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24644479396
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note
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Since all methyl groups contain 3 C-H bonds and all methylenes 2 C-H bonds, we will quote binding on a "per group" basis rather than a "per hydrogen" basis.
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24644454043
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note
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Alternatively, one could formulate a model in which binding was the same but the rate of oxidative cleavage was different for the two types of methyl group C-H bond. The relative rates would be the same as those found with the present model.
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33
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24644483882
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Professor Carl Frieden, Department of Biological Chemistry, Box 8231, Washington University School of Medicine, St. Louis, MO 63110. Available on the web; search KINSIM
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Professor Carl Frieden, Department of Biological Chemistry, Box 8231, Washington University School of Medicine, St. Louis, MO 63110. Available on the web; search KINSIM.
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39
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note
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Amounts were measured using volume for all cases because of the volatility of the solvents used, except isobutane and propane, which were measured by difference using mass.
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