Decomposition of a Phosphine-Free Metathesis Catalyst by Amines and Other Bronsted Bases: Metallacyclobutane Deprotonation as a Major Deactivation Pathway

ACS Catalysis

Volumn 5, Issue 8, 2015, Pages 4690-4698

  Ireland, Benjamin J ^a   Dobigny, Bernadette T ^a   Fogg, Deryn E ^a  

^a UNIVERSITY OF OTTAWA   (Canada)

Author keywords

amine; decomposition; homogeneous catalysis; Hoveyda catalyst; Hoveyda Grubbs catalyst; metallacyclobutane; olefin metathesis

Indexed keywords

AMINES; CATALYSIS; CATALYSTS; DECOMPOSITION; ETHYLENE; METALS; OLEFINS; PHOSPHORUS COMPOUNDS; PYRIDINE; STYRENE;

1 ,8-DIAZABICYCLO[5.4.0]UNDEC-7-ENE; DEACTIVATION PATHWAYS; DECOMPOSITION PATHWAY; HOMOGENEOUS CATALYSIS; HOVEYDA-GRUBBS CATALYST; METALLACYCLOBUTANE; OLEFIN METATHESIS; PRIMARY AND SECONDARY AMINE;

CATALYST DEACTIVATION;

EID: 84938709495     PISSN: 21555435     EISSN: None     Source Type: Journal    
DOI: 10.1021/acscatal.5b00813     Document Type: Article

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