINGTON   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AERODYNAMICS; AIR QUALITY; BOUNDARY LAYERS; COASTAL ZONES; DIAMONDS; HALOGEN ELEMENTS; OCEAN ENGINEERING; OCEANOGRAPHY; OXIDATION; REACTION KINETICS; SEAWATER; SULFUR; SULFUR COMPOUNDS;

AEROSOL FORMATION; CHEMICAL TRANSFORMATIONS; COASTAL REGIONS; DIMETHYL SULFIDE; DIMETHYL SULFIDE OXIDATION; ENTRAINMENT VELOCITIES; GULF OF MAINE; HALOGEN SPECIES; INTERNATIONAL TRANSPORT; MARINE BOUNDARY LAYERS; MIXING RATIOS; NEW ENGLAND AIR QUALITY STUDIES; NITRATE RADICALS; OXIDATION RATES; REGIONAL VARIATION; SIMULTANEOUS MEASUREMENT; WIND SPEED;

SIPHONS;

AEROSOL FORMATION; AIR QUALITY; ALTITUDE; ATMOSPHERIC MODELING; ATMOSPHERIC POLLUTION; BOUNDARY LAYER; DIMETHYLSULFIDE; ENTRAINMENT; HALOGEN; MIXING RATIO; NITRATE; OXIDATION; PHOTOCHEMISTRY; RADICAL; REDUCTION; SEAWATER; SULFUR;

ATLANTIC OCEAN; GULF OF MAINE;

EID: 66249120153     PISSN: 01480227     EISSN: None     Source Type: Journal    
DOI: 10.1029/2008JD010990     Document Type: Article

References (50)

1. 5 in a polluted marine environment: Results from in situ measurements during New England Air Quality Study 2002, Z Geophys. Res., 111, D23S73, doi:10.1029/2006JD007252.
2. Allan, B. J., et al. (2000), Observations of iodine monoxide in the remote marine boundary layer, Z Geophys. Res., 105, 14,363-14,369, doi:10.1029/1999JD901188.
3. Angevine, W. M., et al. (2006), Structure and formation of the highly stable marine boundary layer over the Gulf of Maine, Z Geophys. Res., 111, D23S22, doi:10.1029/2006JD007465.
4. Bandy, A., et al. (1996), Chemistry of dimethyl sulfide in the equatorial Pacific atmosphere, Geophys. Res. Lett., 23, 741-744, doi: 10.1029/96GL00779.
5. Barnes, I., et al. (2006), Dimethyl sulfide and dimethyl sulfoxide and their oxidation in the atmosphere, Chem. Rev., 106, 940-975, doi:10.1021/ cr020529.
6. Bates, T. S., et al. (1998), Processes controlling the distribution of aerosol particles in the lower marine boundary layer during the First Aerosol Characterization Experiment (ACE 1), Z, Geophys. Res., 103, 16,369-16,383.
7. Bates, T. S., et al. (2000), Aerosol physical properties and processes in the lower marine boundary layer: A comparison of shipboard sub-micron data from ACE-I and ACE-2, Tellus, Ser. B, 52, 258-272.
8. x in the summer marine boundary layer, Geophys. Res. Lett., 31, L07108, doi:10.1029/2004GL019412.
9. 5 and their implications for tropospheric chemistry, Z Photochem. Photobiol Chem., 176, 270-278, doi:10.1016/j.jphotochem.2005.10.004.
10. Charlson, R. J., et al. (1987), Oceanic phytoplankton, atmospheric sulfur, cloud albedo and climate, Nature, 326,655-661, doi:10.1038/326655a0.
11. 3 using the wetted-wall flowtube technique, Atmos. Chem. Phys., 3, 1665-1673.
12. De Bruyn, W. J., et al. (1998), Shipboard measurements of dimethyl sulfide and SO2 southwest of Tasmania during the First Aerosol Characterization Experiment (ACE 1), Z. Geophys. Res., 103, 16,703-16,711, doi:10.1029/98JD00971.
13. De Bruyn, W. J., et al. (2006), DMS and SO2 measurements in the tropical marine boundary layer, Z Atmos. Client., 53, 145-154, doi:10.1007/S10874-005-9000-Z.
14. de Gouw, J. A., et al. (2005), Budget of organic carbon in a polluted atmosphere: Results from the New England Air Qualify Study in 2002, Z Geophys. Res., 110, D16305, doi:10.1029/2004JD005623.
15. Faloona, L, et al. (2005), Observations of entrainment in eastern Pacific marine stratocumulus using three conserved scalars, Z .Atmos. Sci., 62, 3268-3285, doi:10.1175/JAS3541.1.
16. Fehsenfeld, F. C, et al. (2006), International Consortium for Atmospheric Research on Transport and Transformation (ICARTT): North America to Europe-Overview of the 2004 summer field study, Z Geophys. Res., 111, D23S01, doi:10.1029/2006JD007829.
17. 2 on synthetic sea salt and some of its components, Geophys. Res. Lett., 27, 887-890, doi:10.1029/1999GL011152.
18. Gershenzon, M., et al. (2001), Simultaneous uptake of DMS and ozone on water, Z Phys. Chem. A, 105, 7031-7036, doi:10.1021/jp010696y.
19. Goldan, P. D., et al. (2004), Nonmethane hydrocarbon and oxy hydrocarbon measurements during the 2002 New England Air Quality Study, Z Geophys. Res., 109, D21309, doi:10.1029/2003JD004455.
20. Hynes, A. J., et al. (1986), Kinetics and mechanism of OH reactions with organic sulfides, Z Phys. Chem., 90, 4148-4156, doi:10.1021/J100408a062.
21. Jenkin, M. E., et al. (2003), Protocol for the development of the Master Chemical Mechanism, MCM v3(Part B): Tropospheric degradation of aromatic volatile organic compounds, Atmos. Chem. Phys., 3, 181-193.
22. 3, Z Atmos. Chem., 14, 95-108, doi:10.1007/BF00115226.
23. Jobson, B. T., et al. (1998), Spatial and temporal variability of nonmethane hydrocarbon mixing ratios and their relation to photochemical lifetime, Z Geophys. Res., 103, 13,557-13,567, doi:10.1029/97JD01715.
24. Langner, J., and H. Rodhe (1991), A global 3-dimensional model of the tropospheric sulfur cycle, Z Atmos. Chem., 13, 225-263, doi:10.1007/BF00058134.
25. Lucas, D. D., and R. G. Prinn (2002), Mechanistic studies of dimethylsulfide oxidation products using an observationally constrained model, Z Geophys. Res., 107(D14), 4201, doi:10.1029/2001JD000843.
26. Lucas, D. D., and R. G. Prinn (2003), Tropospheric distributions of sulfuric acid-water vapor aerosol nucleation rates from dimethylsulfide oxidation, Geophys. Res. Lett., 30(22), 2136, doi:10.1029/2003GL018370.
27. Lucas, D. D., and R. G. Prinn (2005a), Parametric sensitivity and uncertainty analysis of dimethylsulfide oxidation in the clear-sky remote marine boundary layer, Atmos. Chem. Phys., 5, 1505-1525.
28. Lucas, D. D., and R. G. Prinn (2005b), Sensitivities of gas-phase dimemylsulfide oxidation products to the assumed mechanisms in a chemical transport model, Z Geophys. Res., 110, D21312, doi:10.1029/2004JD005386.
29. Nightingale, P. D., et al. (2000), In situ evaluation of air-sea gas exchange parameterizations using novel conservative and volatile tracers, Global Biogeochem. Cycles, 14, 373-387, doi:10.1029/1999GB900091.
30. Osthoff, H. D., et al. (2006), Observation of daytime N2O5 in the marine boundary layer during New England Air Quality Study-Intercontinental Transport and Chemical Transformation 2004, Z Geophys. Res., 111 D23S14, doi:10.1029/2006JD007593.
31. Pilling, M. J., and P. W. Seakins (1995), Reaction Kinetics, Oxford Univ. Press, Oxford, U. K.
32. Piatt, U., et al. (2002), Free radicals and fast photochemistry during BERLIOZ, Z Atmos. Chem., 42, 359-394,- doi:10.1023/A:1015707531660.
33. Pszenny, A. A. P., E. V. Fischer, R. S. Russo, B. C Sive, and R. K. Varner(2007), Estimates of Cl atom concentrations and hydrocarbon kinetic reactivity in surface air at Appledore Island, Maine (USA), during International Consortium for Atmospheric Research on Transport and Transformation/Chemistry of Halogens at the Isles of Shoals, Z Geophys. Res.,112, D10S13, doi:10.1029/2006JD007725.
34. x removal, Atmos. Environ., 18, 2421 -2432, doi: 10.1016/0004-6981(84)90012-X.
35. 3 in the mid-latitude marine boundary layer, Atmos. Chem. Phys., 6, 1513-1528.
36. Sander, S. P., et al. (2006), Chemical kinetics and photochemical data for use in atmospheric studies, Eval 15, NASA/Jet Propul. Lab., Pasadena, Calif.
37. 3(Part A): Tropospheric degradation of non-aromatic volatile organic compounds, Atmos. Chem. Phys.-, 3, 161-180.
38. Singh, H. B. (1995), Composition, Chemistry, and Climate of the Atmosphere, 527 pp., Van Nostrand Reinhold, New York.
39. Sommariva, R., et al. (2008), Radicals in the marine boundary layer during NEAQS 2004: A model study of day-time and night-time sources and sinks, Atmos. Chem. Phys. Discuss., 8, 16,643-16,692.
40. Stark, H., et al. (2007), Influence of nitrate radical on the oxidation of dimethyl sulfide in a polluted marine environment, Z Geophys. Res., 112, D10S10, doi:10.1029/2006JD007669.
41. Suhre, K., et al. (1995), Biogenic sulfur emissions and aerosols over the tropical South Atlantic: 2. One-dimensional .simulation of sulfur chemistry in the marine boundary layer, Z Geophys. Res., 100, 11,323-11,334, doi:10.1029/95JD00412.
42. Tumipseed, A. A., et al. (1996), Reaction of OH with dimethyl sulfide: 2. Products and mechanisms, Z Phys. Chem., 100, 14,703-14,713, doi:10.1021/jp960867c.
43. von Glasow, R., and P. J. Crutzen (2004), Model study of multiphase DMS oxidation with a focus on halogens, Atmos. Chem. Phys., 4, 589-608.
44. Warneke, C, et al. (2004), Comparison of daytime and nighttime oxidation of biogenic and anthropogenic VOCs along the New England coast in summer during New England Air Quality Study 2002, Z Geophys. Res., 109, D10309, doi:10.1029/2003JD004424.
45. Warneke, C, et al. (2007), Determination of urban volatile organic compound emission ratios and comparison with an emissions database, Z Geophys. Res., 112, D10S02, doi:10.1029/2006JD007589.
46. Wayne, R. P., et al. (1991), The nitrate radical-Physics, chemistry, and the atmosphere, Atmos. Environ., Part A, 25, 1-203, doi: 10.1016/0960-1686(91)90192-A.
47. Winer, A. M., et al. (1984), Gaseous nitrate radical--Possible nighttime atmospheric sink for biogenic organic compounds, Science, 224, 156-159, doi:10..1126/science.224.4645.156.
48. Wingenter, O. W, et al. (2005), Atomic chlorine concentrations derived from ethane and hydroxyl measurements over the equatorial Pacific Ocean: Implication for dimemyl sulfide and bromine monoxide, Z Geophys. Res., 110, D20308, doi:10.1029/2005JD005875.
49. Yin, F. D., et al. (1990), Photooxidation of dimethyl sulfide and dimethyl disulfide: 1. Mechanism development, Z Atmos. Chem., 11, 309-364, doi:10.1007/BF00053780.
50. Yvon, S. A., et al. (1996), Atmospheric sulfur cycling in the tropical Pacific marine boundary layer (12°S, 1350W): A comparison of field data and model results: 1. Dimethylsulfide, Z Geophys. Res., 101, 6899-6909, doi:10.1029/95JD03356.