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Volumn 127, Issue 35, 2005, Pages 12315-12322

Alkane coordination selectivity in hydrocarbon activation by [Tp′Rh(CNneopentyl)]: The role of alkane complexes

Author keywords

[No Author keywords available]

Indexed keywords

BORATE MINERALS; CARBON; CHEMICAL BONDS; CHLORINE; COMPLEXATION; COORDINATION REACTIONS; HYDROGEN; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PHOTOLYSIS;

EID: 24644447716     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja042152q     Document Type: Article
Times cited : (66)

References (39)
  • 15
    • 0001406599 scopus 로고    scopus 로고
    • For recent reviews on the formation of alkane complexes in the oxidative cleavage of C-H bonds using transition metal catalysts, see: (a) Hall, C.; Perutz, R. Chem. Rev. 1996, 96, 3125.
    • (1996) Chem. Rev. , vol.96 , pp. 3125
    • Hall, C.1    Perutz, R.2
  • 16
    • 0003464697 scopus 로고    scopus 로고
    • Murai, S., Ed.; Springer: New York
    • (b) Topics Organometallic Chemistry; Murai, S., Ed.; Springer: New York, 1999; Vol. 3.
    • (1999) Topics Organometallic Chemistry , vol.3
  • 22
    • 24644447178 scopus 로고    scopus 로고
    • Harris, C. B. et al. Science 1997, 278, 260.
    • (1997) Science , vol.278 , pp. 260
    • Harris, C.B.1
  • 27
    • 16244401629 scopus 로고    scopus 로고
    • Ball has recently reported observation of an equilibrium mixture of σ-pentane complexes to an unsaturated rhenium fragment, showing a slight preference (0.13 kcal/mol) for secondary coordination. See: Lawes, D. J.; Geftakis, S.; Ball, G. E. J. Am. Chem. Soc. 2005, 127, 4134.
    • (2005) J. Am. Chem. Soc. , vol.127 , pp. 4134
    • Lawes, D.J.1    Geftakis, S.2    Ball, G.E.3
  • 28
    • 24644479396 scopus 로고    scopus 로고
    • note
    • Since all methyl groups contain 3 C-H bonds and all methylenes 2 C-H bonds, we will quote binding on a "per group" basis rather than a "per hydrogen" basis.
  • 32
    • 24644454043 scopus 로고    scopus 로고
    • note
    • Alternatively, one could formulate a model in which binding was the same but the rate of oxidative cleavage was different for the two types of methyl group C-H bond. The relative rates would be the same as those found with the present model.
  • 37
    • 0000333617 scopus 로고
    • Wiley: New York; Collect
    • Schuster, R. E. Organic Synthesis; Wiley: New York, 1973; Collect. Vol. V, p 772.
    • (1973) Organic Synthesis , vol.5 , pp. 772
    • Schuster, R.E.1
  • 38
    • 24644483882 scopus 로고    scopus 로고
    • Professor Carl Frieden, Department of Biological Chemistry, Box 8231, Washington University School of Medicine, St. Louis, MO 63110. Available on the web; search KINSIM
    • Professor Carl Frieden, Department of Biological Chemistry, Box 8231, Washington University School of Medicine, St. Louis, MO 63110. Available on the web; search KINSIM.
  • 39
    • 24644470279 scopus 로고    scopus 로고
    • note
    • Amounts were measured using volume for all cases because of the volatility of the solvents used, except isobutane and propane, which were measured by difference using mass.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.