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Volumn 5, Issue 9, 2015, Pages 5366-5372

Moisture-Tolerant Frustrated Lewis Pair Catalyst for Hydrogenation of Aldehydes and Ketones

Author keywords

carbonyl; catalysis; frustrated Lewis pair; hydrogenation; moisture tolerant

Indexed keywords

ALDEHYDES; CATALYSIS; CATALYSTS; HYDROGENATION; KETONES; MOISTURE;

EID: 84941141930     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/acscatal.5b01299     Document Type: Article
Times cited : (141)

References (77)
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    • In the presence of amines, however, the borane catalyst 1a becomes sensitive even to trace amount of water and aldehydes. Therefore, appropriate scavengers were utilized during FLP hydrogenation (see in.
    • In the presence of amines, however, the borane catalyst 1a becomes sensitive even to trace amount of water and aldehydes. Therefore, appropriate scavengers were utilized during FLP hydrogenation (see in.
  • 69
    • 84886429221 scopus 로고    scopus 로고
    • Interestingly, even ethereal type of solvent can be a sufficiently strong base to render water binding irreversible. For example, complete loss of FLP hydrogenation activity was reported by Ashley and co-workers when adding 1.0 equiv of water to 1e /dioxane FLP hydrogenation catalyst (see ref 6a)
    • Thomson, J. W.; Hatnean, J. A.; Hastie, J. J.; Pasternak, A.; Stephan, D. W.; Chase, P. A. Org. Process Res. Dev. 2013, 17, 1287-1292 Interestingly, even ethereal type of solvent can be a sufficiently strong base to render water binding irreversible. For example, complete loss of FLP hydrogenation activity was reported by Ashley and co-workers when adding 1.0 equiv of water to 1e /dioxane FLP hydrogenation catalyst (see ref 6a) 10.1021/op4000847
    • (2013) Org. Process Res. Dev. , vol.17 , pp. 1287-1292
    • Thomson, J.W.1    Hatnean, J.A.2    Hastie, J.J.3    Pasternak, A.4    Stephan, D.W.5    Chase, P.A.6
  • 74
    • 79951833533 scopus 로고    scopus 로고
    • Soós, T. Pure Appl. Chem. 2011, 83, 667-675 10.1351/PAC-CON-11-01-02
    • (2011) Pure Appl. Chem. , vol.83 , pp. 667-675
    • Soós, T.1


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.