Dehydrogenation of n -Alkanes by Solid-Phase Molecular Pincer-Iridium Catalysts. High Yields of α-Olefin Product

Journal of the American Chemical Society

Volumn 137, Issue 31, 2015, Pages 9894-9911

  Kumar, Akshai ^a,c   Zhou, Tian ^a   Emge, Thomas J ^a   Mironov, Oleg ^b   Saxton, Robert J ^b   Krogh Jespersen, Karsten ^a   Goldman, Alan S ^a  

^a RUTGERS UNIVERSITY   (United States)

^b CHEVRON ENERGY TECHNOLOGY COMPANY   (United States)

^c INDIAN INSTITUTE OF TECHNOLOGY GUWAHATI   (India)

Author keywords

[No Author keywords available]

Indexed keywords

CATALYSIS; CATALYSTS; DEHYDROGENATION; ETHYLENE; IRIDIUM COMPOUNDS; ISOMERIZATION; ISOMERS; OLEFINS; PARAFFINS; PROPYLENE;

ALKANE DEHYDROGENATIONS; CATALYTIC SYSTEM; DEHYDROGENATION PRODUCTS; HYDROGEN ACCEPTOR; ISOMERIZATION PATHWAYS; MECHANISTIC STUDIES; OLEFIN ISOMERIZATION; TRANSFER DEHYDROGENATION;

IRIDIUM;

ALKANE DERIVATIVE; ALKENE DERIVATIVE; ETHYLENE; HYDROGEN; IRIDIUM; IRIDIUM COMPLEX; PROPYLENE;

ARTICLE; CARBON NUCLEAR MAGNETIC RESONANCE; CATALYST; CHEMICAL REACTION KINETICS; CHEMICAL STRUCTURE; COVALENT BOND; CRYSTAL STRUCTURE; DEHYDROGENATION; DENSITY FUNCTIONAL THEORY; DIMERIZATION; GAS; HYDROGENATION; ISOMERIZATION; MOLECULE; PROTON NUCLEAR MAGNETIC RESONANCE; REPRODUCIBILITY; SOLID; STEADY STATE; SURFACE AREA; THERMODYNAMICS; TURNOVER NUMBER; X RAY DIFFRACTION;

EID: 84938908891     PISSN: 00027863     EISSN: 15205126     Source Type: Journal    
DOI: 10.1021/jacs.5b05313     Document Type: Article

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